Patents Assigned to Plantic Technologies Ltd.
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Publication number: 20240400799Abstract: The present invention relates to a resin composition comprising: 50 to 98 parts by mass of modified starch (A); 2 to 50 parts by mass of polyvinyl alcohol (B); and 0.01 to 0.15 part by mass of a compound represented by formula (1): or a salt thereof (C), in which the total content of the components (A), (B) and (C) is 100 parts by mass, and the average amylose content in the modified starch (A) is 50% by mass or more.Type: ApplicationFiled: October 7, 2022Publication date: December 5, 2024Applicant: Plantic Technologies Ltd.Inventor: Masahiko Ota
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Patent number: 11718733Abstract: In one aspect, the invention provides a substantially exfoliated nanocomposite material including starch and hydrophobically modified layered silicate clay. In another aspect, the invention provides packaging made from material including the substantially exfoliated nanocomposite material described above. The nanocomposite material has improved mechanical and rheological properties and reduced sensitivity to moisture in that the rates of moisture update and/or loss are reduced. In another aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material described above, including a step of mixing the starch in the form of an aqueous gel with the hydrophobic clay in a melt mixing device.Type: GrantFiled: April 14, 2021Date of Patent: August 8, 2023Assignee: PLANTIC TECHNOLOGIES LTD.Inventors: Kishan Khemani, Graeme Moad, Edmond Lascaris, Guoxin Li, George Simon, Jana Habsuda, Robert Shanks, Antonietta Genovese, Wasantha Gunaratne, Lance Nichols
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Publication number: 20230241864Abstract: The present invention relates to a multilayer structure including a starch layer (A), an adhesive layer (B), and a base material layer (C) in the order mentioned. In this multilayer structure, a material constituting the starch layer (A) comprises a starch and water; a material constituting the adhesive layer (B) comprises a thermoplastic resin having a density of 0.920 g/cm3 or lower and has an acid value of 0.3 mgKOH/g or higher; and the base material layer (C) is a layer having a tensile elastic modulus of 100 MPa or higher.Type: ApplicationFiled: September 11, 2020Publication date: August 3, 2023Applicant: PLANTIC TECHNOLOGIES LTDInventors: Akihiro KOTAKA, Masahiko OTA, Nicholas John MCCAFFREY
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Publication number: 20230191759Abstract: A laminate comprising: a gas barrier layer (I) comprising a modified starch (A) having an average amylose content of 45% by mass or more and a water-soluble polymer (B); and a substrate (II) adjacent to the gas barrier layer (I), wherein the laminate exhibits a degree of biodegradation of 80% or more in a biodegradability test in accordance with ISO 14855-1.Type: ApplicationFiled: May 14, 2021Publication date: June 22, 2023Applicant: Plantic Technologies Ltd.Inventors: Masahiko Ota, Nicholas John McCaffrey, Brendan Leigh Morris
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Publication number: 20230167277Abstract: The resin composition of the present invention comprises 40 to 98 parts by mass of a modified starch (A), 2 to 60 parts by mass of a polyvinyl alcohol (B) having a degree of saponification of 75.0 mol% or more, and optionally a clay (C), wherein the total content of the (A), (B) and (C) is 100 parts by mass, and the peak temperature of tan ? in measurement of dynamic viscoelasticity in a range of 20° C. to 150° C. is 128° C. or lower.Type: ApplicationFiled: April 28, 2021Publication date: June 1, 2023Applicant: Plantic Technologies Ltd.Inventors: Masahiko Ota, Akihiro Kotaka, Tsuyoshi Katakura
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Publication number: 20230092120Abstract: Provided is a resin composition capable of forming a coated product that exhibits low adhesion to a metal roll during production and is superior in oxygen barrier property and capable of forming a film or sheet superior in oxygen barrier property, impact strength under low humidity and color tone. The resin composition of the present invention contains 50 to 98 parts by mass of a modified starch (A), 2 to 50 parts by mass of a polyvinyl alcohol (B), 0.1 to 10 parts by mass of a polyoxyalkylene (C), and optionally 0 to 5 parts of a polyol plasticizer (D), wherein the total content of the (A), (B), (C) and (D) is 100 parts by mass.Type: ApplicationFiled: February 3, 2021Publication date: March 23, 2023Applicant: Plantic Technologies LtdInventors: Masahiko Ota, Akihiro Kotaka, Nicholas John McCaffrey
