Abstract: A reactive-separation process converts glycerin into lower alcohols, having boiling points less than 200° C., at high yields. Conversion of natural glycerin to propylene glycol through an acetol intermediate is achieved at temperatures from 150° to 250° C. at pressures from 1 and 25 bar. The preferred applications of the propylene glycol are as an antifreeze, deicing compound, or anti-icing compound. The preferred catalyst for this process in a copper-chromium.
Type:
Grant
Filed:
August 28, 2006
Date of Patent:
September 13, 2011
Assignees:
The Curators Of the University Of Missouri, Renewable Alternatives LLC
Inventors:
Galen J. Suppes, William Rusty Sutterlin
Abstract: A reactive-separation process converts glycerin into lower alcohols, having boiling points less than 200° C., at high yields. Conversion of natural glycerin to propylene glycol through an acetol intermediate is achieved at temperatures from 150° to 250° C. at a pressure ranging from 1 and 25 bar. The preferred applications of the propylene glycol are as an antifreeze, deicing compound, or anti-icing compound. The preferred catalyst for this process in a copper-chromium powder.
Type:
Grant
Filed:
December 22, 2009
Date of Patent:
October 19, 2010
Assignees:
The Curators of the University of Missouri, Renewable Alternatives LLC
Inventors:
Galen J. Suppes, William Rusty Sutterlin, Mohanprasad Dasari
Abstract: A reactive-separation process converts glycerin into lower alcohols, having boiling points less than 200° C., at high yields. Conversion of natural glycerin to propylene glycol through an acetol intermediate is achieved at temperatures from 150° to 250° C. at a pressure ranging from 1 and 25 bar. The preferred applications of the propylene glycol are as an antifreeze, deicing compound, or anti-icing compound. The preferred catalyst for this process in a copper-chromium powder.
Type:
Grant
Filed:
March 24, 2005
Date of Patent:
February 16, 2010
Assignees:
The Curators of the University of Missouri, Renewable Alternatives LLC
Inventors:
Galen J. Suppes, William Rusty Sutterlin, Mohanprasad Dasari