Patents Assigned to Repsol S.A.
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Publication number: 20250313765Abstract: The present invention relates to a process for the treatment of a plastics pyrolysis oil, comprising: a hydrotreating of the feedstock in the presence of hydrogen and of a catalyst, a separation/scrubbing of the hydrotreated effluent in the presence of an aqueous solution in order to obtain at least a first aqueous effluent and a hydrotreated hydrocarbon effluent, a separation of the H2S contained in the first aqueous effluent, in order to obtain a gas phase containing the H2S and a second aqueous effluent, it being possible for said gas phase containing the H2S to be, at least partly, recycled upstream of stage b), a separation of the NH3 contained in the second aqueous effluent in order to obtain a gas phase containing NH3 and a third aqueous effluent. The present invention makes it possible, by the recycling of the H2S resulting from the process, to decrease the consumption of sulfiding agent for keeping the catalysts in the sulfide form in feedstocks containing only a little sulfur.Type: ApplicationFiled: April 17, 2023Publication date: October 9, 2025Applicants: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Jerome BONNARDOT, Loïk GUENAULT, Floriane MALDONADO, Inigo RIBAS SANGUESA, Martin SANTOS MARTINEZ, Sheyla CARRASCO HERNANDEZ, Wilfried WEISS, Marisa DE SOUSA DUARTE
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Patent number: 12351764Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) selective hydrogenation of said feedstock in the presence of at least hydrogen and of at least one selective hydrogenation catalyst; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent; c) hydrocracking of said hydrotreated effluent in the presence of at least hydrogen and of at least one hydrocracking catalyst, to obtain a hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: GrantFiled: July 26, 2021Date of Patent: July 8, 2025Assignees: IFP Energies nouvelles, REPSOL S.A.Inventors: Wilfried Weiss, Jérôme Bonnardot, Iñigo Ribas Sangüesa
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Patent number: 12344800Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) hydrogenation of said feedstock in the presence of at least hydrogen and of at least one hydrogenation catalyst at an average temperature of between 140 and 340° C., the outlet temperature of step a) being at least 15° C. higher than the inlet temperature of step a), to obtain a hydrogenated effluent; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent, the average temperature of step b) being higher than the average temperature of step a); c) separation of the hydrotreated effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: GrantFiled: December 21, 2021Date of Patent: July 1, 2025Assignees: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Wilfried Weiss, Dominique Decottignies, Jérôme Bonnardot, Iñigo Ribas Sangüesa, Lidia Escudero Castejon
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Publication number: 20250034465Abstract: The present invention relates to a process for the treatment of a plastics pyrolysis oil, comprising: a) the hydrogenation of said feedstock as a mixture with at least a part of the liquid effluent resulting from stage c) and in the presence of hydrogen and of a catalyst at a temperature between 14° and 340° C.; b) the hydrotreating of said hydrogenated effluent in the presence of hydrogen and of a catalyst; c) a separation of the hydrotreated effluent operated at high temperature and high pressure, in order to obtain a gaseous effluent and a liquid effluent, a part of which is recycled upstream of stage a), d) a separation operated at low temperature and high pressure and fed with the gaseous effluent and the other part of the liquid effluent resulting from stage c) and an aqueous solution, in order to obtain a hydrocarbon effluent.Type: ApplicationFiled: November 23, 2022Publication date: January 30, 2025Applicants: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Wilfried WEISS, Dominique DECOTTIGNIES, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA, Martin SANTOS MARTINEZ, Sheyla CARRASCO HERNANDEZ
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Publication number: 20240059977Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) hydrogenation of said feedstock in the presence of at least hydrogen and of at least one hydrogenation catalyst at an average temperature of between 140 and 340° C., the outlet temperature of step a) being at least 15° C. higher than the inlet temperature of step a), to obtain a hydrogenated effluent; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent, the average temperature of step b) being higher than the average temperature of step a); c) separation of the hydrotreated effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: ApplicationFiled: December 21, 2021Publication date: February 22, 2024Applicants: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Wilfried WEISS, Dominique DECOTTIGNIES, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA, Lidia ESCUDERO CASTEJON
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Publication number: 20230287283Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) the selective hydrogenation of said feedstock to obtain a hydrogenated effluent; b) hydrotreatment of said hydrogenated effluent to obtain a hydrotreatment effluent; c) a first step of hydrocracking of said hydrotreated effluent to obtain a first hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, to obtain a gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent; e) fractionation of the hydrocarbon-based liquid effluent to obtain at least one gas stream and at least one naphtha cut and a heavier cut; f) a second step of hydrocracking of the heavier cut to obtain a second hydrocracked effluent; g) recycling of at least a portion of said second hydrocracked effluent into the separation step d).Type: ApplicationFiled: July 26, 2021Publication date: September 14, 2023Applicants: IFP Energies nouvelles, REPSOL S.A.Inventors: Wilfried WEISS, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA
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Publication number: 20230272292Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) selective hydrogenation of said feedstock in the presence of at least hydrogen and of at least one selective hydrogenation catalyst; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent; c) hydrocracking of said hydrotreated effluent in the presence of at least hydrogen and of at least one hydrocracking catalyst, to obtain a hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: ApplicationFiled: July 26, 2021Publication date: August 31, 2023Applicants: IFP Energies nouvelles, REPSOL S.A.Inventors: Wilfried WEISS, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA
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Patent number: 10794155Abstract: The invention is a method for exploiting a subterranean formation including hydrocarbons with at least one lithologic facies of the formation having undergone at least one diagenetic phase over geological times. From at least one sample of rock obtained from the formation, from measured production data relating to the formation and from a meshed representation representative of the formation, each mesh of the meshed representation is determined including at least one indicator relating to the distribution of the facies present in the mesh. The method comprises a step of history matching in which at least one of the adjustment parameters is the diagenetic state of the identified facies.Type: GrantFiled: November 29, 2017Date of Patent: October 6, 2020Assignees: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Mickaele Le Ravalec, Mickael Barbier, Maria Fernanda Leon Carrera, Brigitte Doligez
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Patent number: 8679343Abstract: The present disclosure describes a method for the revaluation of aqueous waste streams generated in the propylene oxide and styrene co-production processes. In particular, it discloses a method of reducing the organic contaminant load from a highly contaminated aqueous stream and recovery from said stream of organic compounds that may be recirculated or used as fuel in the co-generation of energy, and which comprises: acidification of said aqueous stream with inorganic acid at a pH less than 4.5; separation of the two resulting phases at a temperature greater than 40° C.; washing of the organic phase produced in the previous step with an aqueous solution of excess acid and separation of the two resulting phases.Type: GrantFiled: May 14, 2008Date of Patent: March 25, 2014Assignee: Repsol S.A.Inventors: Eva Maria Garcia Biosca, Ignacio Rivera Sarmiento, Belén Mula Andres, Jorge Rodriguez Bustamante, Maria Pilar De Frutos Escrig