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Patent number: 11578193Abstract: Provided is a resin composition comprising a starch and a polyvinyl alcohol, which is excellent in the breaking strength and breaking elongation at a low temperature, and at the same time, has the good gas barrier property. The resin composition comprises modified starch and polyvinyl alcohol, and where in a cross section photograph by a transmission electron microscope, a cross-sectional area of each of particles of the polyvinyl alcohol dispersed is calculated, and a cross-sectional shape of each of the particles of the polyvinyl alcohol is postulated to be circular based on the cross-sectional area, the particles of the polyvinyl alcohol have a conversion particle diameter of 50 to 300 nm, and the conversion particle diameter has a dispersity of 3.0 or less.Type: GrantFiled: June 25, 2018Date of Patent: February 14, 2023Assignee: PLANTIC TECHNOLOGIES LTDInventors: Masahiko Ota, Nicholas John McCaffrey
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Publication number: 20210246286Abstract: In one aspect, the invention provides a substantially exfoliated nanocomposite material including starch and hydrophobically modified layered silicate clay. In another aspect, the invention provides packaging made from material including the substantially exfoliated nanocomposite material described above. The nanocomposite material has improved mechanical and rheological properties and reduced sensitivity to moisture in that the rates of moisture update and/or loss are reduced. In another aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material described above, including a step of mixing the starch in the form of an aqueous gel with the hydrophobic clay in a melt mixing device.Type: ApplicationFiled: April 14, 2021Publication date: August 12, 2021Applicant: Plantic Technologies Ltd.Inventors: Kishan Khemani, Graeme Moad, Edmond Lascaris, Guoxin Li, George Simon, Jana Habsuda, Robert Shanks, Antonietta Genovese, Wasantha Gunaratne, Lance Nichols
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Patent number: 11008442Abstract: In one aspect, the invention provides a substantially exfoliated nanocomposite material including starch and hydrophobically modified layered silicate clay. In another aspect, the invention provides packaging made from material including the substantially exfoliated nanocomposite material described above. The nanocomposite material has improved mechanical and rheological properties and reduced sensitivity to moisture in that the rates of moisture update and/or loss are reduced. In another aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material described above, including a step of mixing the starch in the form of an aqueous gel with the hydrophobic clay in a melt mixing device.Type: GrantFiled: June 21, 2017Date of Patent: May 18, 2021Assignee: PLANTIC TECHNOLOGIES LTD.Inventors: Kishan Khemani, Graeme Moad, Edmond Lascaris, Guoxin Li, George Simon, Jana Habsuda, Robert Shanks, Antonietta Genovese, Wasantha Gunaratne, Lance Nichols
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Patent number: 10066088Abstract: There is provided a starch composition comprising a crosslinked starch. The composition may be useful in a variety of applications, for example, in thermoformed articles or as a component in multilayer films.Type: GrantFiled: April 16, 2015Date of Patent: September 4, 2018Assignee: Plantic Technologies LtdInventor: Nicholas John McCaffrey
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Publication number: 20170283579Abstract: In one aspect, the invention provides a substantially exfoliated nanocomposite material including starch and hydrophobically modified layered silicate clay. In another aspect, the invention provides packaging made from material including the substantially exfoliated nanocomposite material described above. The nanocomposite material has improved mechanical and rheological properties and reduced sensitivity to moisture in that the rates of moisture update and/or loss are reduced. In another aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material described above, including a step of mixing the starch in the form of an aqueous gel with the hydrophobic clay in a melt mixing device.Type: ApplicationFiled: June 21, 2017Publication date: October 5, 2017Applicant: Plantic Technologies Ltd.Inventors: Kishan Khemani, Graeme Moad, Edmond Lascaris, Guoxin Li, George Simon, Jana Habsuda, Robert Shanks, Antonietta Genovese, Wasantha Gunaratne, Lance Nichols
