Abstract: Plastisol coatings and adhesives having reduced bulk density are provided by incorporating hollow thermoplastic microspheres, wherein the surface of the microspheres is wet by a surfactant which preferentially wets the surface of the microspheres, where the total solids content of the plastisol does not exceed the critical pigment volume concentration, and where the temperature and pressure of processing and use of the microsphere filled plastisol are kept to the minimums required for effective operation. Preferred hollow thermoplastic microspheres having a thermally bonded surface coating of a solid particulate material, such as calcium carbonate, silica, or the like are employed where the thermoplastic of the microspheres is wet by a surfactant which preferentially wets the surface of the thermoplastic and where the solid particulate material on the surface is wet by a surfactant or plasticizer which preferentially wets the solid particles are particularly effective in such plastisol coatings and adhesives.

Abstract: Microsphere wet cake is mixed with a surface barrier coating effective to prevent agglomeration and surface bonding of the microspheres, and removing water by drying with continuous mixing at high shear. In a subsequent step, by the control of the application of heat and balancing temperature and low shear mixing, it is possible to also control expansion of the microspheres.The surface barrier coating in the present invention is any one of a wide diversity of materials which meet the requirements of the intended function, i.e., to prevent the agglomeration of the microspheres during the process. Suitable materials include, by way of example, dry inorganic pigments or filler materials, and the like, and related organic materials.

Abstract: Microsphere wet cake is mixed with a surface barrier coating effective to prevent agglomeration and surface bonding of the microspheres, and removing water by drying with continuous mixing at high shear. In a subsequent step, by the control of the application of heat and balancing temperature and low shear mixing, it is possible to also control expansion of the microspheres.The surface barrier coating in the present invention is any one of a wide diversity of materials which meet the requirements of the intended function, i.e., to prevent the agglomeration of the microspheres during the process. Suitable materials include, by way of example, dry inorganic pigments or filler materials, and the like, and related organic materials.

Abstract: In the present invention, polymer binder systems are filled with inert fillers, such as calcium carbonate, and with specific thermoplastic microspheres bearing a surface coating of an inert particulate material compatible with the polymer binder system. The preferred inert particulate material on the microspheres is particulate or fibrous forms of calcium carbonate. The microspheres have a very low density, and the inert particulate for fibrous coating is thermally bonded to surface thereof. The microspheres may be employed in proportions up to as much as about 70 volume percent of the casting or molding composition, resulting in a product of exceptionally low weight and density.The products of the present invention also provide high impact strength, high resistance to cracking and crack propagation, high tensile and yield strength, and a high modulus of elasticity, particularly compared to the usual cast marble products known to the art.

Abstract: Enhanced hiding power for opacifiers in paints, inks, and other coatings is provided by employing the opacifiers, such as TiO.sub.2, ZnO, talc, CaCo.sub.3, and the like, adhered to or embedded in the surface of thermoplastic microspheres. The composite opacifier-microsphere material is readily formed with a preselected specific gravity, so that there is little tendency for the material to separate. In addition, the composite behaves in the coating as a opacifier-air interface, having a very high difference in refractive indices, and exceptional hiding power. The high volume to weight ratio of the composite affords very attractive economic advantages, effectively reducing the weight proportion of opacifiers required in the formulations, and other related advantages.

Abstract: Dental restorations are made of a palladium alloy which consists essentially of, on a weight basis, 50-85 percent palladium; 5-40 percent of at least one metal selected from the group consisting of copper and cobalt; 1-15 percent gallium; up to 5 percent of a modifier selected from the group consisting of nickel, gold, indium, ruthenium, tin and mixtures thereof; from 0.005 up to 1 percent, ordinarily less than about 0.2 percent, of an oxygen scavenging component which is a member selected from the group consisting of germanium, lithium, and mixtures thereof; and up to 0.5 percent of a grain refiner selected from the group consisting of rhenium and iridium. The alloy is free of boron.

Abstract: Enhanced hiding power for opacifiers in paints, inks, and other coatings is provided by employing the opacifiers, such as TiO.sub.2, ZnO, talc, CaCo.sub.3, and the like, adhered to or embedded in the surface of thermoplastic microspheres. The composite opacifier-microsphere material is readily formed with a preselected specific gravity, so that there is little tendency for the material to separate. In addition, the composite behaves in the coating as a opacifier-air interface, having a very high difference in refractive indices, and exceptional hiding power. The high volume to weight ratio of the composite affords very attractive economic advantages, effectively reducing the weight proportion of opacifiers required in the formulations, and other related advantages.

