Abstract: An elastomeric composite polyurethane skin having an average flexural modulus, measured in accordance with ASTM D790-03, smaller than 35 MPa is disclosed. The elastomeric composite polyurethane skin includes a first aliphatic polyurethane layer made from a first polyurethane reaction mixture having at least one isocyanate compound with at least two NCO-groups which are not directly attached to an aromatic group, at least one isocyanate-reactive component (B1), and at least one catalyst component (C1) substantially free of lead, and a second aromatic polyurethane layer made from a second polyurethane reaction mixture having at least one aromatic isocyanate compound (A2), and at least one isocyanate-reactive component (B2).

Abstract: The present invention relates to a method for producing an elastomeric grained skin which comprises at least an elastomeric skin layer and a coating layer overlying the skin layer. The skin has at least a portion which hasa grained surface, which comprises at least one elastomeric skin layer and which has at least one coating layer overlying the skin layer. To produce the skin a coating composition is applied onto at least a portion of a mould surface, which portion is grained, to produce said coating layer; and the elastomeric skin layer is moulded at least against a back side of said coating layer to produce said portion of the elastomeric skin. In order to accent the grain texture so that it stands out more clearly and so that the visibility thereof is less dependent on the direction of the incident light and the position of the viewer use is made of a coating composition which comprises effect pigment particles contained in a transparent or translucent medium.

Abstract: An elastomeric composite polyurethane skin having an average flexural modulus, measured in accordance with ASTM D790-03, smaller than 35 MPa is disclosed. The elastomeric composite polyurethane skin includes a first aliphatic polyurethane layer made from a first polyurethane reaction mixture having at least one isocyanate compound with at least two NCO-groups which are not directly attached to an aromatic group, at least one isocyanate-reactive component (B1), and at least one catalyst component (C1) substantially free of lead, and a second aromatic polyurethane layer made from a second polyurethane reaction mixture having at least one aromatic isocyanate compound (A2), and at least one isocyanate-reactive component (B2).

Abstract: The present invention relates to a method for manufacturing a flexible skin which has at least one insert adhered thereto. In a first step, the skin is molded on a mold surface. In order to adhere the insert to the skin, an opening is first made in the skin giving access to the back face of the insert. The insert is positioned with its back face against the front face of the skin and an adhering layer is provided which is adhesively connected to the back face of the skin layer which surrounds the opening in the skin layer and, through this opening, to the back face of the insert. The adhering layer is preferably produced by applying a layer of a hardenable material, in particular a curable polyurethane composition. Since the back face of the insert engages the front side of the skin penetration of hardenable material to the front face of the insert is avoided.

Abstract: The thermoset, phase-separated polyurethane material of the flexible skin layer is produced from a reactive mixture which is made of one or more isocyanate compounds and isocyanate reactive compounds which include one or more polyol compounds, flexibilizers, chain extenders and/or crosslinkers and amine-initiators. Apart from at least one crosslinking amine-initiator, these amine-initiators further include at least one extender amine-initiator.

Abstract: The present invention relates to a method of making an elastomeric skin (1) wherein droplets of at least one first skin forming composition (2) are applied onto a mould surface to form a layer of the first skin forming composition thereon and wherein one or more second skin forming compositions (4) are applied at least partially onto the back of the layer of said first skin forming composition (2) to produce the skin (1). In order to obtain a special visual appearance when using of differently colored first and second skin forming materials, or in order to reduce the effect of the first skin forming composition (2) on the overall physical properties of the skin (1), the droplets of the first skin forming composition (2) are applied onto the mould surface and are allowed to coalesce to form a non-continuous layer of the first skin forming composition which comprises a plurality of gaps (3).

Abstract: The present invention relates to a method for manufacturing a flexible skin which has at least one insert adhered thereto. In a first step, the skin is moulded on a mould surface. In order to adhere the insert to the skin, an opening is first made in the skin giving access to the back face of the insert. The insert is positioned with its back face against the front face of the skin and an adhering layer is provided which is adhesively connected to the back face of the skin layer which surrounds the opening in the skin layer and, through this opening, to the back face of the insert. The adhering layer is preferably produced by applying a layer of a hardenable material, in particular a curable polyurethane composition. Since the back face of the insert engages the front side of the skin penetration of hardenable material to the front face of the insert is avoided.

