Abstract: Chlorine is generated by electrolyzing aqueous alkali metal chloride in a cell wherein the anode and cathode are separated by and in contact with an ion exchange diaphragm and wherein the anode and/or cathode contains particles of an electroconductive catalytic material along with particles of an electroconductive extender bonded to the membrane.
Type:
Grant
Filed:
July 27, 1988
Date of Patent:
September 11, 1990
Assignee:
Oronzio de Nora Permelec S.p.A.
Inventors:
Russell M. Dempsey, Thomas G. Coker, Anthony B. LaConti, Anthony R. Fragala
Abstract: The present invention concerns a method for preparing electrodes for use in electrochemical processes, said electrodes being constituted by a conductive support whereto an electrocatalytic coating is applied by galvanic deposition from a galvanic plating bath which additionally contains the groups IB, IIB, IIIA, IVA, VA, VB, VIB, VIII Of the periodic table.The electrodes of the invention, obtainable according to the method of the invention, when used as cathodes in membrane or diaphragm chlor-alkali cells, exhibit low hydrogen overvoltages, constant with time, and are substantially immune to poisoning by iron, mercury or other metal impurities present in the alkaline solutions.
Abstract: A dimensionally stable anode for high-speed galvanizing processes comprising a plurality of substantially parallel, foraminous layers, in electrical contact with each other, each layer comprising an inert, electroconductive substrate with an oxygen evolving electrocatalytic coating, characterized in that the current density of each individual layer is substantially the same and does not exceed the value corresponding to the minimum desired lifetime of the anode. The number of layers is sufficient to provide the total current density required for the high-speed galvanizing. The anode further comprises spacers suitable for preventing short-circuits.
Type:
Grant
Filed:
December 16, 1987
Date of Patent:
May 9, 1989
Assignee:
Permelec S.p.A.
Inventors:
Carlo Traini, Tomaso Leone, Renato Schira