Abstract: Glazing assembly are described comprising at least a first (inner) glass pane, a second (outer) glass pane and at least one peripheral spacer structure for providing a predetermined separation between the first and second glass pane, the peripheral spacer structure being positioned at the peripheral area of the first and second glass pane; one or more photovoltaic (PV) cell modules mounted on at least part of the peripheral spacer structure, the one or more PV cell modules being positioned in the space defined by the first and second glass panes and the peripheral spacer structure (inter-pane space); wherein at least part of the peripheral spacer structure comprises one or more mounting members adapted to orient a light receiving surface of PV cells of the PV cell modules in a tilted position with respect to the plane of the second (outer) glass pane.