Patents Assigned to QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
  • Publication number: 20250011479
    Abstract: Disclosed are an iron-based catalyst and its application catalytic diene polymerization. The iron-based catalyst provided by the present application includes iron-containing organic compounds, alkyl aluminum compounds and isocyanide-containing organic compounds, and the molar ratio between the iron element of the iron-containing organic compounds, the alkyl aluminum compounds and the isocyanide-containing organic compounds is 1:(5˜100):(0.5˜100). The iron-based catalyst system of the present application can initiate polymerization of diene with high activity at high temperature by using isocyanide-containing organic compounds as an electron donor and alkyl aluminum compounds as a co-catalyst.
    Type: Application
    Filed: June 24, 2024
    Publication date: January 9, 2025
    Applicant: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Chunyu ZHANG, Yingnan ZHAO, Lihua NA, Heng LIU, Xuequan ZHANG
  • Publication number: 20250011515
    Abstract: Disclosed is a method of adjusting the molecular weight of syndiotactic 1,2-polybutadiene prepared using an iron-based catalyst. In the present application, when an iron-based catalyst catalyzes the polymerization of butadiene to prepare syndiotactic 1,2-polybutadiene, alpha-olefins are added as a molecular weight regulator, and a chain transfer effect is achieved through competitive adsorption. At the same time, since alpha-olefins are stable to iron-based catalysts, cannot be initiated to polymerize, and are easy to separate from butadiene, they have a significant effect on molecular weight regulation and do not have a significant effect on activity, making it possible to prepare syndiotactic 1,2-polybutadiene thermoplastic elastomers with number average molecular weights ranging from 3,000-250,000. The syndiotactic 1,2-polybutadiene rubber prepared by the present application has better processability.
    Type: Application
    Filed: June 24, 2024
    Publication date: January 9, 2025
    Applicant: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Chunyu ZHANG, Shiliang XU, Yao YU, Heng LIU, Xuequan ZHANG
  • Patent number: 12072276
    Abstract: An online measurement device for crystal size and shape in a high-solid-content crystallization process includes a solution amplifier, a measurement device, a peristaltic pump, a crystallization kettle, a dilution device and a solution storage tank. A crystal-containing solution is arranged in the crystallization kettle; an inner wall of the solution amplifier is smooth, one end is an amplification end, and the other end is a contraction end. The contraction end is communicated with one end of the solution storage tank and one end of the crystallization kettle. The amplification end is communicated with the dilution device and the peristaltic pump. The peristaltic pump is communicated with the other end of the crystallization kettle. The solution amplifier, the peristaltic pump and the crystallization kettle form a complete passage through a pipeline. A measurement instrument of the measurement device is arranged at the outer side of the solution amplifier.
    Type: Grant
    Filed: November 8, 2021
    Date of Patent: August 27, 2024
    Assignee: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Fangkun Zhang, Zidong Ai, Bing Wu, Baoming Shan
  • Publication number: 20240279452
    Abstract: Disclosed are a high temperature blasting resistance isotactic polybutene alloy and a preparation method thereof. The isotactic polybutene alloy of the present invention comprises 1-40% of isotactic polypropylene in parts by mass, 0.1-10% of a polypropylene-polybutene-1 block copolymer in parts by mass, 35-95.9% of isotactic polybutene-1 of a medium molecular weight in parts by mass, and 3-15% of isotactic polybutene-1 of a high molecular weight in parts by mass. The alloy material is prepared using a method of segmented polymerization of propylene polymerization, high hydrogen content butene polymerization and low hydrogen content butene polymerization. The prepared isotactic polybutene alloy has excellent high temperature blasting resistance and high temperature hydrostatic pressure, is high in vicat softening temperature, and is applicable to pressure pipes.
    Type: Application
    Filed: April 29, 2024
    Publication date: August 22, 2024
    Applicant: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Aihua HE, Chenguang LIU, Huafeng SHAO
  • Patent number: 11987567
    Abstract: The present invention discloses a synthesis method of lactide by confinement effect catalysis of crystalline porous polymer material, wherein the method comprising: (I) synthesis of catalyst; (II) synthesis of lactide by confinement effect catalysis; and (III) purification of lactide. In the present invention, a yield of L-lactide by catalysis of L-lactic acid by crystalline polymers is as high as 85.6%, which is 10% higher than the yield of lactide by H-? molecular sieve reported in documents currently available; it is easy to prepare the crystalline porous polymer material catalyst, which is environmental friendly, has a high yield and is recyclable, for consecutive 7 times the catalysis yield is maintained to be higher than 70%, and catalysis yield conservation rate is far higher than catalysis effects of catalysts reported in documents currently available.
