Abstract: Multi-layer film products comprising an inner or core layer made from polyolefin polymers produced by polymerizing an .alpha.-olefin in the presence of a catalyst including: a pro-catalyst having a magnesium halide; an aluminum halide; a tetravalent titanium halide, ;an electron donor; and a silane having the formula R.sub.1 R.sub.2 Si(OR.sub.3)(OR.sub.4), wherein R.sub.1 and R.sub.2 are each an H, C.sub.1-6 alkyl, aryl, C.sub.5-12 cycloalkyl, each of which may be unsubstituted, mono- or di-substituted, and R.sub.3 and R.sub.4 are H, C.sub.1-6 alkyl, or a mono- or di-substituted C.sub.1-6 alkyl; and a co-catalyst comprising an organometallic compound, or reaction products of the pro-catalyst and the co-catalyst. The film products have excellent clarity, superior dart impact, resistance to tear and favorable sealibility characteristics.

Abstract: A flexible hose which is formed by attaching a resin reinforcing coil member to a cylindrical body, the cylindrical body being composed of a nonwoven fabric layer which is formed by winding a nonwoven fabric tape spirally and connecting adjacent side end portions and an air-cut layer which forms on at least one side of the nonwoven layer. The nonwoven fabric tape and the reinforcing coil member are formed of heat-fusible resin materials, and the reinforcing coil member is fused with the nonwoven fabric layer in a body.

Abstract: A method and apparatus for product recovery of polyolefins, particularly high molecular weight amorphous poly alphaolefins, wherein the use of water during the method is significantly decreased and wherein the intermediate stage of storing and drying the chunk form of the polyolefin is eliminated. Polyolefins produced in a reactor are heated and mixed by sigma blades in a kneader-extruder to remove any unreacted monomer(s). The polyolefin material in a liquid form is then transferred directly to an extruder to further remove any unreacted monomer(s) and catalyst(s). The invention further includes a method of measuring the inventory in a vessel using a gas of known quantity and known thermodynamic properties.

Abstract: A catalyst for use in the production of flexible polyolefins using a pro-catalyst of (a) a magnesium halide, (b) an aluminum halide, (c) a tetravalent titanium halide, (d) an electron donor comprising at least one of 2,6-lutidine, 6-chloro-2-picoline, or 2,6-dichloropyridine; and (e) a silane having the formula R.sub.1 R.sub.2 Si(OR.sub.3)(OR.sub.4), wherein R.sub.1 and R.sub.2 are each an H, C.sub.1-6 alkyl, C.sub.1-6 aryl, C.sub.5-12 cycloalkane, each of which may be unsubstituted, mono- or di-substituted, and R.sub.3 and R.sub.4 are H, C.sub.1-6 alkane, or a mono- or di-substituted C.sub.1-6 alkane, and a co-catalyst of an organometallic compound, as well as an optional external modifier that may be combined to form a catalyst. Methods for preparing the catalyst, for using the same to produce flexible polyolefin compositions having reduced stickiness and tacticity, and the flexible polyolefin compositions produced thereby are also part of the invention.

Abstract: The case of an intake silencer system includes a first case half and a second case half coupled to each other at mating faces, with an intake duct clamped between the mating faces. The intake duct opens into a resonant chamber within the case, so that noise is damped by a resonant effect. Three ribs are provided on an inner surface of the first case half, thereby defining four subsidiary silencing chambers each functioning as a side branch for producing a resonant effect to obtain a silencing effect in a wide frequency range. The ribs also contribute to an enhancement in rigidity of the wall surfaces of the case.

Abstract: A flexible synthetic resin tube is provided by uniting an inner layer of a polyether-series thermoplastic polyurethane resin with a hard synthetic resin spiral reinforcement (e.g. a hard vinyl chloride resin) or a soft synthetic resin outer layer (e.g. a soft vinyl chloride resin), through an interposed adhesive intermediate resin layer. The polyurethane resin includes a resin having a diol composed of a tetramethylenoxy unit as a polyol component. The spiral reinforcement may be buried in the outer layer. The intermediate resin layer may comprise a mixture of the polyether-series thermoplastic polyurethane resin, and the synthetic resin for the spiral reinforcement or the outer layer. This tube imparts an enhanced hydrolysis-resistant property to the polyurethane resin forming the inner layer, and an improved adhesive strength between the inner layer and the spiral reinforcement or the outer layer.

