Patents Assigned to Repsol S.A.
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Patent number: 12287443Abstract: A method for reconstructing at least one trace in a seismic image of a common receiver and time domain includes a convolutional neural network trained under an unsupervised learning approach with a modified receptive field.Type: GrantFiled: July 25, 2022Date of Patent: April 29, 2025Assignee: REPSOL, S.A.Inventors: Prashanth Nadukandi, Pablo Enrique Vargas Mendoza, Santiago Fernández Prieto, German Ocampo Botero, Wenyi Hu, Shirui Wang, Pengyu Yuan
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Patent number: 12258436Abstract: The present invention refers to the use of hydrofoil impellers for the preparation of polymer polyols and to a method for preparing a polymer polyol, which comprises reacting a base polyol, at least one ethylenically unsaturated monomer and a macromer or a preformed stabilizer in the presence of a free-radical initiator and optionally a chain transfer agent in a reactor, wherein said reactor is stirred by means of a stirring system comprising a shaft rotatable about its longitudinal axis, and a plurality of radially extending hydrofoil impellers mounted on the shaft and respectively axially spaced apart and wherein the reactor does not contain baffles.Type: GrantFiled: November 29, 2023Date of Patent: March 25, 2025Assignee: REPSOL, S.AInventors: Juan Pedro Pérez Valencia, José Antonio Carazo Angulo, Félix Fernández Villar
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Publication number: 20250034465Abstract: The present invention relates to a process for the treatment of a plastics pyrolysis oil, comprising: a) the hydrogenation of said feedstock as a mixture with at least a part of the liquid effluent resulting from stage c) and in the presence of hydrogen and of a catalyst at a temperature between 14° and 340° C.; b) the hydrotreating of said hydrogenated effluent in the presence of hydrogen and of a catalyst; c) a separation of the hydrotreated effluent operated at high temperature and high pressure, in order to obtain a gaseous effluent and a liquid effluent, a part of which is recycled upstream of stage a), d) a separation operated at low temperature and high pressure and fed with the gaseous effluent and the other part of the liquid effluent resulting from stage c) and an aqueous solution, in order to obtain a hydrocarbon effluent.Type: ApplicationFiled: November 23, 2022Publication date: January 30, 2025Applicants: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Wilfried WEISS, Dominique DECOTTIGNIES, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA, Martin SANTOS MARTINEZ, Sheyla CARRASCO HERNANDEZ
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Patent number: 12111252Abstract: A method for sorting flexible polyurethane foams including: a) providing two or more calibration samples of conventional flexible polyurethane foams, two or more calibration samples of high resilience (HR) flexible polyurethane foams, and two or more calibration samples of viscoelastic flexible polyurethane foams, and obtaining a mid-infrared (MIR) spectrum of each calibration sample; b) carrying out a spectral pre-processing of the spectra of all the calibration samples and, then a first PCA to define a first library; c) carrying out a spectral pre-processing of the infrared spectra of conventional and HR calibration samples and, then a second PCA to define a second library; d) obtaining the MIR spectrum of a sample of polyurethane foam and, based on the first and second libraries, classifying the sample of polyurethane foam as a conventional, HR or viscoelastic polyurethane foam, or as a foam that is neither a conventional, a HR or a viscoelastic polyurethane foam.Type: GrantFiled: June 17, 2022Date of Patent: October 8, 2024Assignee: REPSOL, S.A.Inventors: Miguel Rubio Moreno, Francisco Javier Carvajal González, Sonia Segura Fernández, Enrique Domínguez Ramos
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Patent number: 12024672Abstract: Methods of cementing, cementing compositions made from the methods, and articles manufacturable by the cementing compositions are disclosed. The method can include mixing a cement composition and water to make a cement slurry and applying to the cement slurry an alternating magnetic field of from 25 mT to 60 mT at a frequency from 50 kHz to 200 kHz in order to set the cement slurry. The cement composition can have a cement and an amount of magnetic nanoparticles from 0.01 wt % to 10 wt % relative to the amount of cement (0.01% to 10% BWOC). The magnetic nanoparticles can have a mean particle size determined by Transmission Electron Microscopy (TEM) from 10 nm to 50 nm and a crystallite size determined by the Scherrer equation which is at least an 80% the mean particle size.Type: GrantFiled: December 7, 2020Date of Patent: July 2, 2024Assignee: REPSOL, S.A.Inventors: María Ángeles González Fernández, Ricardo Bezerra De Melo, Luisa María Fraga Trillo, Sabino Veintemillas Verdaguer, Álvaro Gallo Córdova, María Del Puerto Morales Herrero
