Patents Assigned to PHB
  • Patent number: 9045595
    Abstract: A process for recovering polyhydroxyalkanoates (PHAs) from cellular biomass of bacteria, said biomass being obtained by fermentation and in the form of a cellular biomass slurry in aqueous suspension, comprising the steps of: submitting the slurry to operations of injection of PHA solvent, agitation and heating, in order to form a suspension comprising PHA solvent with the dissolved PHA, water and insoluble residues; recuperating the solvent enriched with PHA; rapidly cooling the solution of PHA solvent to precipitate the dissolved PHA; micro-filtrating the suspension of PHA precipitated in the solvent, in order to separate a paste concentrated with precipitated PHA; washing with water, heating and agitating the concentrated PHA paste, to promote evaporation of the solvent and to obtain a suspension containing PHA granules; agitating and shearing the PHA granules and depleting the residual solvent; and separating the purified PHA particles from the suspension.
    Type: Grant
    Filed: November 25, 2004
    Date of Patent: June 2, 2015
    Assignee: PHB Industrial S.A.
    Inventors: Paulo Eduardo Mantelatto, Alvaro Minto Duzzi, Tetuhiko Sato, Nazareno Antonio Sertori Durao, Roberto Vianna Nonato, Carlo Rocchiccioli, Sonia Maria Kesserlingh
  • Patent number: 8357508
    Abstract: A process for extracting and recovering polyhydroxyalkanoates (PHAs) from cellular biomass comprising the steps of: extracting the polyhydroxyalkanoate with at least one non-halogenated solvent which is non-aggressive to the environment; heating the cellular biomass, in order to form a suspension comprising PHA solvent with the dissolved PHA and insoluble residues; recovering the solvent enriched with PHA; injecting the PHA-enriched solvent in a vapor flow in order to rapidly promote the complete precipitation of PHA in water, while processing the solvent evaporation; depleting the residual solvent; separating the purified PHA particles from the suspension and drying them.
    Type: Grant
    Filed: March 6, 2006
    Date of Patent: January 22, 2013
    Assignee: PHB Industrial S.A.
    Inventors: Paulo Eduardo Mantelatto, Nazareno Antonio Sertori Durao
  • Publication number: 20100048767
    Abstract: The present invention refers to a polymeric blend for the preparation of environmentally degradable materials, said blend comprising biodegradable polymers, polyhydroxybutyrate—PHB or copolymers thereof and poly(butylene adipate/butylene terephthalate) aliphatic-aromatic copolyester and at least one additive. The present invention further refers to the process for obtaining said blend, by applying the extrusion technique to obtain an adequate morphology in the distribution, dispersion and interaction of the polymers, so as to obtain compatible polymeric blends, allowing the granules of the produced polymeric blends to be utilized to manufacture several injection molded products.
    Type: Application
    Filed: February 23, 2007
    Publication date: February 25, 2010
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Jose Augusto Marcondes Agnelli
  • Publication number: 20090291119
    Abstract: The polymeric implant is obtained from a renewable source, comprising a body formed by at least one biodegradable polymer selected from the group consisting of polyhydroxyalcanoates (PHAs) and copolymers thereof, said body incorporating, in its micro-structure, an active ingredient in a sufficient quantity to control at least one oestrus cycle of mammal animals. The invention further refers to a process for obtaining a polymeric implant comprising the steps of: mixing progesterone or progestogen, at least one polymer of the group of PHAs, one polymeric additive defined by poly(?-caprolactone), and at least one dispersant additive and/or solvent, to obtain a colloidal solution; evaporating the solvent of the colloidal solution, and forming a paste with the components dispersed therein; drying the paste to remove the residual solvents and control the granulometry of the polymer composite; extruding the polymeric composite and moulding the latter in an implant body.
    Type: Application
    Filed: February 6, 2007
    Publication date: November 26, 2009
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski
  • Publication number: 20090253816
    Abstract: Composition for preparing a biodegradable polyurethane-based foam and a biodegradable polyurethane foam, comprising mixtures based on poly(hydroxybutyrate) polymer, polyols of renewable source, isocyanates and additives, with the object of preparing biodegradable polyurethane foams. In the process, the poly(hydroxybutyrate) plus the polyol, the isocyanate and the additives are previously mixed in specific mixers; once the homogenization is reached, the mixture is poured in mold for growing. After curing, the resulting product presents foam characteristics, with its density, toughness and cell size varying according to the proportion of the reagents and allowing the manufacture of several products.
