Abstract: Disclosed herein is a method of operating a polymerization reactor for a polymerization reaction comprising modifying a recycle gas composition to increase the heat capacity of the recycle gas wherein the recycle gas composition is modified by reducing or eliminating the nitrogen concentration in the recycle gas. In an embodiment, the nitrogen concentration is reduced or eliminated by reducing or eliminating one or more nitrogen input sources to the polymerization reactor and replacing the nitrogen with an alternate inert fluid (a gas or liquid that is inert to the catalyst and reactants). The alternate inert fluid has a higher heat capacity and a higher molecular weight than nitrogen. In an embodiment, the nitrogen utilized to convey a catalyst into the polymerization reactor is replaced with an alternate inert fluid. In an embodiment, the alternate inert fluid is ethane, propane, isobutane, or combinations thereof.
Abstract: A novel alkylation catalyst is described which is used in processes for alkylating olefin hydrocarbons with isoparaffin hydrocarbons to produce high octane alkylate products suitable for use as a blending component of gasoline motor fuel. The novel catalyst comprises a mixture of a hydrogen halide and a sulfone. The novel alkylation catalyst is utilized in a novel process for alkylating olefin hydrocarbons with isoparaffin hydrocarbons.
Type:
Grant
Filed:
November 22, 1993
Date of Patent:
May 5, 2009
Assignee:
Phillips Petroleum Company
Inventors:
Ronald G. Abbott, Ralph P. Williams, Marvin M. Johnson, John W. Vanderveen
Abstract: A process to oxidize an olefin wax, comprising: contacting a feedstock olefin wax composition with an oxygen-containing gas at a temperature greater than a melting point of the feedstock olefin wax composition melting point, to prepare an oxidized olefin wax composition wherein the oxidized olefin wax composition has an acid number greater than 1 mg KOH/g oxidized olefin wax composition and a kinematic viscosity at 100° C. less than 70 cSt.
Type:
Grant
Filed:
January 27, 2005
Date of Patent:
May 5, 2009
Assignee:
Chevron Phillips Chemical Company, LP
Inventors:
Hu Yang, Eduardo Baralt, Willie J. Isom, Ronald G. Abbott
Abstract: This invention modifies pectin, and improves, by the use of the modified pectin, physical properties of a subject composition, such as dispersion stability, emulsifying activity/emulsion stability, water holding property (syneresis inhibiting property), texture, viscosity development property, and gelling property. Pectin is modified by heating a raw material pectin in the form of a powder at 50 to 150° C. for 1 minute to 48 hours. Preferably, as a raw material pectin to be heated, pectin whose loss upon drying is 20% (w/w) or lower is used. More preferably, the raw material pectin is heated at 50 to 150° C. for 1 minute to 48 hours at a relative humidity of 20 to 90% (w/w) and/or under a reduced pressure.
Type:
Application
Filed:
June 7, 2006
Publication date:
April 30, 2009
Applicants:
SAN-EI GEN F.F.I., INC., PHILLIPS HYDROCOLLOIDS RESEARCH LIMITED
Inventors:
Takahiro Funami, Yohei Kataoka, Mika Hiroe
Abstract: A process and apparatus for separating polymer solids, hydrocarbon fluids, and purge gas in an intermediate pressure zone and a purge zone. The purge gas in the purge zone is used to remove hydrocarbon fluids from the polymer solids, and a stream containing the purge gas and hydrocarbons is passed to a hydrocarbon/purge gas recovery zone. High-purity purge gas from the recovery zone is efficiently used by passing a portion back to the purge zone and another portion to an extruder feed zone. Hydrocarbon fluids separated from polymer solids in the intermediate pressure zone and in the hydrocarbon/purge gas recovery zone are liquefied and passed to a recycle zone, and the hydrocarbons (typically liquid diluent and/or unreacted monomer) are recycled to the reactor without fractionation.
Type:
Grant
Filed:
November 3, 2003
Date of Patent:
April 28, 2009
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Donald W. Verser, David H. Burns, John D. Hottovy
Abstract: Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
Type:
Grant
Filed:
February 12, 2007
Date of Patent:
April 21, 2009
Assignee:
Chevron Phillips Chemical Company, LP
Inventors:
Kumudini C. Jayaratne, Michael D. Jensen, Qing Yang
Abstract: This invention relates to catalyst compositions, methods, and polymers encompassing at least one Group 4 metallocene compound comprising bridging ?5-cyclopentadienyl-type ligands, typically in combination with at least one cocatalyst, and at least one activator. The compositions and methods disclosed herein provide ethylene polymers with low levels of long chain branching.