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Patent number: 11987661Abstract: The present invention relates to new modified polymer polyols comprising at least one polyol and a stable dispersion of polymeric particles in the at least one polyol. The dispersed polymeric particles having a high content of P and N. There are also disclosed processes for the preparation of the herein described modified polymer polyols, and processes for preparing polyurethane materials containing them.Type: GrantFiled: July 6, 2018Date of Patent: May 21, 2024Assignee: REPSOL, S.A.Inventors: César Muñoz De Diego, Victoria Isabel Blasco Garcés, Olivier Lemoine
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Patent number: 11912812Abstract: The present invention relates to new stable modified polymer polyol dispersions. The modified polymer polyols of the present invention comprise at least one polyol and a stable dispersion of polymeric particles in the at least one polyol. There are also disclosed processes for the preparation of the herein described modified polymer polyols, and processes for preparing polyurethane materials containing them.Type: GrantFiled: December 17, 2020Date of Patent: February 27, 2024Assignee: REPSOL, S.A.Inventors: César Muñoz De Diego, José Román Galdámez Peña, Victoria Isabel Blasco Garcés, Olivier Lemoine
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Publication number: 20240059977Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) hydrogenation of said feedstock in the presence of at least hydrogen and of at least one hydrogenation catalyst at an average temperature of between 140 and 340° C., the outlet temperature of step a) being at least 15° C. higher than the inlet temperature of step a), to obtain a hydrogenated effluent; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent, the average temperature of step b) being higher than the average temperature of step a); c) separation of the hydrotreated effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: ApplicationFiled: December 21, 2021Publication date: February 22, 2024Applicants: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Wilfried WEISS, Dominique DECOTTIGNIES, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA, Lidia ESCUDERO CASTEJON
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Patent number: 11885032Abstract: The present invention relates to an electrochemical device and a method for operating the electrochemical device for inducing specific behaviours in its chemical kinetics by supplying externally selected random (stochastic) voltage perturbations while the electrochemical system is operating in a non-oscillatory regime.Type: GrantFiled: December 19, 2018Date of Patent: January 30, 2024Assignee: REPSOL, S.A.Inventors: María Dolores Hernández Alonso, Valentín Ruíz Santa Quiteria, Juan Pérez Mercader
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Publication number: 20230287283Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) the selective hydrogenation of said feedstock to obtain a hydrogenated effluent; b) hydrotreatment of said hydrogenated effluent to obtain a hydrotreatment effluent; c) a first step of hydrocracking of said hydrotreated effluent to obtain a first hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, to obtain a gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent; e) fractionation of the hydrocarbon-based liquid effluent to obtain at least one gas stream and at least one naphtha cut and a heavier cut; f) a second step of hydrocracking of the heavier cut to obtain a second hydrocracked effluent; g) recycling of at least a portion of said second hydrocracked effluent into the separation step d).Type: ApplicationFiled: July 26, 2021Publication date: September 14, 2023Applicants: IFP Energies nouvelles, REPSOL S.A.Inventors: Wilfried WEISS, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA
