Abstract: A crosslinked polyorganosiloxane is obtained from the free radical-initiated addition polymerization of polymerizable polyorganosiloxane containing at least two free radical polymerizable groups.

Abstract: The present invention relates to an addition-curable silicone rubber composition having self-bonding capability. The addition-curable silicone rubber composition exhibits self-bonding capability in particular to substrates that contain residual hydroxyl groups or other residual hydrosilyl-reacting groups on their surface, including polycarbonate, polyester, polyamide, polysulfone, polyurethane, phenolic resin, epoxy resin, cellulose, glass and the mixture thereof.

Abstract: There is provided herein an opaque one-part room temperature vulcanizing silicone polymer composition comprising: (a) a silanol-terminated diorganopolysiloxane, (b) an opaque reinforcing filler; (c) a polyalkoxysilane crosslinking agent; (d) a condensation cure catalyst; (e) an organo-functional alkoxy silane adhesion promoter; and, (f) a cyclic siloxane. There is also provided a method for the continuous production of such a silicone polymer composition, and a paint containing such a silicone polymer composition.

Abstract: There is provided herein an elastomeric coating composition containing (a) at least one condensation polymerization-effective polymer bearing two or more silicon atoms; (b) a surface wetting agent, (c) a filler; (d) a condensation catalyst; and, (e) optionally, one or more crosslinking agents. There are also provided architectural coatings including the same, as well as single coat anti-dirt, and/or anti-stain, and/or anti-fouling coatings including the same.

Abstract: A method of stabilizing imino-functional silane involving adding thereto at least one Brønsted-Lowry base to inhibit, suppress or prevent the addition reactions of the imino-functional silane with itself to form a imino- and amino-functional silane and the subsequent deamination reactions to form conjugated carbon-carbon double bond-containing imino-functional silanes and stabilized imino-functional silanes containing the at least one Brønsted-Lowry base.

Abstract: A light emitting diode assembly comprising such thermal management assembly is shown and described herein. The light emitting diode assembly may comprise a light emitting diode in thermal contact with a heat spreader. The heat spreader may comprise a core and/or fins. The core and/or fins comprise a thermal pyrolytic graphite material. The thermal management assembly comprising the core and/or fins can dissipate heat from the light emitting diode.

Abstract: There is provided novel mono-acrylate functionalized siloxane monomer containing carbosiloxane linkage for improved hydrolysis resistance. This invention also provides copolymers produced using these monomers and their use in various applications.

Abstract: A curable composition comprising (A) an organopolysiloxane comprising a curable functional group; and (B) a silicone-free, organic material comprising a reactive functional group. The curable composition exhibits high refractive index and optical clarity. The curable composition can be used to prepare a cured material that exhibits high refractive index, optical clarity, crack resistance, and low moisture vapor permeability.

Abstract: The method includes the steps of functionalizing a polyaryletherketone (PAEK) polymer, and blending the PAEK polymer with water to form a sizing composition. The method may further include the step of applying the sizing composition to a fiber. The method may further include the step of heating the fibers, coated with sizing composition, for example to between 300C-400C. In some methods, the functionalized PAEK polymer comprises functionalized polyetherketoneketone (PEKK). In yet other methods, the functionalized PAEK polymer comprises sulfonated PEKK (sPEKK).

Abstract: A transport puck vertically aligns a caulking cartridge, nozzle-down. The puck includes (i) a substantially solid lower plug portion, having a lead face and a bottom face and an center passageway that is at least partially inverted frustum-shaped that forms a side contact face that tapers from a wider lead face opening to a narrower bottom face opening; and or to a tubular sleeve from the side contact face to the bottom face opening; (ii) an upper sleeve, shaped to receive the caulking cartridge in a desired vertical alignment to the lower plug portion; and (iii) at least one funnel-shaped bore into the bottom face with an inserted connector comprising a head and stem, the head spaced within the bore to define a spacing that has been determined to identify bottom face wear.

