Abstract: The present invention is an in-situ apparatus for generating carbon dioxide gas at an oil site for use in enhanced oil recovery (EOR). The apparatus includes a steam generator adapted to boil and superheat water to generate a source of superheated steam, as well as a source of essentially pure oxygen. The apparatus also includes a steam reformer adapted to react a carbonaceous material with the superheated steam and the pure oxygen, in an absence of air, to generate a driver gas comprising primarily carbon dioxide gas and hydrogen gas. A separator is adapted to separate at least a portion of the carbon dioxide gas from the rest of the driver gas to generate a carbon dioxide-rich driver gas and a hydrogen-rich fuel gas. A compressor is used for compressing the carbon dioxide-rich driver gas for use in enhanced oil recovery, and the compressed carbon dioxide-rich driver gas, with substantially no oxygen, is injected to a predetermined depth in order to enhance oil recovery at the oil site.

Abstract: Ketene chemistry and hydrogenation reactions are used to synthesize fuels and chemicals. Ketene from acetic acid is hydrogenated to form fuels and chemicals; acetic acid can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc. In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass.

Abstract: Systems, catalysts, and methods are provided for transforming carbon based material into synthetic mixed alcohol fuel.

Abstract: The present invention discloses a system for converting methanol or synthesis gas to liquid hydrocarbons with comparable energy content to gasoline within a mixed bed single reactor or double reactor systems. Varying catalyst composition and temperature profiles allow for significant tailoring of reaction conditions to the specific feedstocks or the desired products.

Abstract: Methods and apparatus for removing oil or natural gas from the ground. In one example, the method may include reforming a fuel source by reaction with water to generate driver gas, and injecting the driver gas into the oil well. The reforming operation may include causing the combustion of a combustible material with ambient oxygen for the release of energy; and heating a reforming reaction fuel and water sources, with the energy released from the combustion of the combustible material, to a temperature above that required for the reforming reaction wherein the fuel and water sources are reformed into driver gas. In one example, the amount of the combustible material combusted is sufficient to result in the release of enough energy to heat an amount of the reforming reaction fuel and water sources to the temperature above that required for the reforming reaction to proceed. The driver gas may be used to help extract oil from the ground and especially oil from depleted oil wells.

Abstract: The present invention is an in-situ apparatus for generating carbon dioxide gas at an oil site for use in enhanced oil recovery (EOR). The apparatus includes a steam generator adapted to boil and superheat water to generate a source of superheated steam, as well as a source of essentially pure oxygen. The apparatus also includes a steam reformer adapted to react a carbonaceous material with the superheated steam and the pure oxygen, in an absence of air, to generate a driver gas comprising primarily carbon dioxide gas and hydrogen gas. A separator is adapted to separate at least a portion of the carbon dioxide gas from the rest of the driver gas to generate a carbon dioxide-rich driver gas and a hydrogen-rich fuel gas. A compressor is used for compressing the carbon dioxide-rich driver gas for use in enhanced oil recovery, and the compressed carbon dioxide-rich driver gas, with substantially no oxygen, is injected to a predetermined depth in order to enhance oil recovery at the oil site.

Abstract: Provided are methods and apparatus for removing oil or natural gas from the ground. In one example, the method includes reforming a fuel source by reaction with water to generate driver gas, and injecting the driver gas into the oil well. The reforming operation can include causing the combustion of a combustible material with ambient oxygen for the release of energy; and heating a reforming reaction fuel and water sources, with the energy released from the combustion of the combustible material, to a temperature above that required for the reforming reaction wherein the fuel and water sources are reformed into driver gas. In one example, the amount of the combustible material combusted is sufficient to result in the release of enough energy to heat an amount of the reforming reaction fuel and water sources to the temperature above that required for the reforming reaction to proceed. The driver gas is used to help extract oil from the ground and especially oil from depleted oil wells.

Abstract: Systems, catalysts, and methods are provided for transforming carbon based material into synthetic mixed alcohol fuel.

Abstract: Systems, catalysts, and methods are provided for transforming carbon based material into synthetic mixed alcohol fuel.