Type:
Grant
Filed:
February 2, 2006
Date of Patent:
April 14, 2009
Assignee:
Chevron Phillips Chemical Company, LP
Inventors:
Qing Yang, Michael D. Jensen, Joel L. Martin, Matthew G. Thorn, Max P. McDaniel, Youlu Yu, David C. Rohlfing
Abstract: A method for transferring polymer within a polymerization system, comprising continuously withdrawing the polymer from the reactor and conveying the polymer from a reactor to a flash chamber via a pressure differential between the reactor and the flash chamber. A method for transferring polymer within a polymerization system comprising conveying the polymer from a reactor to a flash chamber via a pressure differential between the reactor and the flash chamber and purging interstitial gases from the polymer prior to conveying the polymer from the sash chamber to a purge column. A method for transferring polymer within a polymerization system comprising conveying the polymer from a flash chamber directly to a purge column via a pressure differential between the flash chamber and the purge column.
Type:
Grant
Filed:
August 25, 2006
Date of Patent:
April 14, 2009
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Robert R. McElvain, John D. Hottovy, Bryan M. Garner, Gregory G. Hendrickson, John H. Tait
Abstract: A method of making a composition, said method comprising, spraying a substance comprising platinum and iron into or onto an alumina-containing compound is disclosed. The resulting composition can then be used in a process for oxidizing carbon monoxide with free oxygen.
Type:
Grant
Filed:
August 20, 2008
Date of Patent:
April 7, 2009
Assignee:
Conoco Phillips Company
Inventors:
M. Bruce Welch, Roland Schmidt, Jianhua Yao, Glenn W. Dodwell, Robert W. Morton, Jason J. Gislason, James B. Kimble, David E. Simon, Marvin M. Johnson
Abstract: This invention provides a method of preparing emulsion compositions particularly emulsion foods, with excellent emulsifying activity, emulsion stability, heat resistance, and texture or mouthfeel. The method can be performed by carrying out a step (1) mixing pectin obtained by heating sugar beet pectin derived from sugar beet in powder form at a temperature of 50 to 150° C. at a relative humidity of 20 to 90% for 1 to 48 hours with raw materials for emulsion compositions; and a step (2) emulsifying the mixture obtained in the step (1), or, in place of step (1), (a) homogenizing a modified pectin in alternatively water systems; (b) mixing the water dispersions of the modified pectin obtained in step (a) with raw materials for emulsion compositions; and (c) emulsifying the mixture obtained in step (b). Thus, emulsion compositions can be prepared.
Type:
Application
Filed:
September 28, 2006
Publication date:
April 2, 2009
Applicants:
SAN-EI GEN F.F.I., INC., PHILLIPS HYDROCOLLOIDS RESEARCH LIMITED
Abstract: A method of manufacturing a semiconductor device having damascene structures with air gaps is provided. In one embodiment, the method comprises the steps of depositing and patterning a disposable layer, depositing a first barrier layer on top of the patterned disposable layer, depositing a metal layer, planarizing the metal layer, depositing a second barrier layer, planarizing the second barrier layer until substantially no barrier layer material is present on top of the disposable layer, depositing a permeable layer, removing the disposable layer through the permeable layer to form air gaps.
Type:
Grant
Filed:
March 16, 2005
Date of Patent:
March 31, 2009
Assignees:
Interuniversitair Microelektronica Centrum (IMEC), Koninklikje Phillips Electronics
Abstract: Interference surfaces are constructed on inner transition surfaces between wings of a fastener having a spiral recess. A portion of the transition surface is tapered to provide the interference. A standard driver for a spiral recess will engage the interference surface to create a “stick fit” engagement. The punch is formed using a wire EDM operation to construct tapered surfaces within the die cavity of a hob. The hob is machined down to obtain the desired depth, which is measured up from a gage spot indicative of the sticking point.
