Abstract: Zinc glycerolate comprised of plate-like crystals is prepared by heating a mixture of zinc oxide, or zinc oxide precursor compound, with glycerol at 15.degree. C. to 105.degree. C., usually at least 45.degree. C. Excess glycerol can be removed from the crude zinc glycerolate product by washing at least once with a C.sub.1 -C.sub.4 alkanol, preferably isopropanol.