Abstract: The present disclosure provides a new and improved process for preparation of intermediate compounds and synthesis of mesotrione therefrom. The present disclosure provides an economical, efficient and eco-friendly process for preparation of mesotrione.
Type:
Application
Filed:
July 31, 2021
Publication date:
September 28, 2023
Applicant:
RALLIS INDIA LIMITED
Inventors:
A.S. PANIRAJ, Suresh D. KUMAR, Adithya S.V.R.
Abstract: The present disclosure provides process for preparation of azimsulfuron or its salts, isomers, and other derivatives thereof. The process involves treating a compound of formula I, with aqueous acetic acid or formic acid and chlorine gas or sodium hypochlorite in presence of hydrochloric acid in chlorinated solvents such as dichloromethane, 1,2-dichloroethane or with aqueous acetic acid and N-chlorosuccinimide or hydrogen peroxide in presence of hydrochloric acid in aqueous cyclic ether such as tetrahydrofuran, 1,4-dioxane to obtain 1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H-pyrazole-5-sulfonyl chloride; converting the sulfonyl chloride to a sulfonamide and treating the sulfonamide with a phenyl(4,6-dimethoxypyrimidin-2-yl) carbamate to obtain azimsulfuron or its salts, isomers, and other derivatives thereof.
Type:
Application
Filed:
April 12, 2013
Publication date:
April 23, 2015
Applicant:
RALLIS INDIA LIMITED
Inventors:
Jivan Dhanraj Pawar, Sanjay Sambhajirao Palimkar, B. Sankar, Subhash Rajaram Kadam, Rama Mohan Hindupur, Venkatesh M. Prabhu, Hari Narayan Pati, Vadiraj Gopinath Suphala, Avinash Sheshrao Mane