Abstract: An abrasion resistant composite hose comprises (a) an outer layer composing a spiral tape of a soft synthetic resin, where adjacent side edges of the spiral tape join each other to form the outer layer, (b) a spiral reinforcement of a hard synthetic resin for retaining and reinforcing the outer layer, and (c) an inner layer comprising a spiral strip formed by a rubber, where adjacent side edges of the spiral strip join each other to form the inner layer, and the outer layer and inner layer join each other. In such a composite hose having this structure, at least a periphery of the strip except an exposed surface to an inner surface of the hose is covered with a covering element comprising a rubber adhesive to the soft synthetic resin constituting the outer layer, and the rubber strip is formed by a rubber having higher abrasion resistance than the covering element to obtain a composite hose having enhanced abrasion resistance.

Abstract: A rod 3 is driven forward to open an annular slit 5 between a die 2 and a mandrel 4 and the molten resin in a resin accumulation chamber 10 is expelled from annular slit 5 to form a parison. In this operation, the die 2 is displaced from an original position adjoining to the mandrel 4 (axially aligned position) upon opening of the annular slit 5 to correct for any variation in thickness of parison P to be extruded from the annular slit 5. Then, the molten resin accumulated in accumulation chamber 10 is expelled from annular slit 5 to form parison P. The die 2 is then reset to the original position to bring the die 2 and mandrel 4 into axial alignment. Therefore, as the rod 3 is driven back, the annular slit 5 can be closed tight by the mandrel 4 to prevent resin leakage. After closure of the annular slit 5, molten resin is accumulated again in the accumulation chamber 10 and the annular slit 5 is opened. This procedure is repeated to produce parisons on an intermittent basis.

Abstract: The invention comprises processes for the production of useful fluid or grease from curable silicone compositions or silicone rubbers, preferably reclaimed or scrap silicone rubber. The processes involve the application of energy in such a manner that a un-curable silicone grease or liquid that contains essentially all of the original material is produced from curable silicone compositions and grease or liquid is produced from silicone rubbers. Suitable energy forms include thermal and mechanical. The fluid or grease produced by the processes are useful as raw materials for the manufacture of silicone products such as: antifoam compounds (defoamers), greases, conformal coatings or rubbers. The materials produced by these processes were unexpectedly found to have exceptional antifoam properties without requiring the addition of other materials or further processing.

Abstract: The invention comprises processes for the production of useful fluid or grease from curable silicone compositions or silicone rubbers, preferably reclaimed or scrap silicone rubber. The processes involve the application of energy in such a manner that a un-curable silicone grease or liquid that contains essentially all of the original material is produced from curable silicone compositions and grease or liquid is produced from silicone rubbers. Suitable energy forms include thermal and mechanical. The fluid or grease produced by the processes are useful as raw materials for the manufacture of silicone products such as: antifoam compounds (defoamers), greases, conformal coatings or rubbers. The materials produced by these processes were unexpectedly found to have exceptional antifoam properties without requiring the addition of other materials or further processing.

Abstract: The invention comprises processes for the production of useful fluid or grease from curable silicone compositions or silicone rubbers, preferably reclaimed or scrap silicone rubber. The processes involve the application of energy in such a manner that a un-curable silicone grease or liquid that contains essentially all of the original material is produced from curable silicone compositions and grease or liquid is produced from silicone rubbers. Suitable energy forms include thermal and mechanical. The fluid or grease produced by the processes are useful as raw materials for the manufacture of silicone products such as: antifoam compounds (defoamers), greases, conformal coatings or rubbers. The materials produced by these processes were unexpectedly found to have exceptional antifoam properties without requiring the addition of other materials or further processing.

Abstract: A method of manufacturing hollow resin products which are curved two-dimensionally or three-dimensionally. The method includes extruding a tubular parison from an extruder at a constant speed and cutting the parison at a specified length; receiving the parison extruded from the extruder into a conveyer having a feeder which is driven at the same speed as the extruding speed of the parison; maintaining the parison in the conveyer by stopping the feeder temporarily; feeding a leading portion of the parison to a trailing portion thereof successively through an outlet of the conveyer into a cavity of a lower mold of a blow molding machine by driving the feeder, the cavity being curved two-dimensionally or three-dimensionally; and closing the lower mold with an upper mold of the blow molding machine and blowing compressed gas into the parison in the blow molding machine.

