Patents Assigned to Research Institute of Petroleum
  • Patent number: 11318444
    Abstract: A desulfurization catalyst includes at least: 1) a sulfur-storing metal oxide, 2) an inorganic binder, 3) a wear-resistant component, and 4) an active metal component. The sulfur-storing metal is one or more of a metal of Group IIB of the periodic table, a metal of Group VB of the periodic table, and a metal of Group VIB of the periodic table, e.g., zinc. The desulfurization catalyst has a good stability and a high desulfurization activity.
    Type: Grant
    Filed: October 31, 2017
    Date of Patent: May 3, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jun Long, Shuandi Hou, Wei Lin, Ye Song, Huiping Tian
  • Patent number: 11260374
    Abstract: The present invention relates to a Cu-based catalyst, a preparation process thereof and its use as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst contains copper, at least one auxiliary metal selected from metal of Group IIA, non-noble metal of Group VIII, metal of Group VIB, metal of Group VIIB, metal of Group IIB and lanthanide metal of periodic table of elements, and an alkali metal, and further contains at least one ketone additive selected from a ketone represented by formula (II) and a ketone represented by formula (II?). Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin. R1-C(?O)—CH(OH)—R2??(II) R1-C(?O)—CH(?O)—R2??(II?) In formulae (II) and (II?), each group is defined as in the description.
    Type: Grant
    Filed: November 14, 2018
    Date of Patent: March 1, 2022
    Assignees: China Petroleum & Chemical Corporation, Dalian Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.
    Inventors: Kai Qiao, Feng Zhou, Jie Su, Huixia Ma, Qingtong Zhai, Shumei Zhang
  • Patent number: 11224859
    Abstract: A carbon-coated transition metal nanocomposite material includes carbon-coated transition metal particles having a core-shell structure. The shell layer of the core-shell structure is a graphitized carbon layer doped with oxygen and/or nitrogen, and the core of the core-shell structure is a transition metal nanoparticle. The nanocomposite material has a structure rich in mesopores, is an adsorption/catalyst material with excellent performance, can be used for catalyzing various hydrogenation reduction reactions, or used as a catalytic-oxidation catalyst useful for the treatment of volatile organic compounds in industrial exhaust gases.
    Type: Grant
    Filed: July 27, 2018
    Date of Patent: January 18, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Junfeng Rong, Genghuang Wu, Jingxin Xie, Mingsheng Zong, Weiguo Lin, Peng Yu, Hongbo Ji
  • Patent number: 11213788
    Abstract: A method for flue gas denotation includes the step of, in the presence of ammonia, enabling flue gas in a denitration reactor to pass through a plurality of catalyst beds from the bottom to the top to participate in a denitration reaction. Each catalyst bed contains a catalyst support component and a granular denitration catalyst stacked on the catalyst support component, and, in every single catalyst bed, the granular denitration catalyst moves along a same direction on the catalyst support component. Between every two adjacent catalyst beds, the granular denitration catalyst falls from the tail of a previous catalyst support component to the head of a next catalyst support component, making the granular denitration catalyst travel along the catalyst support components reciprocatively.
    Type: Grant
    Filed: August 31, 2017
    Date of Patent: January 4, 2022
    Assignees: China Petroleum & Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.
    Inventors: Xin Li, Shuhe Liu, Tianzhu Han, Mingxing Wang
  • Patent number: 11207669
    Abstract: The supporter material for catalyst includes a main body alumina and a rod-shaped alumina. The main body alumina is provided with micron-sized pore channels, at least part of the rod-shaped alumina is distributed on the exterior surface of the main body alumina and/or in the micron-sized pore channels with a pore diameter D within a range of 3-10 ?m; the rod-shaped alumina has a length of 1-12 ?m and a diameter of 80-300 nm. The alumina supporter material is used as a residual oil hydrogenation catalyst supporter to facilitate a long period operation of the residual oil hydrogenation, and has high demetalization rate, desulfurization rate and denitrification rate.
    Type: Grant
    Filed: October 26, 2018
    Date of Patent: December 28, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC CORP.