Abstract: The present invention relates to a method for producing a flexible elastomeric composite polyurethane skin wherein a polyurethane reaction mixture is sprayed onto a mold surface and the polyurethane reaction mixture is allowed to cure to produce the skin layer. The polyurethane reaction mixture is composed of components comprising at least an isocyanate component, isocyanate-reactive components and a catalyst component and the isocyanate component is composed of at least one isocyanate having at least two NCO-groups which are not directly attached to an aromatic group. The catalyst component is substantially free of lead, which leads to a lower flexibility. In accordance with the invention, the flexibility of the polyurethane skin is increased by means of at least one flexibiliser which reduces the flexural modulus of the skin and which comprises at least one isocyanate-reactive group. The flexibiliser is preferably a monofunctional flexibiliser which comprises only one isocyanate-reactive group.

Abstract: The invention relates to a method for producing a multilayered part which comprises a moulded core (5) and a flexible polyurethane skin layer (4). The core itself comprises a moulded substrate layer (1) which is made of a substrate material, in particular a thermoplastic material, having a Shore A hardness higher than 60. The flexible polyurethane skin (4) is produced by a reaction overmoulding (ROM) process wherein a polyurethane reaction mixture is moulded in a closed mould (11, 12) over at least a first area of the core surface. The moulded core (5) comprises in addition to said substrate layer (1) a softer material which is moulded onto the substrate layer (1) and/or onto which the substrate layer (1) is moulded. This moulded softer material has a Shore A hardness lower than 60 and forms a softer layer (2) between the flexible polyurethane layer (4) and the substrate layer (1) and/or a seal (3) engaging the internal wall of the mould (11, 12) during the ROM process.

Abstract: The thermoset, phase-separated polyurethane material of the flexible skin layer is produced from a reactive mixture which is made of one or more isocyanate compounds and isocyanate reactive compounds which comprise one or more polyol compounds, flexibilisers, chain extenders and/or crosslinkers and amine-initiators. Apart from at least one crosslinking amine-initiator, these amine-initiators further comprise at least one extender amine-initiator which has a functionality of 2 and a molecular weight of less than 300 and which corresponds to formula (I) HR1N—R2—OH??(I) wherein: R1 is H or a cyclic or acyclic hydrocarbon chain, which is substituted or not and which comprises one or more hetero-atoms or not, R1 being preferably H or a C1 to C6 alkyl group; and R2 is a hydrocarbon chain which is substituted or not, which comprises a hetero-atom or not and which comprises a backbone linking the amino group with the hydroxyl group and containing at least two carbon atoms.

Abstract: For producing a polyurethane layer by spraying a polyurethane reaction mixture, this mixture is supplied under pressure to a spray nozzle, within the nozzle the reaction mixture is accelerated by passing it through one or more channels having a reduced cross-sectional area, and the accelerated reaction mixture is sprayed, with a predetermined amount of kinetic energy, through a spray opening out of the spray nozzle onto a surface. The channels wherein the reaction mixture is accelerated have a total minimum cross-sectional area of S mm2, S being a value smaller than 1.0, the reaction mixture is sprayed out of the nozzle at a flow rate of between 10×S and 80×S g/sec, and, per gram reaction mixture, an amount of 0.05 to 2.5 mmol of a pressurized gas is sprayed together with the reaction mixture through said spray opening out of the nozzle to increase the kinetic energy of the reaction mixture which is sprayed out of the nozzle.

Abstract: The pressure swirl atomizing nozzle for spraying a curable composition comprises an orifice piece (16), which defines a funnel-shaped cavity and an exit orifice (17), and an injector piece (18) which closing off the funnel-shaped cavity so that the funnel-shaped cavity forms a swirl chamber (19) between a front side of the injector piece (18) and the exit orifice (17). The injector piece (18) comprises at least two swirl ports (20) which end in the swirl chamber (19) for injecting the curable composition therein and for thereby imparting swirl to the curable composition. Compared to the sum of the smallest cross-sectional areas of the swirl ports (20), the side wall (24) of the swirl chamber (19) has a relatively small surface area which is however still large enough to distribute the curable composition so as to achieve a uniform spray pattern. By the reduced size of the swirl chamber (19), the curable composition can be atomized more efficiently.

Abstract: The present invention relates to a method for producing a flexible elastomeric composite polyurethane skin wherein a polyurethane reaction mixture is sprayed onto a mould surface and the polyurethane reaction mixture is allowed to cure to produce the skin layer. The polyurethane reaction mixture is composed of components comprising at least an isocyanate component, isocyanate-reactive components and a catalyst component and the isocyanate component is composed of at least one isocyanate having at least two NCO-groups which are not directly attached to an aromatic group. The catalyst component is substantially free of lead, which leads to a lower flexibility. In accordance with the invention, the flexibility of the polyurethane skin is increased by means of at least one flexibiliser which reduces the flexural modulus of the skin and which comprises at least one isocyanate-reactive group. The flexibiliser is preferably a monofunctional flexibiliser which comprises only one isocyanate-reactive group.

