Abstract: A method of treating, stabilizing, precipitating, or otherwise removing heavy metal ions contained in a contaminated media, which method includes: providing a sodium-iron-sulfide mineral or crystalline phase, either alone or in combination with a pH adjusting substance; contacting said contaminated media containing heavy metal ions with the sodium-iron-sulfide mineral or crystalline phase, either alone or in combination with a pH adjusting substance; and allowing the contaminated media containing the heavy metal ions to react with said sodium-iron-sulfide mineral or crystalline phase, either alone or in combination with a pH adjusting substance, such that the contaminated media containing heavy metal ions form single or mixed metal-sulfide precipitates or co-precipitates.
Abstract: A liquid suspension comprised of ferrous sulfide particles and method of using the same for the removal of selenium from industrial gas. Said liquid suspension may be (1) directly injected, or (2) coated onto or into a substrate and then injected into an industrial gas containing selenium to remove said selenium from the industrial gas stream in a dry scrubber system. Said liquid suspension of ferrous sulfide particles may also be used to remove selenium contained in industrial gases in a wet scrubber system.
Type:
Grant
Filed:
August 26, 2016
Date of Patent:
November 7, 2017
Assignee:
Redox Technology Group, LLC
Inventors:
Gary J. Meyer, Thomas P. McCullough, Anthony J. Kriech
Abstract: A wet gas scrubber liquor and method of using the same to remove mercury from flue gases. The wet gas scrubber liquid is an alkaline liquid suspension of ferrous sulfide particles that can be prepared by combining together a ferrous ion source such as ferrous chloride, a sulfide ion source such as sodium hydrosulfide and an alkalinity source such as sodium hydroxide. When used to scrub flue gases to remove mercury from flue gases the mercury reacts with said alkaline liquid suspension of ferrous sulfide particles and can be removed by at least one of: i) adsorption onto said ferrous sulfide particles; ii) adsorption onto iron (hydr)-oxides that form in said alkaline liquid suspension of ferrous sulfide particles; and iii) absorption by reacting with sulfur formed in alkaline liquid suspension of ferrous sulfide particles and forming mercuric sulfide as a precipitate.
Type:
Grant
Filed:
March 7, 2014
Date of Patent:
July 7, 2015
Assignee:
Redox Technology Group, LLC
Inventors:
Thomas P. McCullough, Gary Joel Meyer, Ralph E. Roper, Jr., Anthony J. Kriech
Abstract: A ferrous sulfide suspension that includes at least FeSm and Al(OH)3 and which can be used to reduce mercury emissions in flue gases. Through a combination of complex chemical reactions, precipitation, co-precipitation, and surface adsorption the ferrous sulfide suspension of the present invention effectively removes mercury from gaseous streams while concurrently preventing mercury re-emission.
Type:
Grant
Filed:
February 28, 2014
Date of Patent:
May 19, 2015
Assignee:
Redox Technology Group LLC
Inventors:
Thomas P. McCullough, Gary Joel Meyer, Ralph E. Roper, Jr., Anthony J. Kriech