Patents Assigned to PetroChina Company Limited
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Patent number: 9874089Abstract: A bridge concentric direct-reading testing and adjusting instrument, comprising a cable head connected to a pressure sensor; a supporting mechanism having a pair of supporting arms; a sliding power mechanism including a power motor, a spring, an impact hammer and a one-way clutch assembly, the impact hammer slidably connected to the power motor to be rotated along with rotation of the power motor, a lower end of the impact hammer detachably connected to the one-way clutch assembly, and the one-way clutch assembly connecting the supporting arms via a transmission assembly to control opening and closing of the supporting arms; a flowmeter; and an adjusting actuator including an adjusting motor, an adjusting connector and an adjusting arm, the adjusting arm used for adjusting a waterflooding flow rate through rotation of the adjusting arm.Type: GrantFiled: June 6, 2013Date of Patent: January 23, 2018Assignee: Petrochina Company LimitedInventors: He Liu, Xiaohan Pei, Fuchao Sun, Lichen Zheng, Qinghai Yang, Yang Gao
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Patent number: 9856413Abstract: The present invention relates to viscoelastic fracturing fluids comprising one or more zwitterionic surfactants having multiple hydrophobic and hydrophilic groups. The viscoelastic fracturing fluids can be used to stimulate reservoir and increase oil and gas production.Type: GrantFiled: September 6, 2013Date of Patent: January 2, 2018Assignee: Petrochina Company LimitedInventors: Jiang Yang, Yongjun Lu, Baoshan Guan, Weixiang Cui, Xiaohui Qiu
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Patent number: 9844772Abstract: The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination.Type: GrantFiled: April 13, 2012Date of Patent: December 19, 2017Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Patent number: 9840422Abstract: The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: GrantFiled: April 13, 2012Date of Patent: December 12, 2017Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Chaowei Liu, Di Li, Xueli Li, Zhengguo Tan, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Chenxi Zhang
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Patent number: 9828831Abstract: A bridge concentric continuously adjustable water regulator comprising: an outer tube; an adjusting sleeve disposed in the outer tube; a concentric valve connected below the adjusting sleeve, with a center of circle of the concentric valve being concentric to the outer tube; a water outlet which runs through a side wall of the outer tube and is connected to the concentric valve; a lower sealed section which is disposed in the outer tube and is below the concentric valve and the water outlet; and a bridge passage disposed in the side wall of the outer tube and outside the concentric valve and the lower sealed section.Type: GrantFiled: June 6, 2013Date of Patent: November 28, 2017Assignee: PETROCHINA COMPANY LIMITEDInventors: He Liu, Xiaohan Pei, Fuchao Sun, Lichen Zheng, Qinghai Yang, Yang Gao
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Patent number: 9789475Abstract: The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: GrantFiled: April 13, 2012Date of Patent: October 17, 2017Assignee: Petrochina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Patent number: 9739134Abstract: The present application provides a method for characterizing reservoir micro pore structures, in particular structures smaller than 50 nm and a system therefore. The method can include fabricating a reservoir sheet; fabricating a reservoir sheet electrode using the reservoir sheet; depositing crystal substance in inner pores of the reservoir sheet of the reservoir sheet electrode using chemical deposition; obtaining the crystal substance by removing rock portions of the reservoir sheet in which the crystal substance is deposited; and scanning the shapes of the obtained crystal substance, the result of the scanning being the reservoir micro pore structure.Type: GrantFiled: June 24, 2015Date of Patent: August 22, 2017Assignee: PETROCHINA COMPANY LIMITEDInventors: Jianming Li, Xu Jin, Xiaoqi Wang
