Patents Assigned to Petroleum Fermentations
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Patent number: 4943390Abstract: Methods and compositions are provided to facilitate the transportation and combustion of highly viscous hydrocarbons by forming reduced viscosity hydrocarbon-in-water emulsions, and in particular, bioemulsifier-stabilized hydrocarbon-in-water emulsions.Type: GrantFiled: September 28, 1988Date of Patent: July 24, 1990Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Kevin R. Hrebenar, Patricia L. Murphy, Laurence E. Futch, Jr., James F. Deal, III, Paul L. Bolden, Jr.
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Patent number: 4934391Abstract: Methods and compositions are provided for the removal of soldering flux, screen inks and resists from contaminated surfaces. The compositions of the invention contain dibasic acid esters in combination with an appropriate emulsifying surfactant.Type: GrantFiled: February 2, 1989Date of Patent: June 19, 1990Assignee: 501 Petroleum Fermentations N.V.Inventors: Larry Futch, Kevin R. Hrebenar, Michael E. Hayes
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Patent number: 4886519Abstract: This invention relates to the reduction of oxidized sulfur compound (SOX) emissions produced during combustion of sulfur (S)-containing combustible compounds. More particularly, this invention provides a method for reducing such emissions wherein the combustible compound is mixed with an admixture of a water soluble and a water insoluble sulfur sorbent. Use of such admixtures, remarkably, produces a reduction in the SOX level far greater than would be expected based on the activity of each sorbent alone. Extremely viscous hydrocarbons can be burned as preatomized fuels, which can also be mixed with sorbent admixtures. Clean burning fuels comprising sulfur-containing combustible compounds and sorbent admixtures are also provided.Type: GrantFiled: April 23, 1987Date of Patent: December 12, 1989Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Kevin R. Hrebenar, Jennifer L. Minor, Lawrence M. Woodworth
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Patent number: 4883757Abstract: Methods and compositions are provided for the preparation and use of new nondialyzable, interfacially-active bioemulsifiers from Acinetobacter calcoaceticus strains.Type: GrantFiled: November 24, 1987Date of Patent: November 28, 1989Assignee: Petroleum Fermentations N.V.Inventors: David L. Gutnick, Eirik Nestaas, Eugene Rosenberg, Nechemia Sar
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Patent number: 4870010Abstract: Personal care products comprising bioemulsifiers, for example, those produced by Acinetobacter calcoaceticus, are provided. Use of such personal care products result in beneficial effects to skin and hair.Type: GrantFiled: April 15, 1986Date of Patent: September 26, 1989Assignee: Petroleum Fermentations N.V.Inventor: Michael E. Hayes
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Patent number: 4821757Abstract: Methods and compositions are provided to facilitate the transportation and combustion of highly viscous hydrocarbons by forming reduced viscosity hydrocarbon-in-water emulsions, and in particular, bioemulsifier-stabilized hydrocarbon-in-water emulsions.Type: GrantFiled: June 23, 1987Date of Patent: April 18, 1989Assignee: Petroleum Fermentations N. V.Inventors: Michael E. Hayes, Kevin R. Hrebenar, Patricia L. Murphy, Laurence E. Futch Jr., James F. Deal III, Paul L. Bolden Jr.
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Patent number: 4818817Abstract: Methods and compositions are provided for the production and use of enzymes that degrade lipopolysaccharide bioemulsifiers, and, in particular, emulsans. The enzymes may be used to demulsify bioemulsifier-stabilized hydrocarbon-in-water emulsions.Type: GrantFiled: May 15, 1987Date of Patent: April 4, 1989Assignee: Petroleum Fermentations N.V.Inventors: Yuval Shoham, Eugene Rosenberg, David L. Gutnick
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Patent number: 4793826Abstract: Methods and compositions are provided to facilitate the transporation and combustion of highly viscous hydrocarbons by forming reduced viscosity hydrocarbon-in-water emulsions, and in particular, bioemulsifier-stabilized hydrocarbon-in-water emulsions.Type: GrantFiled: September 27, 1985Date of Patent: December 27, 1988Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Kevin R. Hrebenar, Patricia L. Murphy, Laurence E. Futch, Jr., James F. Deal, III, Paul L. Bolden, Jr.