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Publication number: 20230272292Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) selective hydrogenation of said feedstock in the presence of at least hydrogen and of at least one selective hydrogenation catalyst; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent; c) hydrocracking of said hydrotreated effluent in the presence of at least hydrogen and of at least one hydrocracking catalyst, to obtain a hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: ApplicationFiled: July 26, 2021Publication date: August 31, 2023Applicants: IFP Energies nouvelles, REPSOL S.A.Inventors: Wilfried WEISS, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA
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Patent number: 11685694Abstract: Disclosed is a rapid, reproducible solution-based method to synthesize solid sodium ion-conductive materials. The method includes: (a) forming an aqueous mixture of (i) at least one sodium salt, and (ii) at least one metal oxide; (b) adding at least one phosphorous precursor as a neutralizing agent into the mixture; (c) concentrating the mixture to form a paste; (d) calcining or removing liquid from the paste to form a solid; and (e) sintering the solid at a high temperature to form a dense, non-porous, sodium ion-conductive material. Solid sodium ion-conductive materials have electrochemical applications, including use as solid electrolytes for batteries.Type: GrantFiled: November 16, 2019Date of Patent: June 27, 2023Assignees: International Business Machines Corporation, Repsol, S.A.Inventors: Younes Ansari, Young-hye Na, Khanh Nguyen, Francisco José Alía Moreno-Ortiz
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Patent number: 11682807Abstract: A metal-oxygen battery includes a catholyte with: (i) carbon black; and, (ii) at least one of graphite and graphene, wherein said at least one of graphite and graphene constitutes between 0 wt % and 30 wt % of the total carbon in the catholyte.Type: GrantFiled: November 19, 2019Date of Patent: June 20, 2023Assignees: International Business Machines Corporation, Repsol, S.A.Inventors: Younes Ansari, Young-Hye Na, Francisco José Alia Moreno-Ortiz
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Patent number: 11629590Abstract: A method is described for estimating either flowback or the reservoir fluids production rate from either one individual inlet or the contribution from several inlets separated by intervals in a wellbore located in an oil and/or gas reservoir. The wellbore may include a casing with a plurality of magnetic irregularity elements, such as casing collars, to generate magnetic perturbations within the casing. In the method, one or more sensor elements are delivered in such a way that the flow drags them while the sensor elements record in time the magnetic perturbations generated by the magnetic irregularity elements. The known location of the magnetic irregularity elements and the reading of perturbations enables estimating the velocity of the sensor element(s) along the path direction of the casing, to determine the velocity of the fluid.Type: GrantFiled: April 5, 2019Date of Patent: April 18, 2023Assignee: REPSOL, S.A.Inventors: Ricardo Cesar Bezerra De Melo, Ramy Nabil Eid
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Patent number: 11519897Abstract: The present invention is related to computer implemented method for characterizing a target fluid of a hydrocarbon reservoir under uncertainty providing a set of fluid properties from a limited amount of information.Type: GrantFiled: March 27, 2018Date of Patent: December 6, 2022Assignee: Repsol, S.A.Inventors: José Luís Peña Díez, Daniel Merino García, Verónica Benito Iglesias, Paula Sanz Sanz
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Patent number: 11414988Abstract: The present invention relates to a method of estimating the region of damage due to collapse in the wall of a well during the drilling operation, normally using drilling fluid, where said well can, for example, be intended either for the injection or else for the production of a gas or oil reservoir. Other uses can be found in mining and in civil engineering work. This method is characterized by a set of analytical steps that allow establishing, for example, optimal drilling parameters so as to allow the fastest possible drilling speed that is also safe enough to allow is charging the collapse material without jamming the drilling tool. This method likewise allows assessing both the width and depth of damage in the wall of the well.Type: GrantFiled: April 3, 2018Date of Patent: August 16, 2022Assignee: REPSOL, S.A.Inventors: Jose Alvarellos Iglesias, José María Segura Serra, Marta Dueñas Díez, Enric Ibañez Martinez, Lakshmikantha Mookanahallipatna Ramasesha, Almudena Díaz Aguado
