Abstract: The present invention relates to a tin-containing organolithium compound which can be used as anionic polymerization initiators, represented by the following formula (1):
Type:
Application
Filed:
June 11, 2002
Publication date:
September 25, 2003
Applicant:
China Petroleum and Chemical Corp and Research Institute of Beijing Yanshan Petrochemical Co Ltd
Inventors:
Chuanqing Li, Aimin Liang, Wei Li, Liyun Zhao, Song Lu, Lin Xu, Qing Liu
Abstract: The present invention relates to star-block interpolymers having the following structure (X-Y)n-C, wherein X represents a random copolymer block derived from conjugated diene and monovinyl aromatic monomer; Y represents a polyconjugated diene block; C represents a residue derived from a multifunctional lithium based initiator; and n represents the functionality of the initiator and has a value of not less than 3; and preparation of the same. The star-block interpolymers according to the present invention have in the same molecule both a random copolymer block derived from conjugated diene and monovinyl aromatic monomer and a rubber block selected from the group consisting of a homopolymer block derived from conjugated diene, a tapered copolymer block derived from conjugated dienes, a random copolymer block derived from conjugated dienes and combinations thereof, and hence possess excellent properties of the both kinds of rubbers, and can be used widely as elastomeric materials.
Type:
Grant
Filed:
October 18, 2001
Date of Patent:
October 8, 2002
Assignees:
China Petroleum and Chemical Corporation, Research Institute of Beijing Yanshan Petrochemical Co.,
Ltd.
Inventors:
Yang Li, Hongde Xu, Yurong Wang, Dingyi Hong, Mingchu Gu, Mei Wang, Zhanxia Lü, Aili Xu
Abstract: The present invention relates to butadiene/isoprene/monovinyl aromatic monomer heptablock copolymers having the following symmetric structure:
Z-XZ-X-Y-X-XZ-Z
wherein Z represents a polymer block of monovinyl aromatic monomer, X and Y, being different from each other, represent polymer blocks of butadiene or isoprene, XZ represents a tapered copolymer block of monovinyl aromatic monomer and butadiene or isoprene, and wherein the content of the recurring units derived from monovinyl aromatic monomer is 10 to 50 percent by weight, the content of the recurring units derived from butadiene is 10-75 percent by weight and the content of the recurring units derived from isoprene is 10-75 percent by weight, all based on the weight of the block copolymer, and methods for the preparation thereof.
Type:
Grant
Filed:
July 27, 2000
Date of Patent:
April 16, 2002
Assignees:
China Petrochemical Corporation, Research Institute of Beijing Yanshan Petrochemical Co.,
Ltd.