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Patent number: 4770711Abstract: A method utilizing a portable hydraulic apparatus for cleaning the hydrocarbon contaminated sludge deposit of an oil storage tank with a fluidizing agent, the tank having a floor, a side wall and a passageway through the side wall positioned adjacent the floor of the tank, comprises a frame having a central portion and first and second end portions. The frame is configured and dimensioned to pass through the passageway. A pair of independently movable endless chain belts are position on opposite sides of the frame for selectively moving the frame within the oil storage tank to selected locations. A hydraulic line coupled to the central portion of the frame discharges the fluidizing agent onto an adjacent first portion of the sludge deposit so as to form a pool of sludge and fluidizing agent. A suction pump is positioned on the central portion of the frame for drawing up the pool of sludge and fluidizing agent.Type: GrantFiled: August 24, 1984Date of Patent: September 13, 1988Assignee: Petroleum Fermentations N.V.Inventors: James F. Deal, III, Anderson M. Foote, III, Stephen R. Gabbard
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Patent number: 4740247Abstract: Methods and compositions are provided for the removal of rosin soldering flux and adhesive tape residues from printed circuit and/or wiring boards, and for testing the quality of curing of U.V.-cured soldermask on such boards. The compositions of the invention contain terpene compounds, preferably in combination with terpene emulsifying surfactants to facilitate removal by rinsing in water.Type: GrantFiled: June 24, 1986Date of Patent: April 26, 1988Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Craig C. Hood, Ronald E. Miller, Robert Sharpe
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Patent number: 4706749Abstract: A non-thermal, chemical "huff and puff" method for improved oil recovery is provided in which surfactant/cosurfactant/brine mixtures are used to recover viscous and other hydrocarbons from single wells.Type: GrantFiled: November 6, 1984Date of Patent: November 17, 1987Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Gary R. Hass, Robert Sharpe, Eirik Nestaas, Mikhail V. Ostrovsky
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Patent number: 4704360Abstract: Methods and compositions are provided for the production and use of enzymes that degrade lipopolysaccharide bioemulsifiers, and, in particular, emulsans. The enzymes may be used to demulsify bioemulsifier-stabilized hydrocarbon-in-water emulsions.Type: GrantFiled: November 30, 1983Date of Patent: November 3, 1987Assignee: Petroleum FermentationsInventors: Yuval Shoham, Eugene Rosenberg, David L. Gutnick
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Patent number: 4684372Abstract: Methods and compositions are provided to facilitate the transportation and combustion of highly viscous hydrocarbons by forming reduced viscosity hydrocarbon-in-water emulsions, and in particular, bioemulsifier-stabilized hydrocarbon-in-water emulsions.Type: GrantFiled: September 24, 1984Date of Patent: August 4, 1987Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Kevin R. Hrebenar, Patricia L. Murphy, Laurence E. Futch, Jr., James F. Deal, III, Paul L. Bolden, Jr.
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Patent number: 4666457Abstract: Methods and composition are provided to facilitate the utilization of highly viscous hydrocarbons as clean burning fuels.Type: GrantFiled: October 15, 1985Date of Patent: May 19, 1987Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Kevin R. Hrebenar, James F. Deal, III, Paul L. Bolden, Jr.