    Type: Grant
    Filed: August 31, 2022
    Date of Patent: May 21, 2024
    Assignee: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Yingjie Zhao, Wenqi Qiu, Hui Liu, Zhenxiu Zhang, Jinyu Zhao
  • Patent number: 11808678
    Abstract: A system for a deep-sea planktonic microorganism in-situ concentration, temperature maintaining and pressure maintaining sampling is provided and includes a sampling cylinder body with double layer structures, the sampling cylinder body is provided with a plug-shaped inner cavity, the plug-shaped inner cavity is provided with a transfer water outlet and a water inlet connected to a water inlet component, the plug-shaped inner cavity is connected to an end cover, the plug-shaped inner cavity is connected to a filter part, the sampling cylinder body is provided with a sampling water outlet, the sampling water outlet is respectively connected to a pressure maintaining device and a water outlet pipe, a temperature maintaining material layer and a temperature control component are connected between the double layer structures, and the temperature control component is electrically connected to a controller. The system can complete sampling on the premise of maintaining in-situ pressure of samples.
    Type: Grant
    Filed: April 7, 2022
    Date of Patent: November 7, 2023
    Assignee: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Ping Fu, Junfei Wu, Siyang Wu, Yang Bai, Yuting Zhou, Guangxu Luan, Shuo Yin, Mingsai Zhang, Chenxu Wang
  • Patent number: 11624670
    Abstract: A measuring device for pore throat pressure of Jamin effect based on mechanochromic materials is provided and includes: a bubble pressurization part, configured to inject bubbles into a microscopic visualization test part; the microscopic visualization test part including a mechanochromic material and a pore throat structure, configured to characterize changes of pore throat pressure during bubble injection; a waste liquid recycling part, configured to recycle bubble waste liquid passing through the microscopic visualization test part; a data acquisition and analysis part, configured to acquire changing data of the pore throat pressure in the microscopic visualization test part and analyze the changing data to obtain the pore throat pressure. The device is simple in structure and easy to operate, and provides a method for measuring an internal surface pressure of an object. The method can realize a real time measurement of the pore throat pressure of Jamin effect.
    Type: Grant
    Filed: October 18, 2022
    Date of Patent: April 11, 2023
    Assignee: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventor: Fei Wang
  • Patent number: 11242362
    Abstract: Provided are a phosphazene compound, a method for preparing a phosphazene compound and a method for producing a polymer with a phosphazene compound as a catalyst. The compound of formula (I) or a solvate thereof, where A is a six- or eight-membered ring consisting of repeated P?N, and B is at least one of unsubstituted or substituted C1-6 alkylamino, unsubstituted or substituted C1-6 cycloalkylamino, unsubstituted or substituted arylamino, or halogen, and B is attached to A at phosphorus in P?N, where R is unsubstituted or substituted C1-6 alkyl, unsubstituted or substituted C1-6 cycloalkyl, unsubstituted or substituted aryl, or unsubstituted or substituted benzyl, or R forms C1-6 heterocycloalkyl together with N attached thereto.
    Type: Grant
    Filed: June 19, 2019
    Date of Patent: February 8, 2022
    Assignee: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Zhibo Li, Na Zhao, Chuanli Ren, Xiaohui Fu, Shaofeng Liu
  • Patent number: 10988561
    Abstract: A method for industrial production of a butadiene-isoprene copolymer rubber having a trans-1,4-structure (TBIR) and an apparatus for implementing the method. The production method includes: pumping a predetermined amount of a butadiene and an isoprene into a polymerization reactor, and performing bulk polymerization in the presence of a catalyst to obtain TBIR; performing extrusion, devolatilization, granulation and drying on the produced TBIR, and then packaging the produced TBIR; and separating unreacted monomers by a recovery and separation device followed by separately refining the unreacted monomers, and then returning the unreacted monomers to a batching device or a storage tank. The production apparatus has a recovery and refining unit, a polymerization unit, a post-treatment unit and a utility unit. By the production apparatus and the production method industrial production of TBIR by bulk polymerization is realized.
    Type: Grant
    Filed: November 15, 2016
    Date of Patent: April 27, 2021
    Assignees: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY, SHANDONG HUAJU POLYMER MATERIALS CO., LTD., CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE CO., LTD.
    Inventors: Aihua He, Yunsheng Ma, Huafeng Shao, Gang Yao, Chenguang Liu, Bo Luan, Riguo Wang
  • Publication number: 20180201714
    Abstract: A method for industrial production of a butadiene-isoprene copolymer rubber having a trans-1,4-structure (TBIR) and an apparatus for implementing the method. The production method includes: pumping a predetermined amount of a butadiene and an isoprene into a polymerization reactor, and performing bulk polymerization in the presence of a catalyst to obtain TBIR; performing extrusion, devolatilization, granulation and drying on the produced TBIR, and then packaging the produced TBIR; and separating unreacted monomers by a recovery and separation device followed by separately refining the unreacted monomers, and then returning the unreacted monomers to a batching device or a storage tank. The production apparatus has a recovery and refining unit, a polymerization unit, a post-treatment unit and a utility unit. By the production apparatus and the production method industrial production of TBIR by bulk polymerization is realized.
    Type: Application
    Filed: November 15, 2016
    Publication date: July 19, 2018
    Applicants: QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY, SHANDONG HUAJU POLYMER MATERIALS CO., LTD., CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE CO., LTD.
    Inventors: Aihua HE, Yunsheng MA, Huafeng SHAO, Gang YAO, Chenguang LIU, Bo LUAN, Riguo WANG