Abstract: An apparatus for manufacturing hollow resin products. The apparatus includes an extruder for extruding a tubular resin material and cutting the material into a parison with a specified length; a blow molding machine having an upper mold and a lower mold which form a cavity of a specified shape inside; and a parison delivering machine for receiving the parison from the extruder and feeding the parison into the cavity of the lower mold. The parison delivering machine includes a conveyer which has parison feeder for feeding a parison longitudinally from an inlet to an outlet, a driver for driving the feeder, and at least four shafts which serve as pivots of three-dimensional movement of the conveyor.

Abstract: An apparatus for manufacturing a hollow synthetic resin product, including a movable parison guide and a movable lower molding portion which align an extruding head, the parison guide and an end of the lower molding portion in a perpendicular plane. The lower molding portion is moved in a direction perpendicular to the perpendicular plane while a parison is extruded from the extruding head, while the parison guide is moved in a direction crossing the moving direction of the lower molding portion in accordance with a shape of a groove of the lower molding portion to accommodate a first portion of the parison in the groove. A cutter cuts the parison in a predetermined length when the predetermined length thereof is extruded, while a parison pinch holds a portion of the parison to be cut immediately before the parison is cut.

Abstract: The method includes moving a parison guide and a lower molding portion to substantially vertically align an extruding head, the parison guide and an end of the lower molding portion. Then, the lower molding portion is moved substantially horizontally while extruding a parison from the extruding head, while the parison guide is moved laterally in a direction crossing the moving direction of the lower molding portion in accordance with a shape of a groove of the lower molding portion to accommodate a first portion of the parison in the groove. Subsequently, the parison is cut into a predetermined length when the predetermined length thereof is extruded, while a portion of the parison to be cut is held by a parison pinch.

Abstract: A hydroxyl functional polyester suitable for use in powder coating formulations and bearing sulfonate salt groups, its preparation, and its use in powder coating formulations with methoxyalkylene amino group bearing curatives are described. These polyester resins preferably have 200.degree. C. ICI cone and plate viscosities between about 10 and 90 Poise, have DSC determined glass transition temperatures of at least about 40.degree. C., have hydroxyl numbers between about 10 and 60, and have a sulfonate salt group content between about 0.25 and 4 weight percent. They are preferably synthesized by esterification or transesterification utilizing a sulfonate salt group bearing reactant such as 5-sodium sulfo isophthalic acid. The sulfonate salt groups, preferably alkali metal salt groups, serve to catalyze the curing reaction between the resin and the curative.

Abstract: Organopolysiloxane fluids, thiofunctional polysiloxane fluids, or blends of organopolysiloxane fluids and thiofunctional polysiloxane fluids are stabilized against degradation in the presence of kaolin clays at elevated temperatures by adding an epoxy containing compound.

Abstract: Organopolysiloxane fluids, thiofunctional polysiloxane fluids, or blends of organopolysiloxane fluids and thiofunctional polysiloxane fluids are stabilized against degradation in the presence of kaolin clays at elevated temperatures by adding an epoxy containing compound.

Abstract: A hollow synthetic resin product manufacturing apparatus with an extruder having an extruding head for extruding a parison and a mold formed of lower and upper molding portions respectively having grooves, a cutter for cutting the parison extruded from the extruding head into a specified length, a robot having a hand for holding the parison at one point of the parison, and a control unit for moving the hand holding the above portion of the parison so that the parison be accommodated in the groove of the lower molding portion.

Abstract: A method of preparing an alkoxysilane and a silicone resin includes the steps of combining a siloxane A having a first boiling point with a catalyst in a reaction vessel. A tri or tetra alkoxy functional silane monomer B is added to the vessel having a second boiling point. The contents of the vessel are heated. By a rearrangement reaction, an alkoxysilane is distilled from the vessel. The alkoxysilane has a boiling point which is lower than the mixture of the boiling points of the siloxane A, the silane monomer B and the temperature of the heated vessel. A silicone resin having alkoxy functionality and no silanol functionality is recovered from the vessel.