    Type: Application
    Filed: February 23, 2007
    Publication date: October 8, 2009
    Applicants: PHB INDUSTRIAL S.A., KEHL INDUSTRIA E COMERCIO LTDA
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Jose Ricardo De Lello Vicino
  • Publication number: 20090082491
    Abstract: The present invention refers to an environmentally degradable polymeric blend, comprising biodegradable polymers defined by polyhydroxybutyrate (PHB) or copolymers thereof and Polycaprolactone (PCL) and, optionally, at least one additive defined by a filler, nucleant, thermal stabilizer, processing aid, with the purpose of preparing an environmentally degradable polymeric blend. According to the production process described herein, the blend resulting from the mixture of the biodegradable polymers, PHB and PCL, and at least one additive, can be utilized in the manufacture of injected food packages, injected packages for cosmetics, tubes, technical pieces and several injected products.
    Type: Application
    Filed: February 23, 2007
    Publication date: March 26, 2009
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Jose Augusto Marcondes Agnelli
  • Publication number: 20090043000
    Abstract: The present invention refers to a composition of mixtures based on poly(hydroxybutyrate) polymer and vegetable oils, with the object of preparing a degradable polyol polyester. In the process, the poly(hydroxybutyrate) plus the vegetable oil react under heating, producing the polyol polyester, which once purified can be utilized in applications similar to those of the traditional polyurethane: adhesives, foams, elastomers and paints.
    Type: Application
    Filed: February 23, 2007
    Publication date: February 12, 2009
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Jose Ricardo De Lello Vicino
  • Publication number: 20090030112
    Abstract: Biodegradable polymeric composition and method for producing a biodegradable polymeric composition, comprising poly(hydroxybutyrate) or copolymers thereof, a plasticizer obtained from a renewable source, a nucleant additive, a flow aid additive, and a thermal stabilizer additive. The process of obtention comprises the steps of mixing to a load of PHB or PHBV in powder, from about 2% to 30% of a plasticizer based on vegetable oils of natural origin and fatty acids of animal and vegetable origin, distilled and hydrogenated; mixing to the biopolymer already containing the plasticizer a thermal stabilizer additive, a nucleant additive; and a flow aid additive; and extruding the composition obtained in the previous step to promote, in the melt state, the incorporation of the additives in the matrix of PHB or PHBV and its subsequent granulation.
    Type: Application
    Filed: February 23, 2007
    Publication date: January 29, 2009
    Applicants: PHB INDUSTRIAL S.A., KEHL INDUSTRIA E COMERCIO LTDA
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Dawson Buim Arena, Ana Cristina Coelho
  • Publication number: 20090023836
    Abstract: The environmentally degradable polymeric composition is obtained from the biodegradable polymers poly (hydroxybutyrate)-PHB and copolymers thereof and poly (lactic acid)-PLA and, optionally, at least one of the additives defined by: plasticizer of natural origin, such as natural fibers; natural fillers; thermal stabilizer; nucleant; compatibilizer; surface treatment agent; and processing aid.
    Type: Application
    Filed: February 23, 2007
    Publication date: January 22, 2009
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Jose Augusto Marcondes Agnelli
  • Publication number: 20090018235
    Abstract: The present invention refers to a polymeric composition prepared from a biodegradable polymer defined by poly-hydroxybutyrate (PHB) or copolymers thereof, and at least one other biodegradable polymer, such as polycaprolactone (PCL) and poly (lactic acid) (PLA), so as to alter its structure, and further at least one additive of the type of natural filler and natural fibers, and, optionally, nucleant, thermal stabilizer, processing aid, with the object of preparing an environmentally degradable material. According to the production process described herein, the composition resulting from the mixture of the modified biodegradable polymer and additives can be utilized in the manufacture of injected packages for food products, injected packages for cosmetics, tubes, technical pieces and several injected products.
    Type: Application
    Filed: February 23, 2007
    Publication date: January 15, 2009
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Jose Augusto Marcondes Agnelli
  • Publication number: 20080193987
    Abstract: A process for extracting and recovering polyhydroxyalkanoates (PHAs) from cellular biomass comprising the steps of: extracting the polyhydroxyalkanoate with at least one non-halogenated solvent which is non-aggressive to the environment; heating the cellular biomass, in order to form a suspension comprising PHA solvent with the dissolved PHA and insoluble residues; recovering the solvent enriched with PHA; injecting the PHA-enriched solvent in a vapor flow in order to rapidly promote the complete precipitation of PHA in water, while processing the solvent evaporation; depleting the residual solvent; separating the purified PHA particles from the suspension and drying them.
