Abstract: A process for the preparation and modification of additives, with a zeolite base and a high silica alumina ratio (SAR) like the ZSM-5, to increase the yield of propene and LPG in low severity FCC operations, that seeks to maximize the production of medium-distillates with low aromaticity and to minimize molecular cracking in the LCO range. The additives involved guarantee an increase in light olefin yields without altering the yield or the quality of the LCO produced. The innovative process includes surprising actions from rare earths (RE) on the active sites of zeolite, that at once partially block their pores and, in this way, make molecular cracking in the medium-distillate range difficult, which preferably occur at low reaction temperatures and keeps the remaining sites quite active.
Type:
Grant
Filed:
March 6, 2007
Date of Patent:
April 6, 2010
Assignee:
Petroleo Basileiro S.A. - Petrobras
Inventors:
Lam Yiu Lau, Raquel Bastiani, Claudia Maria de Lacerda Alvarenga Baptista