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Patent number: 9695257Abstract: The present invention relates to preparation and application of an olefin polymerization catalyst. The main catalyst is composed of a carrier, a transition metal halide, and an organic alcohol compound. The transition metal halide is obtained by in-situ reaction between titanate and silicon halide. The molar ratio of the carrier to the transition metal halide to the organic alcohol compound is 1 to 0.01-20 to 0.1-6. The molar ratio of the titanate to the silicon halide is 1 to 0.5-2. The co-catalyst is an organo-aluminum compound. The molar ratio of the transition metal halide in the main catalyst to the co-catalyst is 1 to 30-500. Particles of the catalyst are good in morphology and are in a spherical shape. The catalyst has high activity and the polymer obtained by using the catalyst has a high molecular weight. The catalyst is applicable to a slurry method, a vapor phase polymerization process, or a combined polymerization process.Type: GrantFiled: July 11, 2013Date of Patent: July 4, 2017Assignee: Petrochina Company LimitedInventors: Jianjun Yi, Qigu Huang, Hongming Li, Mingge Zhang, Zhi Liu, Wei Liu, Yisen Wang, Weisong Cui
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Patent number: 9625601Abstract: The present invention relates to a constant gradient field nuclear magnetic resonance (NMR) rock sample analysis method and instrument.Type: GrantFiled: September 28, 2011Date of Patent: April 18, 2017Assignee: PETROCHINA COMPANY LIMITEDInventors: Wei Liu, Wei Sun, Zhaobin Gu, Dianqing Sun
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Patent number: 9611435Abstract: The present invention relates to a method for the selective hydrogenation of an unsaturated compound, particularly a method in an unsaturated compound or a mixture containing unsaturated compounds for increase of the light sulphides weight, hydrogenation of a polyunsaturated compound and isomerization of a monounsaturated compound. The method uses a supported catalyst. The supported catalyst contains at least one Group VIB non-noble metal oxide and at least one Group VIII non-noble metal oxide deposited on a carrier; and the catalyst has an optimized acid distribution on the surface of the catalyst, and more preferably has an optimized Group VIII/VIB metal ratio and a Group VIII non-noble metal density per unit of catalyst surface area.Type: GrantFiled: November 8, 2012Date of Patent: April 4, 2017Assignee: Petrochina Company LimitedInventors: Xuejun Zhang, Guanjing Wu, Pingyi Wu, Xiaoliang Yuan, Yuandong Hou, Yin Zhang, Qinfeng Zhao, Shuqin Wang, Kunhong Liu
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Patent number: 9605531Abstract: An intelligent test system and a method for a multi-segment fractured horizontal well. The intelligent test method for a multi-segment fractured horizontal well comprises: step A: placing a test tubular column into an underground horizontal section; step B: setting a pressure building packer and a hanging packer by means of pressurization after the test tubular column is placed into an underground designed position; step C: breaking a hydraulic release connector to separate the hydraulic release connector from a seal pipe; step D: pulling out a first oil pipe, and reserving the tubular column comprising the seal pipe and located on the downstream part of the seal pipe in a horizontal well; and step E: placing a production tubular column or a communications tubular column into a vertical section of the horizontal well.Type: GrantFiled: September 17, 2015Date of Patent: March 28, 2017Assignee: Petrochina Company LimitedInventors: Hong Xin, Tianshou Zhu, Lijun Mu, Wei Huang, Ming Li, Qingming Gan, Haitao Yang, Lei Zhang, Ertao Han
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Patent number: 9597668Abstract: A selective nickel-based hydrogenation catalyst and the preparation thereof, characterized in that: provided that the catalyst is weighed 100%, it comprises nickel oxide 14-20% as active component, lanthanum oxide and/or cerium oxide 2-8%, and VIB element oxide 1-8% as aids, 2-8% silica, 1-8% alkaline earth metal oxides, and alumina as the balance. The catalyst specific surface area is 60-150 m2/g, and the pore volume is 0.4-0.6 ml/g. The catalyst has good hydrogenation performance, especially impurity and colloid resistance and hydrogenation stability. The catalyst can be applied to the diolefin selective hydrogenation of medium or low-distillate oil, especially of the full-distillates pyrolysis gasoline.Type: GrantFiled: August 11, 2014Date of Patent: March 21, 2017Assignee: PETROCHINA COMPANY LIMITEDInventors: Shunqin Liang, Ying Qian, Longgang Lv, Limin Sun, Yundi Zheng, Tinghai Wang, Jie Wu, Fengxia Cao
