Abstract: Solid catalysts suited for the fluidized/moving bed catalytic ammoxidation of alkanes comprise an active catalytic phase having the empirical formula (I):
VSbaSnbTicFedEeOx (I)
in which E is an element which provides an oxide of rutile structure or an element which, in combination with V, Sb, Sn, Ti, Fe and/or with another element E, provides a phase of rutile or trirutile structure, or a solid solution of rutile structure, a is a whole or fractional number equal to or greater than 0.
Abstract: Catalyst compounds comprising at least one transition metal having an oxidation number of 0 or 1 and at least one sulfonated phosphine are electrochemically synthesized, by electrolyzing an aqueous solution catholyte (contained in the cathode compartment of any suitable electrolytic cell) comprising at least one transition metal compound and at least one sulfonated phosphine.
Type:
Grant
Filed:
December 6, 1995
Date of Patent:
October 21, 1997
Assignee:
R. P. Fiber & Resin Intermediates
Inventors:
Alex Chamard, Dominique Horbez, Marc Huser, Robert Perron