Patents Assigned to Penn Color, Inc.
  • Patent number: 11760873
    Abstract: White goniochromatic packaging article. The package wall containing a composition useful for blocking light in the spectrum ranges from about 200 nm to about 1200 nm. The composition has polyester, polymethylpentene, and a light scattering pigment. The composition optionally includes at least one other colorant. Each of the polymethylpentene and the light scattering pigment comprise about 0.1 to about 0.5 weight percent of the wall. The polyester and polymethylpentene are immiscible and when subjected to orientation stresses the composition produces a goniochromatic packaging article.
    Type: Grant
    Filed: December 27, 2018
    Date of Patent: September 19, 2023
    Assignee: Penn Color, Inc.
    Inventors: Kelan Wieloch, Venumadhava S. Eleswarapu, Scott Stamback, James C. Walsh, Fred Biemuller
  • Publication number: 20220340703
    Abstract: The present disclosure generally related to photopolymerizable liquid compositions containing hybridized graft copolymers, reactive diluents and optionally oligomers, photoinitiators, colorants and other additives.
    Type: Application
    Filed: September 25, 2020
    Publication date: October 27, 2022
    Applicant: Penn Color, Inc.
    Inventors: Namgoo Kang, Kenneth Myers, Andrew Sandt, Mark D. Adams, William C. Miles
  • Patent number: 10647804
    Abstract: The present invention provides a process for producing a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink, coating or film that results in a excellent adhesion to metal or plastic substrates. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprising a functional vinylchloride-containing polymer portion having an average molecular weight of from 15,000 to 200,000 g/mole and at least one polymer portion selected from the group consisting of a functional polyolefin and a functional polysiloxane. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer.
    Type: Grant
    Filed: August 5, 2016
    Date of Patent: May 12, 2020
    Assignee: PENN COLOR, INC.
    Inventors: Michael D. Spiegel, Charles B. Rybny
  • Patent number: 10023717
    Abstract: A method of forming a salt-containing carbon-metal particle, the method including forming an aqueous mixture of acidic carbon black and one or more metals and applying energy to the aqueous mixture, whereby applying energy to the aqueous mixture results in the metal chemisorbing to the acidic carbon black. The aqueous mixture may be prepared by preparing an aqueous dispersion of the acidic carbon black and adding metal particles in a zero oxidation state to the aqueous dispersion of the acidic carbon black; or dissolving a metal in a zero oxidation state in an acidic aqueous solution, preparing an aqueous dispersion of the acidic carbon black, and adding the aqueous dispersion of the acidic carbon black to the acidic aqueous solution of the dissolved metal. The acidic carbon black may be oxidized carbon black, and the metal may be zinc, aluminum, gold, iron, lead, silver, copper, or combinations thereof.
    Type: Grant
    Filed: March 4, 2015
    Date of Patent: July 17, 2018
    Assignee: PENN COLOR, INC.
    Inventors: Ronald W. Schuck, Charles B. Rybny
  • Patent number: 9441123
    Abstract: The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
    Type: Grant
    Filed: August 15, 2012
    Date of Patent: September 13, 2016
    Assignee: PENN COLOR, INC.
    Inventors: Michael D. Spiegel, Charles B. Rybny
  • Patent number: 9434849
    Abstract: The present invention provides a durable, external surfactant free, anionic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable acid-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
    Type: Grant
    Filed: October 17, 2013
    Date of Patent: September 6, 2016
    Assignee: PENN COLOR, INC.
    Inventors: Michael D. Spiegel, Charles B. Rybny
  • Publication number: 20140113990
    Abstract: The present invention provides a durable, external surfactant free, anionic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable acid-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
    Type: Application
    Filed: October 17, 2013
    Publication date: April 24, 2014
    Applicant: PENN COLOR, INC.
    Inventors: Michael D. Spiegel, Charles B. Rybny
  • Publication number: 20140051798
    Abstract: The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
    Type: Application
    Filed: August 15, 2012
    Publication date: February 20, 2014
    Applicant: PENN COLOR, INC.
    Inventors: Michael D. SPIEGEL, Charles B. RYBNY
  • Patent number: 8652745
    Abstract: The present invention provides a process for producing a colored toner having a textured surface, the process includes forming a polymer composition of at least one polymer and a colorant, where the at least one polymer has a softening temperature from about 60° C. to about 160° C.; forming an aqueous mineral suspension of at least one multivalent metal phosphate; forming a dispersion by combining the polymer composition and the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition; heating the dispersion to a temperature above a glass transition temperature (Tg) of the polymer composition and increasing the pH to above 7.0; cooling the dispersion including the dispersed particles of the polymer composition to a temperature of from about 1° C. to about 89° C.; and recovering the particles.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: February 18, 2014
    Assignee: Penn Color, Inc.
    Inventors: Ronald W. Schuck, Charles B. Rybny, Choung Lai
  • Publication number: 20130045441
    Abstract: The present invention provides a process for producing a colored toner having a textured surface, the process includes forming a polymer composition of at least one polymer and a colorant, where the at least one polymer has a softening temperature from about 60° C. to about 160° C.; forming an aqueous mineral suspension of at least one multivalent metal phosphate; forming a dispersion by combining the polymer composition and the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition; heating the dispersion to a temperature above a glass transition temperature (Tg) of the polymer composition and increasing the pH to above 7.0; cooling the dispersion including the dispersed particles of the polymer composition to a temperature of from about 1° C. to about 89° C.; and recovering the particles.
