Abstract: A metallic coating includes a first metal, a second metal, phosphorous, and graphene nanoparticles. The first metal may be nickel and the second metal may be a refractory metal, such as tungsten, rhenium, molybdenum, niobium, tantalum, or mixtures thereof. The metallic coating may have, by weight, 1.0% to 40.0% of refractory metal, 1.0% to 20.0% of phosphorous, 0.01% to 5.0% of the graphene nanoplatelets, and a remainder of the nickel.

Abstract: The invention is a metallic coating comprising a first metal, a second metal, phosphorus, and carbon nanoparticles, wherein the carbon is in the form of graphene. In one example, the carbon nanoparticles are selected from a group consisting of graphene nanoplatelets, graphene oxide, and carbon nanotubes. The first metal may preferably be nickel and the second metal may preferably be a refractory metal. The refractory metal may be selected from a group consisting of tungsten, rhenium, molybdenum, niobium, tantalum, and mixtures thereof, and may preferably be tungsten. The metallic coating may include crystallites having a columnar structure. Crystallites comprising the columnar structure precipitate to form grain structures that improve the mechanical strength of the coating through heat treatment.