Abstract: Enhanced hiding power for opacifiers in paints, inks, and other coatings is provided by employing the opacifiers, such as TiO.sub.2, ZnO, talc, CaCo.sub.3, and the like, adhered to or embedded in the surface of thermoplastic microspheres. The composite opacifier-microsphere material is readily formed with a preselected specific gravity, so that there is little tendency for the material to separate. In addition, the composite behaves in the coating as a opacifier-air interface, having a very high difference in refractive indices, and exceptional hiding power. The high volume to weight ratio of the composite affords very attractive economic advantages, effectively reducing the weight proportion of opacifiers required in the formulations, and other related advantages.

Abstract: Syntactic foam graphic arts print media are provided which are particularly suitable for application to a substrate using high speed mechanical printing processes. The invention involves adding to a basic print medium a minor amount of pre-expanded, nonfriable, thermoplastic polyvinylidene chloride based microspheres substantially heat stable between about -20.degree. C. and 175.degree. C., having a particle size to about 10 to 100 microns in diameter, to produce syntactic foams having unlimited shelflife stability. The print media thereby produced may be applied to any known substrate in any desired graphic pattern.

Abstract: Enhanced hiding power for opacifiers in paints, inks, and other coatings is provided by employing the opacifiers, such as TiO.sub.2, ZnO, talc, CaCO.sub.3, and the like, adhered to or embedded in the surface of thermoplastic microspheres. The composite opacifier-microsphere material is readily formed with a preselected specific gravity, so that there is little tendency for the material to separate. In addition, the composite behaves in the coating as a opacifier-air interface, having a very high different in refractive indices, and exceptional hiding power. The high volume to weight ratio of the composite affords very attractive economic advantages, effectively reducing the weight proportion of opacifiers required in the formulations, and other related advantages.

Abstract: Enhanced hiding power for opacifiers in paints, inks, and other coatings is provided by employing the opacifiers, such as TiO.sub.2, ZnO, talc, CaCo.sub.3, and the like, adhered to or embedded in the surface of thermoplastic microspheres. The composite opacifier-microsphere material is readily formed with a preselected specific gravity, so that there is little tendency for the material to separate. In addition, the composite behaves in the coating as a opacifier-air interface, having a very high difference in refractive indices, and exceptional hiding power. The high volume to weight ratio of the composite affords very attractive economic advantages, effectively reducing the weight proportion of opacifiers required in the formulations, and other related advantages.

Abstract: Enhanced hiding power for opacifiers in paints, inks, and other coatings is provided by employing the opacifiers, such as TiO.sub.2, ZnO, talc, CaCo.sub.3, and the like, adhered to or embedded in the surface of thermoplastic micorspheres. The composite opacifier-microsphere material is readily formed with a preselected specific gravity, so that there is little tendency for the material to separate. In addition, the composite behaves in the coating as a opacifier-air interface, having a very high difference in refractive indices, and exceptional hiding power. The high volume to weight ratio of the composite affords very attractive economic advantages, effectively reducing the weight proportion of opacifiers required in the formulations, and other related advantages.

Abstract: Microsphere wet cake is mixed with a processing aid efective to prevent agglomeration and surface bonding of the microspheres, and thereafter removing water by drying with continuous mixing, optionally also under reduced pressure, i.e. vacuum drying. By the control of the application of heat and balancing temperature and the mixing, and optionally also the reduced pressure, it is possible to also control expansion of the microspheres from substantially none to substantially theoretical limits of expansion.The processing aid in the present invention is any one of a wide diversity of materials which meet the requirements of the intended function, i.e., to prevent the agglomeration of the microspheres during the process. Suitable materials include, by way of example, dry inorganic pigments or filler materials, and the like, and related organic materials.

Abstract: Microsphere wet cake is mixed with a processing aid effective to prevent agglomeration and surface bonding of the microspheres, and thereafter removing water by drying with continuous mixing, optionally also under reduced pressure, i.e. vacuum drying. By the control of the application of heat and balancing temperature and the mixing, and optionally also the reduced pressure, it is possible to also control expansion of the microspheres from substantially none to substantially theoretical limits of expansion.The processing aid in the present invention is any one of a wide diversity of materials which meet the requirements of the intended function, i.e. to prevent the agglomeration of the microspheres during the process. Suitable materials include, by way of example, dry inorganic pigments or filler materials, and the like, and related organic materials.

Abstract: Microsphere wet cake is mixed with a processing aid effective to prevent agglomeration and surface bonding of the microspheres, and thereafter removing water by drying with continuous mixing, optionally also under reduced pressure, i.e. vacuum drying. By the control of the application of heat and balancing temperature and the mixing, and optionally also the reduced pressure, it is possible to also control expansion of the microspheres from substantially none to substantially theoretical limits of expansion.The processing aid in the present invention is any one of a wide diversity of materials which meet the requirements of the intended function, i.e., to prevent the agglomeration of the microspheres during the process. Suitable materials include, by way of example, dry inorganic pigments or filler materials, and the like, and related organic materials.