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Patent number: 4640719Abstract: Methods and compositions are provided for the removal of rosin soldering flux and adhesive tape residues from printed circuit and/or wiring boards, and for testing the quality of curing of U.V.-cured soldermask on such boards. The compositions of the invention contain terpene compounds, preferably in combination with terpene emulsifying surfactants to facilitate removal by rinsing in water.Type: GrantFiled: July 1, 1985Date of Patent: February 3, 1987Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Craig C. Hood, Ronald E. Miller, Robert Sharpe
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Patent number: 4618348Abstract: Methods and compositions are provided to facilitate the transporation and combustion of highly viscous hydrocarbons by forming reduced viscosity hydrocarbon-in-water emulsions, and in particular, bioemulsifier-stabilized hydrocarbon-in-water emulsions.Type: GrantFiled: November 2, 1983Date of Patent: October 21, 1986Assignee: Petroleum Fermentations N.V.Inventors: Michael E. Hayes, Kevin R. Hrebenar, Patricia L. Murphy, Laurence E. Futch, Jr., James F. Deal, III
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Patent number: 4592786Abstract: An apparatus and process adapted to clean oil contaminated vessels which uses a closed fluidized system through which fluidized sludge is recirculated to be sprayed under pressure on interior walls of the vessel. Emulsifying agents are added to the vessel to initially form a pool of fluidized sludge in the vessel which is then conveyed to a tank and from the tank conveyed to a high pressure spray where it is sprayed onto the walls to fluidize more sludge.Type: GrantFiled: October 26, 1984Date of Patent: June 3, 1986Assignee: Petroleum Fermentations N.V.Inventors: Joseph L. Williams, John W. Sansing, Michael E. Hayes, James F. Deal
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Patent number: 4395353Abstract: Growth of Acinetobacter Sp. ATCC 31012 on various substrates and under varying conditions has been used to produce two classes of extracellular microbial protein-associated lipopolysaccharides (the "emulsans") which, on a weight-for-weight basis, are probably the most efficient emulsifiers discovered and which possess certain characteristics that permit these unique extracellular microbial lipopolysaccharides to be widely used in cleaning oil-contaminated vessels, oil spill management, and enhanced oil recovery by chemical flooding. Emulsans and apoemulsans, both of which biopolymers are strongly anionic, exhibit a high degree of specificity in the emulsification of hydrocarbon substrates which contain both aliphatic and cyclic components. In addition, these extracellular microbial polysaccharides as well as their O-deacylated and N-deacylated derivatives are adsorbed on and capable of flocculating aluminosilicate ion-exchangers, such as kaolin and bentonite.Type: GrantFiled: May 14, 1980Date of Patent: July 26, 1983Assignee: Petroleum Fermentations N.V.Inventors: David L. Gutnick, Eugene Rosenberg, Igal Belsky, Zosim Zinaida
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Patent number: 4395354Abstract: Growth of Acinetobacter Sp. ATCC 31012 on various substrates and under varying conditions has been used to produce two classes of extracellular microbial protein-associated lipopolysaccharides (the "emulsans") which, on a weight-for-weight basis, are probably the most efficient emulsifiers discovered and which possess certain characteristics that permit these unique extracellular microbial lipopolysaccharides to be widely used in cleaning oil-contaminated vessels, oil spill management, and enhanced oil recovery by chemical flooding. These classes have been named .alpha.-emulsans and .beta.-emulsans, both of which have substantially the same polymer backbone but differ from each other in certain important structural aspects. Emulsans and apoemulsans, both of which biopolymers are strongly anionic, exhibit a high degree of specificity in the emulsification of hydrocarbon substrates which contain both aliphatic and cyclic components.Type: GrantFiled: July 17, 1980Date of Patent: July 26, 1983Assignee: Petroleum Fermentations N.V.Inventors: David L. Gutnick, Eugene Rosenberg, Igal Belsky, Zosim Zinaida
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Patent number: 4380504Abstract: Growth of Acinetobacter Sp. ATCC 31012 on various substrates and under varying conditions has been used to produce two classes of extracellular microbial protein-associated lipopolysaccharides (the "emulsans") which, on a weight-for-weight basis, are probably the most efficient emulsifiers discovered and which possess certain characteristics that permit these unique extracellular microbial lipopolysaccharides to be widely used in cleaning oil-contaminated vessels, oil spill management, and enhanced oil recovery by chemical flooding. Base hydrolysis under mild conditions of the emulsans and apoemulsans produces derivatives (the ".psi.-emulsans" and "apo-.psi.-emulsans", respectively) which are completely N-acylated and partially to completely O-deacylated. Emulsans and apoemulsans, both of which biopolymers are strongly anionic, exhibit a high degree of specificity in the emulsification of hydrocarbon substrates which contain both aliphatic and cyclic components.Type: GrantFiled: May 14, 1980Date of Patent: April 19, 1983Assignee: Petroleum Fermentations N.V.Inventors: David L. Gutnick, Eugene Rosenberg, Igal Belsky, Zosim Zinaida