Abstract: A thermally conductive silicone composition is shown and described herein. The thermally conductive silicone composition comprises (A) an ionically modified siloxane, and (B) a thermally conductive filler comprising a first filler and a second filler, where the first filler and/or the second filler comprises a plurality of filler types, the plurality of filler types differing from one another in terms of particle size and/or morphology. The ionically modified siloxane may function as a dispersing aid or wetter for efficient dispersion of thermal conducting organic and inorganic fillers to achieve high thermal conductivity.

Abstract: A continuous process for preparing a silylated polymer comprising a silylation step where a prepolymer having reactive functional groups, a first intermediate product, is reacted continuously with a silylating agent in an endcapping tubular reaction unit to form a second intermediate product, and where at least a portion of the second intermediate product is backmixed continuously with the first intermediate product to form the silylated polymer. The continuous process may further comprise a stabilization step, a quenching step or both a stabilization step and a quenching step.

Abstract: A transesterification process for preparing alkoxysilane includes removal of metal transesterification catalyst from the alkoxysilane transesterification reaction medium.

Abstract: A curable composition comprising (a) an organopolysiloxane comprising a curable functional group; (b) a cross-linker comprising a silyl hydride group or a thiol group; (c) a reaction accelerator; (d) optionally an inhibitor; and (e) optionally other additives. The curable composition exhibits high refractive index and optical clarity. The curable composition can be used to prepare a cured material that exhibits high refractive index, optical clarity, crack resistance, and low moisture vapor permeability.

Abstract: A functionalized siloxane includes a ligand capable of coordinating a metal. The functionalized siloxane includes a pyridine-containing ligand attached to a siloxane polymer. The functionalized siloxanes can be employed to provide complexes including a metal that may impart a desired property to the polymer. In one embodiment, the polymer can complex lanthanide metals that are capable of phosphorescing upon exposure to UV irradiation. Such polymers can be employed to provide functional materials such as, for example, luminescent films, coatings, etc.

Abstract: There is provided herein a method of preparing an isocyanatosilane including reacting an olefinic isocyanate with a hydridosilane in the presence of a dinuclear rhodium complex under hydrosilylation conditions.

Abstract: A flame-retarded resin includes at least one resin for which flame retardant capability is desired and at least one triaryl silicon-containing compound (I) as flame retardant in admixture therewith and/or chemically bonded, e.g., grafted, to the resin.

Abstract: A heater assembly is disclosed herein. The heater assembly may comprise a tubular body. The tubular body may include a graphite core disposed in a heating path. The graphite core may be coated with an overcoat layer. The tubular body may include slits that may cut-off heat transfer between portions of the tubular body. The heater assembly may have a configuration comprising a plurality of heating rungs having a predominant portion disposed substantially perpendicular to an upper surface of the heater so that the predominant portion is disposed vertically. The heater assembly may include a flange at a first end and a lip at a second end. The heater assembly configuration provides a heater that exhibits reduced thermal stress and/or reduced CTE mismatch stress particularly compared to other designs.

Abstract: There is provided herein a low foam surfactant composition comprising: (a) di-trisiloxane alkoxylate component of the general formula (I): (R1R2R3SiO)2(R4)Si—R5—Si(R6)(OSiR7R8R9)2??(I); and, (b) mono-trisiloxane alkoxylate component of the general formula (II): (R12R13R14SiO)2Si(R15)R16??(II) wherein di-trisiloxane alkoxylate (I) is soluble in mono-trisiloxane alkoxylate and methods of making the same.

Abstract: The present invention provides a polyorganosiloxane compound having a low viscosity, a process for the manufacture of such polyorganosiloxane compounds, polyorganosiloxane compositions comprising said polyorganosiloxane compound and another polyorganosiloxane compound which is different from the polyorganosiloxane compound, aqueous emulsions comprising the polyorganosiloxane compound, and a method of surface treatment using the polyorganosiloxane compound.