Abstract: Disclosed herein is a method for generating “clean” electricity from carbonaceous material, and producing high-pressure CO2 which can be easily sequestered or utilized for a beneficial purpose, such as fuel production. This method utilizes a reformation process that reforms carbonaceous fuel with superheated steam into a high-pressure gaseous mixture that is rich in carbon dioxide and hydrogen gas. This high-pressure gas exchanges excess heat with the incoming steam from a boiler. Once cooled, the high-pressure gas goes through a CO2 separator, after which the CO2-rich gas is sequestered underground or beneficially re-used. The remaining hydrogen-rich gas is used to generate power in a power generation subsystem, such as a gas turbine or a fuel cell. Therefore, carbon-free power is produced from coal, biomass, natural gas, or another carbon-based feedstock.

Abstract: Disclosed herein is a method for generating “clean” electricity from carbonaceous material, and producing high-pressure CO2 which can be easily sequestered or utilized for a beneficial purpose, such as fuel production. This method utilizes a reformation process that reforms carbonaceous fuel with superheated steam into a high-pressure gaseous mixture that is rich in carbon dioxide and hydrogen gas. This high-pressure gas exchanges excess heat with the incoming steam from a boiler. Once cooled, the high-pressure gas goes through a CO2 separator, after which the CO2-rich gas is sequestered underground or beneficially re-used. The remaining hydrogen-rich gas is used to generate power in a power generation subsystem, such as a gas turbine or a fuel cell. Therefore, carbon-free power is produced from coal, biomass, natural gas, or another carbon-based feedstock.

Abstract: A reformation power plant generates clean electricity from carbonaceous material and high pressure CO2 which can be easily sequestered or utilized for a beneficial purpose, such as fuel production. The reformation power plant design utilizes a reformation process that reforms carbonaceous fuel with super-heated steam into a high-pressure gaseous mixture that is rich in carbon dioxide and hydrogen gas. This high-pressure gas exchanges excess heat with the incoming steam from a boiler and continues onward to a condenser. Once cooled, the high-pressure gas goes through a methanol separator, after which the CO2-rich gas is sequestered underground or beneficially re-used. The remaining hydrogen-rich gas is combusted through a gas turbine. The gas turbine provides power to a generator and also regenerative heat for the boiler. Finally, the generator converts mechanical energy into electricity, which is transferred to the electric grid.

Abstract: The present invention is a natural gas steam reforming method for generating an output gas mixture of carbon dioxide and hydrogen, including the following steps. (1) Combusting a portion of the natural gas with an oxidizing agent to generate heat, superheated steam, and a gas mixture of carbon dioxide, carbon monoxide, and hydrogen. (2) Steam reforming the gas mixture with additional superheated steam under steam-rich conditions to transform a remaining portion of the natural gas into carbon dioxide, carbon monoxide, and hydrogen. (3) Water-gas-shifting any residual carbon monoxide into additional carbon dioxide and additional hydrogen by utilizing a water-gas-shift catalyst downstream of the steam reforming step, thereby producing an effluent gas mixture that is predominantly carbon dioxide and hydrogen.

Abstract: The present invention is natural gas steam reforming apparatus for generating an output gas mixture of carbon dioxide and hydrogen. The apparatus is made from two enclosures. A first enclosure contains a source of water, superheated steam, and channels, located within a lower portion of the first enclosure, which contain a water-gas-shift catalyst for converting CO into CO2 and H2. The heat from hot gas flowing through the channels is released into the first enclosure to boil the water to generate the superheated steam. A second enclosure, contained within an upper portion of the first enclosure, includes a steam inlet for receiving the superheated steam from the first enclosure; a combustion chamber; and a reformation chamber. The combustion chamber is used for combusting a portion of the natural gas to generate additional steam, heat, and a hot gas mixture of CO2, CO, and H2.

