Abstract: A solar reactor useful in reaction processes, more particularly, useful in endothermic reaction processes, such as a catalyzed process or an adsorption-desorption process. The reactor comprises a reaction pathway defined by an exterior wall and an interior wall, the exterior wall comprising a solar radiation receiver capable of converting solar radiation into heat and transmitting the heat to the reaction pathway. The reaction pathway has disposed therein, in alternating fashion, a plurality of reactive elements comprised of a catalyst or a sorbent and a plurality of heat transfer elements.

Abstract: A first process and sorbent for removing ammonia from a gaseous environment, the sorbent comprised of graphene oxide having supported thereon at least one compound selected from metal salts, metal oxides and acids, each of which is capable of adsorbing ammonia. A second process and sorbent system for removing ammonia and a volatile organic compound from a gaseous environment; the sorbent system comprised of two graphene-based materials: (a) the aforementioned graphene oxide, and (b) a nitrogen and oxygen-functionalized graphene. The sorbents are regenerable under a pressure gradient with little or no application of heat. The processes are operable through multiple adsorption-desorption cycles and are applicable to purifying and revitalizing air contaminated with ammonia and organic compounds as may be found in spacesuits, aerospace cabins, underwater vehicles, and other confined-entry environments.

Abstract: An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

Abstract: A thermophotovoltaic generator incorporating a two-stage combustor for providing heat to a thermophotovoltaic cell. Combustor parts include a partial oxidation reactor, which functions catalytically to convert a hydrocarbon fuel and a first supply of an oxidant into a gaseous partial oxidation product; and further include downstream thereof, a deep oxidation reactor including a premixer plenum fluidly connected to a heat spreader comprising a porous matrix, such as a ceramic foam. Functionally, the deep oxidation reactor converts the gaseous partial oxidation product and a second supply of oxidant into complete combustion products. Heat produced by the two-stage combustor generates radiative energy from a photon emitter, which is directly converted to electricity in a photovoltaic diode cell.

Abstract: A thermally integrated hotbox apparatus combining a steam reformer, a plurality of solid oxide fuel cell (SOFC) stacks, a plurality of oxidant manifolds, and at least one heat extractor. The steam reformer occupies a central position in the hotbox, around which are disposed in spaced-apart relation a plurality of SOFC stacks. A burner may be associated with the steam reformer, either within or outside the hotbox. An oxidant manifold is disposed between each pair of adjacent SOFC stacks. A heat exchanger is incorporated between an SOFC stack and an oxygen manifold. The hotbox design optimally captures thermal heat from the SOFC stacks for use in producing steam and operating the endothermic steam reformer. The apparatus reduces duty cycle of the burner, which produces heat and steam needed for operation of the endothermic steam reformer.

Abstract: A catalytic solar reactor useful in chemical processes, more particularly, useful in endothermic chemical processes. The reactor comprises a reaction pathway defined by an exterior wall and an interior wall, the exterior wall comprising a solar radiation receiver capable of converting solar radiation into heat and transmitting the heat to the reaction pathway. Further, the reaction pathway has disposed therein, in alternating fashion, a plurality of catalytic elements and a plurality of heat transfer elements. Optionally, a supplementary heater, such as a conventional fossil fuel burner, is disposed in a plenum located within the interior of the reactor. The heater is employed as a supplemental source of heat, for example, when solar radiation is unavailable.

Abstract: A catalytic reactor constructed of a thermally conductive housing defining a reaction zone having disposed therein: (a) a plurality of catalytic elements, each comprising a porous material having a catalyst supported thereon, and (b) a plurality of heat transfer elements, each comprising a porous, thermally conductive, and essentially catalytically inactive material; wherein the plurality of catalytic elements and the plurality of heat transfer elements are disposed in an alternating configuration within the reaction zone. The catalytic reactor is useful in chemical reactions where heat transfer is a rate limiting step.

Abstract: An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an in oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

Abstract: A first process and sorbent for removing ammonia from a gaseous environment, the sorbent comprised of graphene oxide having supported thereon at least one compound selected from metal salts, metal oxides and acids, each of which is capable of adsorbing ammonia. A second process and sorbent system for removing ammonia and a volatile organic compound from a gaseous environment; the sorbent system comprised of two graphene-based materials: (a) the aforementioned graphene oxide, and (b) a nitrogen and oxygen-functionalized graphene. The sorbents are regenerable under a pressure gradient with little or no application of heat. The processes are operable through multiple adsorption-desorption cycles and are applicable to purifying and revitalizing air contaminated with ammonia and organic compounds as may be found in spacesuits, aerospace cabins, underwater vehicles, and other confined-entry environments.

Abstract: A process of removing a volatile organic compound (VOC) from a gaseous environment, involving contacting a gaseous feedstream containing one or more VOC's, such as an odoriferous compound, an irritant, a contaminant or pollutant, for example, formaldehyde, with a sorbent under conditions sufficient to reduce the concentration of the VOC's in the gaseous feedstream. The sorbent is comprised of a functionalized graphene prepared by amination of graphene oxide. The sorbent is regenerated by adsorbate desorption under mild conditions of air flow. The process can be run through multiple adsorption-desorption cycles in a single fixed bed or swing bed configuration, and is applicable to purifying indoor air and ventilation air as well as reducing pollutants in industrial waste gas streams.

