Abstract: A battery (100B) comprises an electrolyte in which a first element forms a redox pair with a second element, wherein the battery (100B) is charged at a voltage sufficient to plate the first element at the anode (122B) and wherein the voltage is insufficient to plate the second element on the anode (122B). Preferred batteries include secondary batteries comprising a mixed electrolyte that includes a redox pair formed by a first element and a second element.
Type:
Grant
Filed:
February 12, 2002
Date of Patent:
July 14, 2009
Assignee:
Plurion Limited
Inventors:
Robert Lewis Clarke, Brian Dougherty, Stephen Harrison, J. Peter Millington, Samaresh Mohanta
Abstract: An electric device comprises a gelled acid electrolyte (142A) in complex with a lanthanide that forms a redox pair with a second element. Preferred electric devices include batteries and especially primary batteries, while preferred acid electrolytes (124A) have a sulfonic acid group. Contemplated lanthanides especially include cerium, and preferred second elements particularly include zinc. Alternatively, contemplated electric devices may comprise a gelled electrolyte (142A) in which with a lanthanide forms a redox pair with zinc.
Type:
Grant
Filed:
February 12, 2002
Date of Patent:
November 20, 2007
Assignee:
Plurion Limited
Inventors:
Robert Clarke, Brian Dougherty, Stephen Harrison, J. Peter Millington, Samaresh Mohanta
Abstract: A load leveling battery (122) comprising an electrolyte that includes a cerium zinc redox pair wherein preferred electrolytes are acid electrolytes, and most preferably comprise methane sulfonic acid. Contemplated load leveling batteries (122) have an open circuit voltage of at least 2.4 Volt per cell. Such batteries are useful at power grid substations (120) and commercial and industrial applications were large amounts of power are used. Preferred capacity is at least 100,000 kWh, more preferably 250,000 kWh.
Type:
Grant
Filed:
August 10, 2001
Date of Patent:
September 18, 2007
Assignee:
Plurion Limited
Inventors:
Robert Lewis Clarke, Brian Dougherty, Stephen Harrison, Peter J. Millington, Samaresh Mohanta
Abstract: A battery (100) comprises an electrolyte in which a lanthanide and zinc form a redox pair. Preferred electrolytes are acid electrolytes, and most preferably comprise methane sulfonic acid, and it is further contemplated that suitable electrolytes may include at least two lanthanides. Contemplated lanthanides include cerium, praseodymium, neodymium, terbium, and dysprosium, and further contemplate lanthanides are samarium, europium, thulium and ytterbium.
Type:
Grant
Filed:
February 12, 2002
Date of Patent:
August 7, 2007
Assignee:
Plurion Limited
Inventors:
Robert Clarke, Brian Dougherty, Stephen Harrison, J. Peter Millington, Samaresh Mohanta
Abstract: A battery (100) comprises a cell having a cathode compartment (120) that includes an element that is oxidized during charging of the battery (100), wherein the oxidized element forms a salt with an acid and thereby increases the H+ concentration in the cathode compartment (120) sufficient to promote an H+ flux into the anode compartment (110) across the separator (130), wherein the H+ flux across the separator (130) is sufficient to disintegrate a zinc dendrite proximal to the separator (130).
Type:
Grant
Filed:
February 12, 2002
Date of Patent:
May 8, 2007
Assignee:
Plurion Limited
Inventors:
Robert Lewis Clarke, Brian Dougherty, Stephen Harrison, Peter J. Millington, Samaresh Mohanta