    Type: Application
    Filed: July 20, 2012
    Publication date: February 21, 2013
    Applicant: PENN COLOR, INC.
    Inventors: Ronald W. SCHUCK, Charles B. RYBNY, Choung LAI
  • Patent number: 8247155
    Abstract: The present invention provides a process for producing a colored toner comprising the steps of: providing a polymer composition comprising at least one polymer wherein the at least one polymer has a softening temperature from about 30° C. to about 160° C.; and a colorant; forming an aqueous mineral suspension of at least one multivalent metal phosphate by contacting a water-soluble salt of the multivalent metal with an aqueous solution comprising: a water-soluble phosphate salt; and at least one crystal growth inhibitor which controls the growth of the at least one multivalent metal phosphate, wherein the pH of the aqueous mineral suspension is from 5.5 to 14; and forming a dispersion of the polymer composition by adding the polymer composition to the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition, wherein the temperature of the aqueous mineral suspension during the dispersing step is at least about 70° C.
    Type: Grant
    Filed: January 15, 2009
    Date of Patent: August 21, 2012
    Assignee: Penn Color, Inc.
    Inventors: Choung Lai, Ronald W. Schuck, Charles B. Rybny
  • Publication number: 20110159421
    Abstract: The present invention provides a process for producing a colored toner comprising the steps of: providing a polymer composition comprising at least one polymer wherein the at least one polymer has a softening temperature from about 30° C. to about 160° C.; and a colorant; forming an aqueous mineral suspension of at least one multivalent metal phosphate by contacting a water-soluble salt of the multivalent metal with an aqueous solution comprising: a water-soluble phosphate salt; and at least one crystal growth inhibitor which controls the growth of the at least one multivalent metal phosphate, wherein the pH of the aqueous mineral suspension is from 5.5 to 14; and forming a dispersion of the polymer composition by adding the polymer composition to the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition, wherein the temperature of the aqueous mineral suspension during the dispersing step is at least about 70° C.
    Type: Application
    Filed: January 15, 2009
    Publication date: June 30, 2011
    Applicant: Penn Color, Inc.
    Inventors: Choung Lai, Ronald W. Schuck, Charles B. Rybny
  • Patent number: 4176096
    Abstract: A novel, durable thermosetting acrylic automotive finish and method for manufacturing same is described which is manufactured from a predispersed, substantially dry composition. The resultant thermosetting acrylic finish has a higher pigment loading at a sprayable viscosity, thereby reducing the number of applications necessary to produce an acceptable automotive finish. In tests conducted by applicants, the described thermosetting acrylic automotive finish exhibits acceptable durability when exposed to solar radiation for extended periods of time.
    Type: Grant
    Filed: March 13, 1978
    Date of Patent: November 27, 1979
    Assignee: PFD/Penn Color, Inc.
    Inventors: George Patterson, Edgar N. Putman, John B. McCool, III
  • Patent number: 4113650
    Abstract: A combination of an aryl sulfonamide-formaldehyde resin and film forming material, such as cellulose acetate butyrate, which may further include a surfactant, such as a non-ionic surfactant including, for example, an alkylarylpolyether, comprises a "universal" dispersant for resin additives, such as pigment materials. This composition generally includes 40-90 weight % of any of various types of additives, including pigments. The dispersant generally comprises from 30-80 weight % film former or binder, which may consist of cellulose acetate butyrate or a solid plasticizer, such as camphor, sucrose benzoate and dicyclohexylphthalate, and from 20-70 weight % of the aryl sulfonamide-formaldehyde resin. Apart from pigments, the additives may consist of fillers, extenders, etc., including, for example, calcium carbonate, antimony oxide and magnesium silicate.
    Type: Grant
    Filed: August 4, 1975
    Date of Patent: September 12, 1978
    Assignee: PFD/Penn Color, Inc.
    Inventors: Edgar N. Putman, George Patterson, Scotty Wimer, John B. McCool, 3rd
  • Patent number: 3959193
    Abstract: A combination of an aryl sulfonamide-formaldehyde resin and film forming material, such as cellulose acetate butyrate, which may further include a surfactant, such as a non-ionic surfactant including, for example, an alkylarylpolyether, comprises a "universal" dispersant for resin additives, such as pigment materials. This composition generally includes 40 - 90 weight % of any of various types of additives, including pigments. The dispersant generally comprises from 30 - 80 weight % film former or binder, which may consist of cellulose acetate butyrate or a solid plasticizer, such as camphor, sucrose benzoate and dicyclohexylphthalate, and from 20 - 70 weight % of the aryl sulfonamide-formaldehyde resin. Apart from pigments, the additives may consist of fillers, extenders, etc., includng, for example, calcium carbonate, antimony oxide and magnesium silicate.
    Type: Grant
    Filed: March 12, 1973
    Date of Patent: May 25, 1976
    Assignee: PFD/Penn Color, Inc.
    Inventors: Edgar N. Putman, George Patterson, Scotty Wimer, John B. McCool, 3rd