Abstract: The present invention is a natural gas steam reforming method for generating an output gas mixture of carbon dioxide and hydrogen, including the following steps. (1) Combusting a portion of the natural gas with an oxidizing agent to generate heat, superheated steam, and a gas mixture of carbon dioxide, carbon monoxide, and hydrogen. (2) Steam reforming the gas mixture with additional superheated steam under steam-rich conditions to transform a remaining portion of the natural gas into carbon dioxide, carbon monoxide, and hydrogen. (3) Water-gas-shifting any residual carbon monoxide into additional carbon dioxide and additional hydrogen by utilizing a water-gas-shift catalyst downstream of the steam reforming step, thereby producing an effluent gas mixture that is predominantly carbon dioxide and hydrogen.

Abstract: An embodiment is an apparatus for generating a driver gas, for recovering fluid from the Earth's subsurface. The apparatus includes a fuel reformer, adapted to react a fuel with water to produce carbon dioxide gas and hydrogen gas; a compressor, adapted to compress a portion of the carbon dioxide gas and a portion of the hydrogen gas; a gas injection unit, adapted to inject the portion of the carbon dioxide gas and the portion of the hydrogen gas compressed by the compressor, into a subsurface reservoir; a gas capture unit, adapted to capture a portion of the carbon dioxide gas and the hydrogen gas, that emerges from the subsurface reservoir; and a control module capable of using subsurface data to regulate operation of the gas injection unit. The apparatus may also include a power generator adapted to utilize a portion of the hydrogen gas to generate power, hence producing electricity without greenhouse gas emissions.

Abstract: The Portable Renewable Energy System for Enhanced Oil Recovery (“PRESEOR”) is a truck mobile system that reforms biomass into CO2 and hydrogen, following which the gases are separated, with the CO2 sequestered underground for enhanced oil recovery (EOR) and the hydrogen used to generate several megawatts of carbon-free electricity. In contrast to large central power plants that are generally not well-located to support EOR, the small PRESEOR can go directly to the oilfields where it is needed, and do so in a timely manner. The PRESEOR sequesters more biomass-derived carbon than is released by the burning of the oil it yields, thereby producing not only carbon-free electricity but carbon-free oil. Using PRESEOR, over 80 billion barrels of U.S. oil would be made recoverable, without the need to drill new wells in pristine areas.

Abstract: Apparatus, methods, and systems for extracting oil or natural gas from a well using a portable coal reformer. In one example, the method may include reforming coal by reaction with water to generate driver gas (comprising carbon dioxide and hydrogen gas), and injecting the driver gas into the well. The driver gas reduces the viscosity and pressurizes the oil to help extract the oil from the oil well. The coal reforming operation may include combusting coal or other combustible material with ambient oxygen to release energy, and heating coal and water with the energy released to a temperature above that required for the coal reforming reaction to proceed, thereby reforming coal and water into driver gas. The driver gas may be purified by filtering out particles and sulfur before injecting into the well. A portion of the hydrogen gas may be separated from the driver gas and used to generate electrical power.

Abstract: An embodiment is a portable, modular apparatus, having one or more modules, for recovering oil from an oil well and generating electric power, and including a chassis to support a fuel reformer, a gas separator, a power generator, and/or a compressor. The fuel reformer module is adapted to react a fuel source with water to generate driver gas including a mixture of carbon dioxide gas and hydrogen gas. The gas separator module is operatively coupled to the reformer module and is adapted to separate at least a portion of the hydrogen gas from the rest of the driver gas. The power generator module is operatively coupled to the gas separator module and is adapted to generate electric power using a portion of the separated hydrogen gas. The compressor module is operatively coupled to the reformer module and is adapted to compress a portion of the driver gas, and to eject the driver gas at high pressure into the oil well for enhanced oil recovery.

Abstract: A control system and control method for controlling a modular apparatus for extracting petroleum and/or generating electricity based on subsurface data as well as market prices of electricity and/or petroleum. One or more probes measure subsurface total pressure, partial pressure of carbon dioxide, partial pressure of hydrogen, oil flow rate, gas flow rate, underground temperature, and/or viscosity of the oil. The control system/method controls the apparatus based on the subsurface parameters by controlling an injection module and/or a gas separator module to increase or decrease output of driver gas. The control system/method may also control the injection module and/or the gas separator module to increase (or decrease) output of driver gas when the market price of electricity decreases (or increases) and/or petroleum increases (or decreases).