Patents Assigned to Penn Color, Inc.
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Patent number: 11760873Abstract: White goniochromatic packaging article. The package wall containing a composition useful for blocking light in the spectrum ranges from about 200 nm to about 1200 nm. The composition has polyester, polymethylpentene, and a light scattering pigment. The composition optionally includes at least one other colorant. Each of the polymethylpentene and the light scattering pigment comprise about 0.1 to about 0.5 weight percent of the wall. The polyester and polymethylpentene are immiscible and when subjected to orientation stresses the composition produces a goniochromatic packaging article.Type: GrantFiled: December 27, 2018Date of Patent: September 19, 2023Assignee: Penn Color, Inc.Inventors: Kelan Wieloch, Venumadhava S. Eleswarapu, Scott Stamback, James C. Walsh, Fred Biemuller
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Publication number: 20220340703Abstract: The present disclosure generally related to photopolymerizable liquid compositions containing hybridized graft copolymers, reactive diluents and optionally oligomers, photoinitiators, colorants and other additives.Type: ApplicationFiled: September 25, 2020Publication date: October 27, 2022Applicant: Penn Color, Inc.Inventors: Namgoo Kang, Kenneth Myers, Andrew Sandt, Mark D. Adams, William C. Miles
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Patent number: 10647804Abstract: The present invention provides a process for producing a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink, coating or film that results in a excellent adhesion to metal or plastic substrates. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprising a functional vinylchloride-containing polymer portion having an average molecular weight of from 15,000 to 200,000 g/mole and at least one polymer portion selected from the group consisting of a functional polyolefin and a functional polysiloxane. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer.Type: GrantFiled: August 5, 2016Date of Patent: May 12, 2020Assignee: PENN COLOR, INC.Inventors: Michael D. Spiegel, Charles B. Rybny
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Patent number: 10023717Abstract: A method of forming a salt-containing carbon-metal particle, the method including forming an aqueous mixture of acidic carbon black and one or more metals and applying energy to the aqueous mixture, whereby applying energy to the aqueous mixture results in the metal chemisorbing to the acidic carbon black. The aqueous mixture may be prepared by preparing an aqueous dispersion of the acidic carbon black and adding metal particles in a zero oxidation state to the aqueous dispersion of the acidic carbon black; or dissolving a metal in a zero oxidation state in an acidic aqueous solution, preparing an aqueous dispersion of the acidic carbon black, and adding the aqueous dispersion of the acidic carbon black to the acidic aqueous solution of the dissolved metal. The acidic carbon black may be oxidized carbon black, and the metal may be zinc, aluminum, gold, iron, lead, silver, copper, or combinations thereof.Type: GrantFiled: March 4, 2015Date of Patent: July 17, 2018Assignee: PENN COLOR, INC.Inventors: Ronald W. Schuck, Charles B. Rybny
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Patent number: 9441123Abstract: The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.Type: GrantFiled: August 15, 2012Date of Patent: September 13, 2016Assignee: PENN COLOR, INC.Inventors: Michael D. Spiegel, Charles B. Rybny
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Patent number: 9434849Abstract: The present invention provides a durable, external surfactant free, anionic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable acid-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.Type: GrantFiled: October 17, 2013Date of Patent: September 6, 2016Assignee: PENN COLOR, INC.Inventors: Michael D. Spiegel, Charles B. Rybny
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Publication number: 20140113990Abstract: The present invention provides a durable, external surfactant free, anionic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable acid-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.Type: ApplicationFiled: October 17, 2013Publication date: April 24, 2014Applicant: PENN COLOR, INC.Inventors: Michael D. Spiegel, Charles B. Rybny
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Publication number: 20140051798Abstract: The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.Type: ApplicationFiled: August 15, 2012Publication date: February 20, 2014Applicant: PENN COLOR, INC.Inventors: Michael D. SPIEGEL, Charles B. RYBNY
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Patent number: 8652745Abstract: The present invention provides a process for producing a colored toner having a textured surface, the process includes forming a polymer composition of at least one polymer and a colorant, where the at least one polymer has a softening temperature from about 60° C. to about 160° C.; forming an aqueous mineral suspension of at least one multivalent metal phosphate; forming a dispersion by combining the polymer composition and the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition; heating the dispersion to a temperature above a glass transition temperature (Tg) of the polymer composition and increasing the pH to above 7.0; cooling the dispersion including the dispersed particles of the polymer composition to a temperature of from about 1° C. to about 89° C.; and recovering the particles.Type: GrantFiled: July 20, 2012Date of Patent: February 18, 2014Assignee: Penn Color, Inc.Inventors: Ronald W. Schuck, Charles B. Rybny, Choung Lai