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Patent number: 9745453Abstract: In one aspect, the invention provides a substantially exfoliated nanocomposite material including starch and hydrophobically modified layered silicate clay. In another aspect, the invention provides packaging made from material including the substantially exfoliated nanocomposite material described above. The nanocomposite material has improved mechanical and rheological properties and reduced sensitivity to moisture in that the rates of moisture update and/or loss are reduced. In another aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material described above, including a step of mixing the starch in the form of an aqueous gel with the hydrophobic clay in a melt mixing device.Type: GrantFiled: June 2, 2008Date of Patent: August 29, 2017Assignee: Plantic Technologies Ltd.Inventors: Kishan Khemani, Graeme Moad, Edmond Lascaris, Guoxin Li, George Simon, Jana Habsuda, Robert Shanks, Antonietta Genovese, Wasantha Gunaratne, Lance Nichols
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Patent number: 8697245Abstract: A biodegradable injection mouldable polymer composition including on a dry weight basis from 45-85% w/w by weight of a starch and/or a modified high amylose starch, from 2-15% w/w by weight of a water soluble polymer preferably selected from polyvinyl alcohol, polyvinyl acetate and copolymers of ethylene and vinyl alcohol which have a melting point compatible with the molten state of the starch components, and from 5-45% w/w by weight of one or more polyol plasticizers having a molecular weight in the range of 50-6000, more preferably 50-2500, and still more preferably 100-400 and preferably selected from the group consisting of sorbitol, glycerol, maltitol, xylitol, mannitol, erythritol, polyglycerol, glycerol trioleate, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, polyethylene oxide, ethylene glycol, diethylene glycol or polyethylene glycol; more preferably glycerol, maltitol, sorbitol, erythritol and xylitol.Type: GrantFiled: August 6, 2007Date of Patent: April 15, 2014Assignee: Plantic Technologies Ltd.Inventors: Kishan Khemani, Nicholas John McCaffrey, Rulande Henderson
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Patent number: 8569402Abstract: A biodegradable injection moldable polymer having the composition a) from 50 to 85% by weight of a starch and or a modified high amylose starch b) from 4 to 13% by weight of a water soluble polymer selected from polyvinylacetate, polyvinyl alcohol and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 10 to 35% by weight of a polyol plasticizer d) from 0.5 to 10% of a polyethylene oxide or polyethylene glycol e) from 0 to 1.5% by weight of a C12-22 fatty acid or salt and f) from 0.25% to 3% of a food grade emulsifier. The polymers are suitable for biodegradable, flushable tampon applicators and other medical or industrial products where flushability and bio degradability are desirable.Type: GrantFiled: October 5, 2005Date of Patent: October 29, 2013Assignee: Plantic Technologies Ltd.Inventors: Rulande Henderson, Ian John Partridge, Elizabeth Emily Rose, Nicholas Roy Oakley
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Patent number: 7854994Abstract: A barrier composition which is injection mouldable and able to be made into a transparent film or incorporated (by co-extrusion and/or lamination) into multi-layer film products, the composition on dry basis: a) from 45 to 90% by weight of a starch and/or a modified starch selected from starches modified by reaction with a hydroxyl alkyl group, an acetate or a dicarboxylic acid anhydride or a grafting polymer; b) from 4 to 12% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 5 to 45% by weight of a non-crystallising mixture of sorbitol and at least one other plasticizer selected from glycerol, maltitol, xylitol, mannitol, glycerol trioleate, epoxidised linseed or soybean oil, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate; polyethylene oxide or polyethylene glycol; d) fromType: GrantFiled: October 18, 2005Date of Patent: December 21, 2010Assignee: Plantic Technologies Ltd.Inventors: Rulande Henderson-Rutgers, Mark Fink, Nicholas Roy Oakley
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Publication number: 20100307951Abstract: In one aspect, the invention provides a substantially exfoliated nanocomposite material including starch and hydrophobically modified layered silicate clay. In another aspect, the invention provides packaging made from material including the substantially exfoliated nanocomposite material described above. The nanocomposite material has improved mechanical and rheological properties and reduced sensitivity to moisture in that the rates of moisture update and/or loss are reduced. In another aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material described above, including a step of mixing the starch in the form of an aqueous gel with the hydrophobic clay in a melt mixing device.Type: ApplicationFiled: June 2, 2008Publication date: December 9, 2010Applicant: PLANTIC TECHNOLOGIES LTD.Inventors: Kishan Khemani, Graeme Moad, Edmond Lascaris, Guoxin Li, George Simon, Jana Habsuda, Robert Shanks, Antonietta Genovese, Wasantha Gunaratne, Lance Nichols
