Abstract: Presented and described is a hydrocarbon resin obtainable by thermal polymerization of a cyclic diolefin component including a cyclic diolefin compound with an aromatic component including indene and/or C1-4-alkylindene, with the hydrocarbon resin having a polydispersity index (PDI) of 1 to less than 2.3. Further described is a production process for the hydrocarbon resin, wherein a monomer mixture which includes an aromatic component including indene and/or C1-4-alkylindene and a cyclic diolefin component including a cyclic diolefin compound is polymerized by heating to a polymerization temperature of at least 180° C. to give a product stream including hydrocarbon resin, and oligomers which include units originating from the cyclic diolefin compound and/or units originating from the aromatic component are separated from the product stream and returned to the monomer mixture.
Type:
Grant
Filed:
February 12, 2021
Date of Patent:
May 7, 2024
Assignee:
Rain Carbon Germany GmbH
Inventors:
Manuel Nau, Björn Dreisewerd, Jun Liu, Edgar Fuhrmann, Matthias Heitmann
Abstract: The invention relates to a method for producing a hydrocarbon resin, in which method a monomer mixture which contains an aromatic component containing indene and/or C1-4 alkylindene and a cyclic diolefin component containing a cyclic diolefin compound is polymerized by heating to a polymerization temperature of at least 180° C. to obtain a product stream containing hydrocarbon resin, wherein oligomers which contain units originating from the cyclic diolefin compound and/or units originating from the aromatic component are separated from the product stream and returned to the monomer mixture, and wherein the hydrocarbon resin is heated in an annealing step to a temperature of 150° C. to 300° C. for a period of 15 minutes to 240 hours. The invention also relates to a hydrocarbon resin that is obtainable by the method, to a hydrogenated hydrocarbon resin, and to the use of the hydrocarbon resin and the hydrogenated hydrocarbon resin.
Abstract: A low molar mass polymeric hydrocarbon tackifier having a number average molar mass Mn of from 200 to 1,500 g/mol provides increased green tack stability over an extended period of time in rubber compounds.