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Patent number: 9540559Abstract: Betaine surfactants of formula (I) and preparation methods and uses thereof are provided. The surfactant can decrease the interfacial surface tension of crude oil till 10?3 mN/m, have the capabilities of antiheating (130° C.), antimineralizing and antidiluting, and can be used in the field of tertiary oil recovery.Type: GrantFiled: March 11, 2011Date of Patent: January 10, 2017Assignee: PETROCHINA COMPANY LIMITEDInventors: Chunde Liu, Shiyi Yuan, Demin Wang, Xinmin Song
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Patent number: 9534178Abstract: A hydrogenation method and distillate two-phase hydrogenation reactor in which the size of an upper space of the reactor is greater than that of a lower catalyst bed part. The reactor comprises 2 to 4 catalyst beds. An inner component for gas replenishment and for stripping a liquid-phase stream containing impurities is arranged between at least one adjacent catalyst bed and comprises a separator plate and exhaust pipes. The separator plate is provided with multiple downcomer through holes. The separator plate is connected with a plurality of exhaust pipes. The exhaust pipes are vertically arranged above the separator plate. The top parts of the exhaust pipes are in contact with the lower part of the upper catalyst bed.Type: GrantFiled: August 1, 2013Date of Patent: January 3, 2017Assignee: PETROCHINA COMPANY LIMITEDInventors: Shoutao Ma, Ran Tian, Zhihua Zhang, Gang Wang, Famin Sun, Ruiqin Zhang, Chunmei Yu, Shengbo Sun, Xiufang Feng, Fengxuan Li, Jinling Zhu
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Patent number: 9493399Abstract: The present invention relates to a multi-branched Mannich base corrosion inhibitor and the method for preparing thereof. The method comprises (1) adding 3˜7 moles ketone and 3˜7 moles aldehyde to reaction kettle, adjusting pH to 2˜6 with acid, controlling temperature to 20˜50° C. and stirring for 20˜30 mins; (2) adding 1 mole organic polyamine to the reaction kettle under stirring, or adding the pH-adjusted ketone, aldehyde and organic solvent to organic polyamine, controlling temperature to 60˜90° C. and reacting for 1˜3 hrs, and after completion of the reaction, heating the system to 110° C. under nitrogen to remove water; the organic polyamine is organic compound comprising three or more primary amine groups and/or secondary amine groups.Type: GrantFiled: April 27, 2012Date of Patent: November 15, 2016Assignee: PETROCHINA COMPANY LIMITEDInventors: Ling Ma, Lei Li, Xiangjun Kong, Malike Dilibai, Xinping Zhen, Chunge Niu, Shengjun Bai
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Publication number: 20160297776Abstract: The present invention provides a mercaptotriazole-based drag-reducing agent for gas pipelines and its preparation method. The drag-reducing agent is prepared by the following steps: producing 1,3-diaminothiourea from hydrazine hydrate and carbon disulfide in a mass ratio of 3:1 to 4:1 under the action of Catalyst I; producing a dithiocarbohydrazone from the condensation reaction of 1,3-diaminothiourea and an aromatic aldehyde in a mass ratio of 1:1 to 1:1.5; producing a mercaptotriazole compound from the dithiocarbohydrazone and an aromatic ester in a mass ratio of 1:1 to 1:3 under the action of Catalyst II; dissolving the mercaptotriazole compound in acetone, adding phosphoric acid or phosphate(s) thereto, and thoroughly mixing them to obtain the target product. The present invention has simple operation and mild reaction conditions and is suitable for online atomization and injection, and the raw materials thereof are available from direct sources.Type: ApplicationFiled: November 7, 2014Publication date: October 13, 2016Applicant: PetroChina Company LimitedInventors: Guoping LI, Zhiheng ZHANG, Muyang AI, Guangwen LIU, Weichun CHANG, Haifeng GUO, Haihong XU, Cheng LIU, Shaoyu LI