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Publication number: 20130045441Abstract: The present invention provides a process for producing a colored toner having a textured surface, the process includes forming a polymer composition of at least one polymer and a colorant, where the at least one polymer has a softening temperature from about 60° C. to about 160° C.; forming an aqueous mineral suspension of at least one multivalent metal phosphate; forming a dispersion by combining the polymer composition and the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition; heating the dispersion to a temperature above a glass transition temperature (Tg) of the polymer composition and increasing the pH to above 7.0; cooling the dispersion including the dispersed particles of the polymer composition to a temperature of from about 1° C. to about 89° C.; and recovering the particles.Type: ApplicationFiled: July 20, 2012Publication date: February 21, 2013Applicant: PENN COLOR, INC.Inventors: Ronald W. SCHUCK, Charles B. RYBNY, Choung LAI
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Patent number: 8247155Abstract: The present invention provides a process for producing a colored toner comprising the steps of: providing a polymer composition comprising at least one polymer wherein the at least one polymer has a softening temperature from about 30° C. to about 160° C.; and a colorant; forming an aqueous mineral suspension of at least one multivalent metal phosphate by contacting a water-soluble salt of the multivalent metal with an aqueous solution comprising: a water-soluble phosphate salt; and at least one crystal growth inhibitor which controls the growth of the at least one multivalent metal phosphate, wherein the pH of the aqueous mineral suspension is from 5.5 to 14; and forming a dispersion of the polymer composition by adding the polymer composition to the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition, wherein the temperature of the aqueous mineral suspension during the dispersing step is at least about 70° C.Type: GrantFiled: January 15, 2009Date of Patent: August 21, 2012Assignee: Penn Color, Inc.Inventors: Choung Lai, Ronald W. Schuck, Charles B. Rybny
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Publication number: 20110159421Abstract: The present invention provides a process for producing a colored toner comprising the steps of: providing a polymer composition comprising at least one polymer wherein the at least one polymer has a softening temperature from about 30° C. to about 160° C.; and a colorant; forming an aqueous mineral suspension of at least one multivalent metal phosphate by contacting a water-soluble salt of the multivalent metal with an aqueous solution comprising: a water-soluble phosphate salt; and at least one crystal growth inhibitor which controls the growth of the at least one multivalent metal phosphate, wherein the pH of the aqueous mineral suspension is from 5.5 to 14; and forming a dispersion of the polymer composition by adding the polymer composition to the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition, wherein the temperature of the aqueous mineral suspension during the dispersing step is at least about 70° C.Type: ApplicationFiled: January 15, 2009Publication date: June 30, 2011Applicant: Penn Color, Inc.Inventors: Choung Lai, Ronald W. Schuck, Charles B. Rybny
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Patent number: 4176096Abstract: A novel, durable thermosetting acrylic automotive finish and method for manufacturing same is described which is manufactured from a predispersed, substantially dry composition. The resultant thermosetting acrylic finish has a higher pigment loading at a sprayable viscosity, thereby reducing the number of applications necessary to produce an acceptable automotive finish. In tests conducted by applicants, the described thermosetting acrylic automotive finish exhibits acceptable durability when exposed to solar radiation for extended periods of time.Type: GrantFiled: March 13, 1978Date of Patent: November 27, 1979Assignee: PFD/Penn Color, Inc.Inventors: George Patterson, Edgar N. Putman, John B. McCool, III
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Patent number: 4113650Abstract: A combination of an aryl sulfonamide-formaldehyde resin and film forming material, such as cellulose acetate butyrate, which may further include a surfactant, such as a non-ionic surfactant including, for example, an alkylarylpolyether, comprises a "universal" dispersant for resin additives, such as pigment materials. This composition generally includes 40-90 weight % of any of various types of additives, including pigments. The dispersant generally comprises from 30-80 weight % film former or binder, which may consist of cellulose acetate butyrate or a solid plasticizer, such as camphor, sucrose benzoate and dicyclohexylphthalate, and from 20-70 weight % of the aryl sulfonamide-formaldehyde resin. Apart from pigments, the additives may consist of fillers, extenders, etc., including, for example, calcium carbonate, antimony oxide and magnesium silicate.Type: GrantFiled: August 4, 1975Date of Patent: September 12, 1978Assignee: PFD/Penn Color, Inc.Inventors: Edgar N. Putman, George Patterson, Scotty Wimer, John B. McCool, 3rd
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Patent number: 3959193Abstract: A combination of an aryl sulfonamide-formaldehyde resin and film forming material, such as cellulose acetate butyrate, which may further include a surfactant, such as a non-ionic surfactant including, for example, an alkylarylpolyether, comprises a "universal" dispersant for resin additives, such as pigment materials. This composition generally includes 40 - 90 weight % of any of various types of additives, including pigments. The dispersant generally comprises from 30 - 80 weight % film former or binder, which may consist of cellulose acetate butyrate or a solid plasticizer, such as camphor, sucrose benzoate and dicyclohexylphthalate, and from 20 - 70 weight % of the aryl sulfonamide-formaldehyde resin. Apart from pigments, the additives may consist of fillers, extenders, etc., includng, for example, calcium carbonate, antimony oxide and magnesium silicate.Type: GrantFiled: March 12, 1973Date of Patent: May 25, 1976Assignee: PFD/Penn Color, Inc.Inventors: Edgar N. Putman, George Patterson, Scotty Wimer, John B. McCool, 3rd