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Publication number: 20100297458Abstract: A biodegradable injection mouldable polymer composition including on a dry weight basis from 45-85% w/w by weight of a starch and/or a modified high amylose starch, from 2-15% w/w by weight of a water soluble polymer preferably selected from polyvinyl alcohol, polyvinyl acetate and copolymers of ethylene and vinyl alcohol which have a melting point compatible with the molten state of the starch components, and from 5-45% w/w by weight of one or more polyol plasticizers having a molecular weight in the range of 50-6000, more preferably 50-2500, and still more preferably 100-400 and preferably selected from the group consisting of sorbitol, glycerol, maltitol, xylitol, mannitol, erythritol, polyglycerol, glycerol trioleate, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, polyethylene oxide, ethylene glycol, diethylene glycol or polyethylene glycol; more preferably glycerol, maltitol, sorbitol, erythritol and xylitol.Type: ApplicationFiled: August 6, 2007Publication date: November 25, 2010Applicant: PLANTIC TECHNOLOGIES LTD.Inventors: Kishan Khemani, Nicholas John McCaffrey, Rulande Henderson
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Patent number: 7495044Abstract: A biodegradable polymer is disclosed having the composition g) from 8 to 80% by weight of a starch modified to include an hydroxyalkyl C2-6 group or modified by reaction with an anhydride of a dicarboxylic acid, preferably hydroxypropylated high amylose starch, a) from 0 to 87.9% of starch, b) from 4 to 11% by weight of a water soluble polymer selected from polyvinylacetate, polyvinyl alcohol and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten stat of the starch components, c) from 0 to 20% by weight of a polyol plasticiser, preferably glycerol, d) from 0.1 to 1.5% by weight of a C12-22 fatty acid or salt, preferably stearic acid and, e) 0 to 12% added water. The polymers are suitable as biodegradable rigid sheet or flexible film materials for use in packaging foodstuffs.Type: GrantFiled: March 1, 2007Date of Patent: February 24, 2009Assignee: Plantic Technologies Ltd.Inventors: Yu Long, Stephen Coombs, Gregor Bruce Yeo Christie
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Patent number: 7384993Abstract: A biodegradable polymer is disclosed having the composition g) from 8 to 80% by weight of a starch modified to include an hydroxyalkyl C2-6 group or modified by reaction with an anhydride of a dicarboxylic acid, preferably hydroxypropylated high amylose starch, a) from 0 to 87.9% of starch, b) from 4 to 11% by weight of a water soluble polymer selected from polyvinylacetate, polyvinyl alcohol and copolymers of ehtylene and vinylalcohol which have a melting point compatible with the molten state of the starch components, c) from 0 to 20% by weight of a polyol plasticiser, preferably glycerol, d) from 0.1 to 1.5% by weight of a C12-22 fatty acid or salt, preferably stearic acid and, e) 0 to 12% added water. The polymers are suitable as biodegradable rigid sheet or flexible film materials for use in packaging foodstuffs.Type: GrantFiled: August 17, 2006Date of Patent: June 10, 2008Assignee: Plantic Technologies LtdInventors: Yu Long, Stephen Coombs, Gregor Bruce Yeo Christie
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Patent number: 7326743Abstract: A biodegradable polymer is disclosed having the composition g) from 8 to 80% by weight of a starch modified to include an hydroxyalkyl C2-6 group or modified by reaction with an anhydride of a dicarboxylic acid, preferably hydroxypropylated high amylose starch, a) from 0 to 87.9% of starch, b) from 4 to 11% by weight of a water soluble polymer selected from polyvinylacetate, polyvinyl alcohol and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten stat of the starch components, c) from 0 to 20% by weight of a polyol plasticiser, preferably glycerol, d) from 0.1 to 1.5% by weight of a C12-22 fatty acid or salt, preferably stearic acid and, e) 0 to 12% added water. The polymers are suitable as biodegradable rigid sheet or flexible film materials for use in packaging foodstuffs.Type: GrantFiled: March 22, 2004Date of Patent: February 5, 2008Assignee: Plantic Technologies Ltd.Inventors: Long Yu, Stephen Coombs, Gregor Bruce Yeo Christie