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Patent number: 9440227Abstract: A method for preparing catalyst coating on a metal base plate comprising: thermal-spraying a layer of ?-aluminum oxide nano-particles on a metal base plate using a high temperature flame powder spray gun, at a temperature of 2500-3500° C. and a pressure of 0.2-1.2 MPa; coating an aluminum sol, the weight concentration of the aluminum sol aqueous solution being 2-30%, at a pH of 0.5-4, the drying temperature being 50-150° C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200° C., and the calcination time being 0.5-24 hours; immersing in an active component, the immersing temperature being 20-120° C., the duration being 0.5-24 hours, the drying temperature being 50-150° C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200° C., and the calcination time being 0.5-24 hours. The method is suitable for the preparation of various catalyst coatings with active components.Type: GrantFiled: November 28, 2011Date of Patent: September 13, 2016Assignees: Petrochina Company Limited, Tsinghua UniversityInventors: Zhongtao Zhang, Yi Cheng, Xuli Zhai, Yong Jin, Jianzhong Li, Guizhi Wang, Zhixiang Zhang, Huimin Yuan, Fengrong Wang, Xianming Xu, Shubao Wan, Fangwei Li, Fengbo Ma, Jing Wei, Jina Zhao, Lijun Liu, Dawei Zhang
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Patent number: 9427721Abstract: A cool hydrogen-propelled cyclone quench box comprises: a mixing chamber (7) arranged at the center of a lower support plate (11); swirl tubes (6) arranged above the lower support plate (11) and outside the mixing chamber (7), the tubes being in tangential communication with the body of the mixing chamber (7) along a horizontal direction; a gas-liquid downcomer (5) perpendicularly arranged outside each swirl tube (6), the bottom portions of the downcomers and the outer walls of the swirl tubes (6) being in tangential communication along a perpendicular direction, and the top portions of the gas-liquid downcomers (5) being connected to fluid inlets (4) arranged on an upper support plate (3). The bottom end of a cool hydrogen branch pipe (8) is arranged outside each swirl tube (6), and is tangentially connected to the swirl tube (6) along a horizontal direction.Type: GrantFiled: June 15, 2012Date of Patent: August 30, 2016Assignees: PetroChina Company Limited, CNPC East China Design InstituteInventors: Zhenmin Cheng, Shengshan Li, Xuehua Li, Guoqi Wang, Zhenyuan Wang, Zibin Huang, Jun Zhu, Yu Long, Xiaobo Liu, Kun Yu, Hongying Wang
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Patent number: 9422486Abstract: The present invention relates to a selective hydrogenation catalyst for an unsaturated compound. The supported catalyst contains at least one Group VIB non-noble metal oxide and at least one Group VIII non-noble metal oxide deposited on a carrier; and the catalyst has an optimized acid distribution on the surface of the catalyst, and more preferably has an optimized Group VIII/VIB metal ratio and a Group VIII non-noble metal density per unit of catalyst surface area. Using the catalyst of the present invention can have the following advantages: the weight increase of light sulphides in an unsaturated compound or a mixture containing unsaturated compounds, the hydrogenation of a polyunsaturated compound, the isomerization of a monounsaturated compound, high operation flexibility and a significant improvement in the effects of a hydrogenation treatment.Type: GrantFiled: November 8, 2012Date of Patent: August 23, 2016Assignee: PetroChina Company LimitedInventors: Xuejun Zhang, An Ma, Xiaoliang Yuan, Yuandong Hou, Honglei Sun, Pingyi Wu, Yin Zhang, Jiarui Piao
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Patent number: 9421533Abstract: A catalyst for synthesizing 1-hexene from ethylene trimerization and its application are provided. Said catalyst consists of (a) the compound containing P and N, (b) electron donor, (c) Cr compound, (d) carrier and (e) accelerator. The molar ratio of (a), (b), (c), (d) and (e) is 0.5-100:0.5-100:1:0.5-10:50-5000. The catalyst is prepared by mixing the components of (a)-(e) in an ethylene trimerization apparatus in situ and ethylene is introduced into the apparatus continuously. The prepared catalyst can be used to synthesize 1-hexene from ethylene trimerization in the inert solvents. The trimerization is performed at 30-150° C. and 0.5-10.0 MPa for 0.1-4 hours. The catalyst has high catalytic activity and high 1-hexene selectivity. During the process of ethylene trimerization, by-product polyethylene does not stick to the apparatus.Type: GrantFiled: July 22, 2010Date of Patent: August 23, 2016Assignee: PETROCHINA COMPANY LIMITEDInventors: Gang Wang, Sihan Wang, Zhonghua Yang, Jiabo Qu, Baojun Zhang, Qian Chen, Deshun Zhang, Libo Wang, Yali Wang, Buwei Yu, Xiuhui Wang, Fuling Huang, Xuemei Han, Dongmei Niu, Shukun Sun, Wenchao Zhang, Hua Li, Gongchen Yan