    Type: Application
    Filed: March 6, 2006
    Publication date: August 14, 2008
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Paulo Eduardo Mantelatto, Nazareno Antonio Sertori Durao
  • Publication number: 20080139702
    Abstract: A plasticized composition including (i) at least one biopolymer selected from the group consisting of poly hydrobutyrate (PHB) and PHB copolymers; and (ii) a plasticizer containing (a) a saturated or unsaturated, linear or branched C6-30 fatty alcohol, and (b) a glycerol ester of a linear or branched, saturated or unsaturated C6-24 fatty acid, wherein (a) and (b) are present in a ratio of 100:0 to 75:25 by weight is provided.
    Type: Application
    Filed: August 6, 2004
    Publication date: June 12, 2008
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Wanderson Bueno De Almeida, Pablo Silva Bizzari, Nazareno Antonio Sertori Durao, Jefter Fernandes Do Nascimento
  • Publication number: 20070161096
    Abstract: A process for recovering polyhydroxyalkanoates (PHAs) from cellular biomass of bacteria, said biomass being obtained by fermentation and in the form of a cellular biomass slurry in aqueous suspension, comprising the steps of: submitting the slurry to operations of injection of PHA solvent, agitation and heating, in order to form a suspension comprising PHA solvent with the dissolved PHA, water and insoluble residues; recuperating the solvent enriched with PHA; rapidly cooling the solution of PHA solvent to precipitate the dissolved PHA; micro-filtrating the suspension of PHA precipitated in the solvent, in order to separate a paste concentrated with precipitated PHA; washing with water, heating and agitating the concentrated PHA paste, to promote evaporation of the solvent and to obtain a suspension containing PHA granules; agitating and shearing the PHA granules and depleting the residual solvent; and separating the purified PHA particles from the suspension.
    Type: Application
    Filed: November 25, 2004
    Publication date: July 12, 2007
    Applicant: PHB INDUSTRIAL S.A.
    Inventors: Paulo Mantelatto, Alvaro Duzzi, Tetuhiko Sato, Nazareno Durao, Roberto Nonato, Carlo Rocchiccioli, Sonia Kesserlingh
  • Patent number: 6295686
    Abstract: A toothbrush, comprising a body having a head portion, a neck portion connected to the head portion, and a handle portion connected to the neck portion, and further comprising a plurality of bristles attached to the head portion. The body comprises a thermoplastic elastomer that is sufficiently strong to be used in the normal, intended manner for dental hygiene purposes and is sufficiently flexible to resist being fashioned into and used as a weapon. In a preferred embodiment, the body comprises approximately 50% Kraton™ DRP6031 thermoplastic rubber and approximately 50% polypropylene.
    Type: Grant
    Filed: May 18, 1999
    Date of Patent: October 2, 2001
    Assignee: PHB
    Inventor: Joseph E. Phillips
  • Patent number: 4473011
    Abstract: A circulating aerial ropeway for conveying material such as loose or bulk goods has individual cars for conveying the material, each car being pivotally borne between two longitudinal carrying beams for swinging movement about a transverse, substantially horizontal axis which is above the center of gravity of the car, the car thereby being free-hanging and arranged always to assume a substantially horizontal position, each carrying beam mounting running wheels, the ropeway also having at least two laterally-spaced, parallel track ropes, a track rope being on each side of each car so that the running wheels run on the track ropes, and at least two laterally-spaced, parallel hauling ropes, a hauling rope being on each side of each car the cars having jaws for coupling the hauling rope to the car.
    Type: Grant
    Filed: March 15, 1982
    Date of Patent: September 25, 1984
    Assignee: PHB Weserhutte AG
    Inventor: Manfred Wuschek
  • Patent number: 4408945
    Abstract: This invention is an improvement in a stationary or mobile receiving bunker adapted to be fed with bulk material, particular by means of industrial trucks, with a delivery conveyor arranged under the receiving bunker, the improvement which comprises two bunker walls enclosing the receiving bunker chamber on the side away from the direction of delivery, with straight lines running through their top edges and projected onto a horizontal plane each forming an angle .alpha.<90.degree. with the longitudinal axis of the delivery conveyor also projected onto the horizontal plane.
    Type: Grant
    Filed: July 9, 1981
    Date of Patent: October 11, 1983
    Assignee: PHB Weserhutte Aktiengesellschaft
    Inventors: Jurgen-Michael Wenzel, Werner Guderley, Ernst Hamel
  • Patent number: 4319677
    Abstract: This invention relates to stockyard transporter and tripper car equipment which is movable on rail disposed on both sides, comprising portal uprights provided with running gears, a tripper car frame and a boom, which is mounted so that it can be lifted and lowered and/or rotated. Here the stockyard transporter is supported in the tripper car substantially without a counterweight.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: March 16, 1982
    Assignee: PHB-Weserhutte AG
    Inventor: Hans Kipper