Abstract: The three-dimensionally shaped sandwich structure is produced starting from a layered material (1) comprising a compressible core layer, in particular a paper honeycomb structure, having two opposite main faces which are each covered with a reinforcing material and with a mouldable material. The layered material (1) is moulded in a compression mould comprising two mutually movable mould sections (7, 9). In order to reduce the formation of cracks, tears or breaks in the core layer, the first mould section (7) is composed of at least two mutually movable mould parts (10 and 11-12). A first portion of the layered material (1) is first deep-drawn by moving the first mould part (10) towards its moulding position so that wrinkles are formed in the layered material and the second mould part (11-12) is moved later and/or more slowly than the first mould part (10) towards its moulding position.

Abstract: The present invention relates to a method for producing a flexible elastomeric composite polyurethane skin comprising a first and a second flexible polyurethane layer obtained by spraying a first and a second polyurethane reaction mixture onto one another. The first reaction mixture is an aliphatic polyurethane reaction mixture which is free of lead and formulated to produce a polyurethane elastomer having a flexural modulus smaller than 35 MPa. The second reaction mixture is an aromatic polyurethane reaction mixture producing a polyurethane elastomer having a smaller flexural modulus. The thickness of the aliphatic polyurethane layer could be made so small with respect to the thickness of the aromatic polyurethane layer that the composite skin has an average flexural modulus smaller than 30 MPa.

Abstract: The present invention relates to a method of making an elastomeric skin (1) wherein droplets of at least one first skin forming composition (2) are applied onto a mould surface to form a layer of the first skin forming composition thereon and wherein one or more second skin forming compositions (4) are applied at least partially onto the back of the layer of said first skin forming composition (2) to produce the skin (1). In order to obtain a special visual appearance when using of differently coloured first and second skin forming materials, or in order to reduce the effect of the first skin forming composition (2) on the overall physical properties of the skin (1), the droplets of the first skin forming composition (2) are applied onto the mould surface and are allowed to coalesce to form a non-continuous layer of the first skin forming composition which comprises a plurality of gaps (3).

Abstract: A method for manufacturing molded flexible plastic skins (9, 24, 27, 34) differing in their shape from each other, each skin being molded against a mold surface (2) of a mold (1), comprises the steps: —providing a mold surface (2) matching the shape of the skin to be molded by using a first mold surface provided by the mold itself or by altering the first mold surface by placing one or more mold inserts covering only a part of the first mold surface onto said mold surface and thereby providing an alternative second mold surface, —applying a plastic compound to be brought to shape by the mold surface (2) provided, —bringing to shape the plastic compound applied to the mold surface (2), and —demolding the molded skin (9) from the effective mold surface (2).

Abstract: A method for manufacturing moulded flexible plastic skins (9, 24, 27, 34) differing in their shape from each other, each skin being moulded against a mould surface (2) of a mould (1), comprises the steps:—providing a mould surface (2) matching the shape of the skin to be moulded by using a first mould surface provided by the mould itself or by altering the first mould surface by placing one or more mould inserts covering only a part of the first mould surface onto said mould surface and thereby providing an alternative second mould surface,—applying a plastic compound to be brought to shape by the mould surface (2) provided,—bringing to shape the plastic compound applied to the mould surface (2), and—demoulding the moulded skin (9) from the effective mould surface (2).

Abstract: The pressure swirl atomizing nozzle for spraying a curable composition comprises an orifice piece (16), which defines a funnel-shaped cavity and an exit orifice (17), and an injector piece (18) which closing off the funnel-shaped cavity so that the funnel-shaped cavity forms a swirl chamber (19) between a front side of the injector piece (18) and the exit orifice (17). The injector piece (18) comprises at least two swirl ports (20) which end in the swirl chamber (19) for injecting the curable composition therein and for thereby imparting swirl to the curable composition. Compared to the sum of the smallest cross-sectional areas of the swirl ports (20), the side wall (24) of the swirl chamber (19) has a relatively small surface area which is however still large enough to distribute the curable composition so as to achieve a uniform spray pattern. By the reduced size of the swirl chamber (19), the curable composition can be atomized more efficiently.

Abstract: The method according to the invention is a moulding method wherein a first layer (21), having a first colour, is produced against a first portion of a mould surface (10) and wherein, in a next step, a second layer (22), having a second colour, is produced against a second portion of the mould surface (10) and at least partially against the back of the first layer (21). The method is intended to obtain a qualitative transition between the colours of the two layers (21, 22) without having to hide the actual colour transition in a groove from view. This object is achieved by applying the material forming the first layer (21) in such a manner on the mould surface (10) that the edge (20) of the first layer (21), which will be situated on the mould surface underneath the second layer (22), is visually sharp and is produced without a mask.