Abstract: Disclosed is an electrochemical polymerization process for preparation of crosslinked gel. The process includes mixing a hydroxylated benzene and aldehyde in an aqueous media in an inert container to form a hydroxylated benzene and aldehyde mixture. Furthermore, the process includes introducing electrodes into the inert container. Further, the electrochemical polymerization process includes supplying electric current to the hydroxylated benzene and aldehyde mixtures in the inert container through the electrodes. The resultant products of electrochemical polymerization process either gels or activated carbon gels have unique characteristics.