Abstract: The invention relates to a medical diagnostic apparatus (1) and to a hose (21) suitable for guiding connections in a medical diagnostic apparatus. The medical diagnostic apparatus (1) comprises a frame (5), a rotatable support (3), at least one connection extending between the frame and the rotatable support, and a hose (21) for guiding this connection. The hose (21) is provided with a chain (29) of reinforcement elements (31). The chain (29) extends mainly in the longitudinal direction of the hose (21). In the chain (29) the reinforcement elements (31) are connected to each other. These reinforcement elements (31) can also be rotated with respect to each other about an axis which is perpendicular to the longitudinal axis of the hose (21), while they are substantially rigidly connected in a direction along their rotation axis.
Abstract: The present invention relates to an integrated electronic-micro fluidic device an integrated electronic-micro fluidic device, comprising a semiconductor substrate (106) on a first (122) support, an electronic circuit (102, 104) on a first semiconductor-substrate side of the semiconductor substrate, and a signal interface structure to an external device. The signal interface structure is arranged on the first semiconductor-substrate side and configured to receive electrical signals from the electronic circuit. A micro fluidic structure (126) is formed in the semiconductor substrate, and is configured to confine a fluid and to allow a flow of the fluid to and from the microfluidic structure only on a second semiconductor-substrate side that is opposite to the first semiconductor-substrate side and faces away form the first support. The electronic-micro fluidic device forms a flexible platform for the formation of various System-in-Package applications.
Type:
Application
Filed:
March 7, 2007
Publication date:
March 19, 2009
Applicant:
Koniklijke Phillips electronics N.V
Inventors:
Ronald Dekker, Remco Henricus Wilhelmus Pijnenburg, Nicolaas Johannes Anthonius Van Veen
Abstract: The present invention utilizes a hoist drum with a number of different diameter sections upon which the different ends of a lifting cable simultaneously spool on and off of as a function of counterclockwise and clockwise cable spooling. This combination reduces the amount of shaft torque required to raise or lower a load while increasing the number of hoist drum rotations required to raise or lower that load. These two features are incorporated into the operation of a main crane cable length adjusting device since they offer precise and rapid adjustment capabilities to be made with smaller sized electric motors and clutches.
Abstract: Claus sulfur recovery plants that include one or more single-stage or multi-stage compact tubular Claus catalytic reactor-heat exchanger units are disclosed. In some instances, these new or improved Claus plants additionally include one or more compact heat exchanger containing cooling tubes that are filled with a heat transfer enhancement medium. The new compact tubular Claus catalytic reactor-heat exchanger units and HTEM-containing heat exchangers are also disclosed. A process for recovering sulfur from a hydrogen sulfide-containing gas stream, employing the new tubular Claus catalytic reactor-heat exchanger unit, and in some instances a HTEM-containing heat exchanger, are also disclosed.
Type:
Grant
Filed:
August 25, 2006
Date of Patent:
March 10, 2009
Assignee:
Conoco Phillips Company
Inventors:
Alfred E. Keller, Sriram Ramani, Joe D. Allison, Steven E. Lusk, Nathan A. Hatcher, Larry D. Swinney, Rebecca S. Shaver
Abstract: Methods and systems are provided for lighting control, including a lighting system manager, a light show composer, a light system engine, and related facilities for the convenient authoring and execution of lighting shows using semiconductor-based illumination units.
Type:
Grant
Filed:
November 22, 2004
Date of Patent:
March 10, 2009
Assignee:
Phillips Solid-State Lighting Solutions, Inc.
Inventors:
Brian Chemel, John Warwick, Frederick M. Morgan, Michael K. Blackwell, Kevin McCormick, Ihor A. Lys
Abstract: This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a supported catalyst composition. One aspect of this invention is the prepraration and use of a catalyst composition comprising a hydrocarbyl-substituted metallocene compound and a chemically-treated solid oxide for olefin polymerization processes. In another aspect, for example, this invention encompasses the preparation of a catalyst composition comprising (?5-cycloalkadienyl)2Zr(hydrocarbyl)2 complexes and sulfated alumina, but containing no organoaluminum or organoboron cocataysts, and further the use of this catalyst composition for polymerizing olefins.
Type:
Grant
Filed:
November 21, 2003
Date of Patent:
March 10, 2009
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Matthew G. Thorn, Qing Yang, Kumi C. Jayaratne
Abstract: A composite resilient scaffold may be used to grow, repair, and/or regenerate tissue such as articular cartilage. The composite scaffold is porous and at least substantially bioremovable. The composite scaffold includes a support structure coated with a discontinuous coating of separate and discrete particles of a ceramic material such as calcium phosphate. The calcium phosphate material may have a porous reticulated structure.