Abstract: Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.
Type:
Grant
Filed:
May 29, 2009
Date of Patent:
September 13, 2011
Assignee:
Pleotint, L.L.C.
Inventors:
Harlan J. Byker, Paul H. Ogburn, Jr., Douglas A. Vander Griend, Brad S. Veldkamp, Derick D. Winkle
Abstract: Alternating layers of a first moisture sensitive layer are formed with a second desiccant containing layer. The desiccant containing layer removes moisture from the first moisture sensitive layer and maintains the first layer in a relatively dry condition.
Type:
Application
Filed:
June 16, 2010
Publication date:
December 16, 2010
Applicant:
PLEOTINT, L.L.C.
Inventors:
Samuel J. DeJong, Michael D. Broekhuis, Harlan J. Byker
Abstract: An energy efficient, thermochromic device that may be used to allow sunlight or solar radiation into a building or structure when sunlight is absent or at high sun angles and substantially blocks solar radiation when sunlight is directly on the window.
Type:
Grant
Filed:
September 4, 2007
Date of Patent:
October 19, 2010
Assignee:
Pleotint, L.L.C.
Inventors:
Frederick A. Millett, Michael D. Broekhuis, Harlan J. Byker, Paul H. Ogburn, Jr.
Abstract: Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.
Type:
Grant
Filed:
September 4, 2007
Date of Patent:
June 2, 2009
Assignee:
Pleotint, L.L.C.
Inventors:
Harlan J. Byker, Paul H. Ogburn, Jr., Douglas A. Vander Griend, Brad S. Veldkamp, Derick D. Winkle
Abstract: Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes. In accordance with one aspect of the present invention, a thermochromic system is disclosed comprising a first metal ion and a second metal ion and at least one ligand that complexes with the first metal ion to form a L?MLC and complexes with the second metal ion to form a H?MLC wherein an increase in temperature of the system results in a reversible net increase in its ability to absorb light energy in the 400 nm to 1400 nm range due to the ligand transferring from the first metal ion to the second metal ion.
Type:
Grant
Filed:
September 4, 2007
Date of Patent:
May 26, 2009
Assignee:
Pleotint, L.L.C.
Inventors:
Harlan J. Byker, Paul H. Ogburn, Jr., Douglas A. Vander Griend, Derick D. Winkle
Abstract: Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes. In accordance with one aspect of the present invention, a thermochromic device is disclosed comprising at least two thermochromic layers when each thermochromic layer includes a polymer, at least one transition metal ion, at least one H?L ligand capable of forming a H?MLC with the transition metal ion and at least one L?L ligand capable of forming an L?MLC with the transition metal ion.
Type:
Grant
Filed:
September 4, 2007
Date of Patent:
April 28, 2009
Assignee:
Pleotint, L.L.C.
Inventors:
Harlan J. Byker, Frederick A. Millett, Paul H. Ogburn, Jr., Douglas A. Vander Griend, Brad S. Veldkamp, Derick D. Winkle
Abstract: The invention is an energy efficient, thermochromic device that may be used to allow sunlight or solar radiation into a building or structure when the ambient temperature is low and substantially blocks solar radiation when the ambient temperature is high, especially when sunlight is directly on the window.
Abstract: Thermally reversible light scattering materials are provided in accordance with the invention including a low melting, polymeric material dispersed in a polymer matrix; a first polymer which upon heating from a temperature below its melting point to a temperature above its melting point changes from a light scattering solid to a liquid, the first polymer being dispersed in a matrix provided by a second polymer to form a light scattering polymer material when cold and a less or non-light scattering material when hot; and thermally reversible light scattering materials which go from light scattering at lower temperatures to less or non-light scattering at higher temperatures.
Type:
Grant
Filed:
May 19, 2000
Date of Patent:
March 26, 2002
Assignee:
Pleotint, L.L.C.
Inventors:
Harlan J. Byker, Frederick A. Millett, Paul H. Ogburn
Abstract: The invention is an energy efficient, thermochromic device for windows that allows sunlight or solar radiation into a building or structure when the ambient temperature is low and substantially blocks solar radiation when the ambient temperature is high, especially when sunlight is directly on the window. Additionally, the invention is a thermochromic device useful as variable transmission shutters for use in lenses or filters.