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Patent number: 11319401Abstract: The present invention refers to a method for the preparation of a polymer polyol which comprises: (i) preparing an intermediate in a first reactor by polymerizing a mixture comprising: (a) a base polyol in an amount from 60 to 100 wt % of the total amount of base polyol, (b) at least one ethylenically unsaturated monomer, (c) an acylperoxide radical initiator in an amount from 50 to 90 wt % of the total amount of acylperoxide radical initiator, and (d) a preformed stabilizer in an amount from 70 to 100 wt % of the total amount of preformed stabilizer or a macromer in an amount of from 70 to 100 wt % of the total amount of macromer; (ii) polymerizing in a second reactor a mixture comprising the intermediate prepared in step (i), the balance acylperoxide radical initiator proportion, the balance preformed stabilizer or macromer proportion and the balance base polyol proportion; wherein the at least one ethylenically unsaturated monomer is added only to the first reactor.Type: GrantFiled: February 24, 2021Date of Patent: May 3, 2022Assignee: REPSOL, S.A.Inventors: Juan Pedro Pérez Valencia, José Antonio Carazo Angulo
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Patent number: 11137514Abstract: One aspect includes a method for determining a drilling plan for new wells in a reservoir. The method includes categorizing the new wells into at least a first new well and a second new well, such that a drilling location for at least the first new well must be determined imminently, but a drilling location for at least the second new well can be determined at a later time. The method further includes determining potential drilling locations for the second new well, determining the drilling location for the first new well based at least in part on the determined potential drilling locations for the second new well, and outputting the drilling plan comprising the determined drilling location for the first new well and the determined potential drilling locations for the second new well.Type: GrantFiled: January 15, 2018Date of Patent: October 5, 2021Assignees: International Business Machines Corporation, REPSOL, S.A.Inventors: David Echeverria Ciaurri, Sonia Mariette Embid Droz, Eduardo Goncalves Dias De Barros, Ruben Rodriguez Torrado
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Patent number: 11119248Abstract: The present invention is related to a method for estimating the fractured volume in a reservoir domain, said fractured volume generated by injecting a high pressure fluid into the reservoir domain. The high pressure fluid generates new fractures allowing a more effective drainage of porous rocks, generally identified as geological material, containing oil or gas. As a result, the effective reservoir volume increases. According to embodiments of the invention, the method provides a dynamic estimation of the fractured volume taking into account the evolution of the rock and the fractures. In other embodiment, the evolution of the fractured volume is estimated by generating an envelope surrounding the induced fractures allowing a better estimation of the fractured volume.Type: GrantFiled: August 20, 2018Date of Patent: September 14, 2021Assignees: REPSOL, S.A., UNIVERSIDAD POLITÉCNICA DE CATALUÑAInventors: Lakshmikantha Mookanahallipatna Ramasesha, José Alvarellos Iglesias, José María Segura Serra, Ignacio Carol Vilarasau, Daniel Garolera Vinent, Pere Prat Catalan
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Publication number: 20210043939Abstract: It is provided a lithium metal anode coated with a protective monolayer disposed on at least a portion of the lithium metal anode, the protective monolayer consisting of a polymer; at least one inorganic particle selected from the group consisting of Al2O3, MnO, MnO2, SiO2, TiO2, ZnO, ZrO2, Fe2O3, CuO, a silicate, an aluminosilicate, a borosilicate, and an oxysalt, or any one of the mentioned inorganic particles which are functionalized; wherein the protective monolayer has a thickness from 0.01 to 10 ?m, the inorganic particles have an average diameter from 1 to 500 nm, and the at least one inorganic particle is in an amount of 0.01 to 30 wt % related to the amount of polymer. It is also provided a method for the preparation of the protected anode, as well as a lithium metal battery comprising it.Type: ApplicationFiled: February 4, 2019Publication date: February 11, 2021Applicant: REPSOL, S.A.Inventors: Rodrigo PARIS ESCRIBANO, Juan NICOLÁS AGUADO, Eneko AZACETA MUÑOZ, José Alberto BLAZQUEZ MARTÍN, Olatz LEONET BOUBETA, Idoia URDAMPILLETA GONZALEZ, Oscar MIGUEL CRESPO