Abstract: The present application discloses a zinc oxide-crystalline silicon laminated solar cell and a preparation method thereof, relates to the technical field of solar cells, and aims to solve the technical problem of low photoelectric conversion rate of existing solar cells. The zinc oxide-crystalline silicon laminated solar cell includes: a P-type silicon substrate layer; a front surface of the P-type silicon substrate layer being sequentially formed with, from bottom to top, a diffusion layer, an N-type zinc oxide layer, a first passivation layer, and a first antireflection layer; wherein the N-type zinc oxide layer is made of tetrapod-like N-type zinc oxide whisker powder as a raw material; and a back surface of the P-type silicon substrate layer being sequentially formed with, from top to bottom, a second passivation layer and a second antireflection layer; and an electrode, the electrode including a front electrode and a back electrode.