Abstract: A system and method are for separating the layers of multilayer plastics, the fragments of multilayer plastic being carried into a receptacle (1) pressurized for 10 to 60 seconds. The receptacle is pressurized using overheated vapor generated in a boiler and introduced into the receptacle until reaching a pressure between 1 and 12 bar and a temperature between 100 and 191.12° C. The fragments are then carried to a discharge tank at a relative pressure between ?0.7 and 0.1 bar and at a temperature between 15 and 25° C. for between 1 and 5 minutes. The multilayer fragments are later transferred to a mechanical separation unit where the fragments are separated into fragments of single-layer plastic and, lastly, to a mechanical sorting unit where the fragments are sorted by material.