Abstract: A reforming process and apparatus exhibiting improved catalyst longevity towards reforming a high sulfur-containing liquid fuel. The process involves contacting in a first reforming zone a first oxidant and a liquid fuel containing high molecular weight organosulfur compounds with a partial oxidation catalyst under CPOX reaction conditions to form a first reformate stream containing a mixture of unconverted and partially-converted hydrocarbons and one or more low molecular weight sulfur compounds; and then contacting in a second reforming zone the first reformate stream with steam and optionally a second oxidant in the presence of an autothermal reforming catalyst under ATR reaction conditions to form a second reformate stream containing carbon monoxide and hydrogen and one or more low molecular weight sulfur compounds. The low molecular weight sulfur compounds can be readily removed from the first and/or second reformate streams by gas phase adsorption methods.

Abstract: A method for operating a hydrogen-fueled gas turbine is provided wherein a supply of fuel is passed to a gas turbine combustor, and a supply of nitrogen and sufficient air to provide at least sufficient compressed air to the gas turbine for fuel combustion is passed to a compressor. A sufficient portion of the compressor discharge flow is passed to a combustor for fuel rich combustion of the fuel flow to the combustor and the fuel is combusted to produce hot combustion gases that are, in turn, passed to a turbine.

Abstract: A method for low NOx combustion, without premixing of fuel and air prior to passage to a combustor, is provided wherein a fuel is injected into a reaction zone via an eductor thereby inducing an air flow and producing a fuel-rich mixture. The fuel-rich mixture is reacted and produces partial reaction products plus heat. A portion of the heat is to transferred to a cooling air stream and the cooled partial reaction products are brought into contact with the heated cooling air stream for combustion. Increased injection of the fuel results in an increased induction of the air flow.

Abstract: The present invention is an apparatus for the gasification of liquid fuels, involving: (a) a nozzle for atomizing and feeding a liquid fuel into a mixing region; (b) an inlet for feeding an oxidizer into the mixing region; (c) the mixing region for mixing the atomized fuel with the oxidizer; (d) a radiation hot box for vaporizing the liquid fuel, the radiation hot box comprising an ignition source positioned inside coiled catalytic reactor; (e) the coiled catalytic reactor comprising a coiled metal screen providing for a radial flow path from an inner diameter to an outer diameter of the coiled metal screen and providing for a plurality of void volumes in random order along the flow path from the inner diameter to the outer diameter; and (f) an outlet for exiting a gaseous reformate.

Abstract: A process of catalytic partial oxidation of a hydrocarbon fuel with an oxidant to produce partially-oxidized reaction products including hydrogen, with simultaneous in-situ coke removal. The process involves feeding a hydrocarbon fuel and an oxidant to a reactor in a fuel-rich feed ratio; reacting the fuel and oxidant for a fuel-rich cycle-time so as to produce a partially-oxidized reaction product; varying the fuel feed, or the oxidant feed, or both feeds to produce a fuel-lean feed to the reactor; maintaining the fuel-lean feed for a fuel-lean cycle-time sufficient to reduce coke deposits while maintaining a substantially constant yield of partially-oxidized reaction product; and alternating between the fuel-rich and fuel-lean operating cycles.

Abstract: A Sabatier process involving contacting carbon dioxide and hydrogen in a first reaction zone with a first catalyst bed at a temperature greater than a first designated temperature; feeding the effluent from the first reaction zone into a second reaction zone, and contacting the effluent with a second catalyst bed at a temperature equal to or less than a second designated temperature, so as to produce a product stream comprising water and methane. The first and second catalyst beds each individually comprise an ultra-short-channel-length metal substrate. An apparatus for controlling temperature in an exothermic reaction, such as the Sabatier reaction, is disclosed.

Abstract: The present invention provides a combustor for an aerospace gas turbine engine comprising two stages wherein each stage defines an inlet and an exit. The second stage inlet is in fluid communication with the first stage exit such that a first flowpath is defined and it passes substantially through the second stage. A plurality of flow channel tubes is positioned within the second stage and each flow channel tube passes sealingly through a header plate positioned upstream of the second stage inlet thereby defining a second flowpath that also passes substantially through the second stage. The first flowpath exit and the second flowpath exit are positioned adjacent and proximate to one another to provide for the generation of microflames or microflame jets exiting the second stage from between and around the flow channel tube exits. The first stage of the combustor provides a gasifier and a reformer.

Abstract: A Sabatier process involving contacting carbon dioxide and hydrogen in a first reaction zone with a first catalyst bed at a temperature greater than a first designated temperature; feeding the effluent from the first reaction zone into a second reaction zone, and contacting the effluent with a second catalyst bed at a temperature equal to or less than a second designated temperature, so as to produce a product stream comprising water and methane. The first and second catalyst beds each individually comprise an ultra-short-channel-length metal substrate. An apparatus for controlling temperature in an exothermic reaction, such as the Sabatier reaction, is disclosed.

Abstract: A process of reforming a liquid fuel comprising from greater than 50 ppmw sulfur to less than 400 ppmw sulfur, the process comprising contacting a liquid hydrocarbon fuel comprising one or more organosulfur compounds in a concentration from greater than 50 ppmw to less than 400 ppmw sulfur with an oxidant and steam or water, the contacting occurring in a catalyst bed comprising a reforming catalyst deposited on an ultra-short-channel-length metal substrate, such that the process is conducted at a peak catalyst temperature greater than 950° C. so as to produce a reformate mixture comprising hydrogen and carbon monoxide.

Abstract: A novel catalytic reactor is provided for controlling the contact of a limiting reactant with a catalyst surface. A first flow vessel defines an interior surface and an exterior surface, and the interior surface has a catalyst deposited on at least a portion thereof. A second flow vessel is positioned within the first flow vessel and the second flow vessel defines a porous surface designed to deliver a fluid uniformly to at least a portion of the interior surface of the first flow vessel.