    Inventors: Honghai Ji, Huicheng Zhang, Fengxiang Ling, Shaojun Wang, Zhiqi Shen, Weiya Yang, Lihua Wang
  • Patent number: 11179705
    Abstract: A modified Y-type molecular sieve contains 0.5-2 wt. % of Na2O based on the total amount of the modified Y-type molecular sieve. In the modified Y-type molecular sieve, the ratio between the total acid amount measured by pyridine and infrared spectrometry and total acid amount measured by n-butyl pyridine and infrared spectrometry is 1-1.2. The total acid amount measured by pyridine and infrared spectrometry of the modified Y-type molecular sieve is 0.1-1.2 mmol/g. The acid center sites of the molecular sieve of the modified Y-type molecular sieve are distributed in the large pore channels. The molecular sieve is used in the hydrocracking reaction process of a wax oil.
    Type: Grant
    Filed: November 29, 2017
    Date of Patent: November 23, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC CORP.
    Inventors: Wei Liu, Minghua Guan, Yanze Du, Fenglai Wang, Bo Qin, Hang Gao
  • Patent number: 11161105
    Abstract: The present application relates to a hydrogenation catalyst, a process for producing the same and application thereof in the hydrotreatment of feedstock oil. The process comprises at least the following steps: (1) contacting a first active metal component and a first organic complexing agent with a carrier to obtain a composite carrier; (2) calcining the composite carrier to obtain a calcined composite carrier having a total carbon content of 1% by weight or less; and (3) contacting a second organic complexing agent with the calcined composite carrier to obtain the hydrogenation catalyst. The hydrogenation catalyst has both excellent hydrodesulfurization activity and hydrodenitrogenation activity, and exhibits a significantly prolonged service life.
    Type: Grant
    Filed: April 24, 2017
    Date of Patent: November 2, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Le Zhang, Mingfeng Li, Huifeng Li, Hong Nie, Shi Ding, Xuefen Liu, Zhihai Hu
  • Patent number: 11161746
    Abstract: A method for the treatment of silicon-containing wastewater from the preparation of a molecular sieve or a catalyst includes the step of contacting the silicon-containing wastewater with at least one acid or at least one alkali, so that at least a part of the silicon elements in the silicon-containing wastewater form a colloid. A mixture containing a colloid is thus obtained. A silicon-containing solid phase and a first liquid phase are produced by a solid-liquid separation. A solid phase and a second liquid phase are produced by a solid-liquid separation after at least a part of the metal elements in the first liquid phase form a precipitate. At least a part of the second liquid phase is subjected to electrodialysis to produce an acid liquor and/or an alkali liquor. The silicon-containing solid phase can be used as the raw material for a molecular sieve synthesis.
    Type: Grant
    Filed: October 28, 2016
    Date of Patent: November 2, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Zhongqing Liu, Yibin Luo, Lina Zhou, Xingtian Shu
  • Patent number: 11137508
    Abstract: The present invention describes a mechanical coupling microseismic monitoring system, which includes at least one microseismic sensor, push rods that are arranged at both ends of the microseismic sensor through a first connection mechanism to send the microseismic sensor into the monitoring hole, introduction mechanisms that are mounted on the push rods for introducing the microseismic sensor into the monitoring hole, and one microseismic monitoring computer that receives signals from the microseismic sensor; the microseismic sensor is a recoverable microseismic sensor; the first connection mechanism is a connection mechanism that can make the push rod swing relative to the microseismic sensor; the introduction mechanism is a three-roller introduction mechanism. The present invention meets the requirement of microseismic monitoring for different parts of deep monitoring hole using multiple microseismic sensors.
    Type: Grant
    Filed: August 14, 2018
    Date of Patent: October 5, 2021
    Assignee: RESEARCH INSTITUTE OF PETROLEUM EXPLORATION & DEVELOPMENT, PETROCHINA COMPANY LIMITED
    Inventors: Dewen Zheng, Zhide Wu, Guosheng Ding, Huayin Zhu, Jianfeng Liu, Lina Ran, Tong Lin
  • Patent number: 11130917
    Abstract: A modified Y-type molecular sieve has a rare earth content of about 4-11% by weight on the basis of rare earth oxide, a sodium content of no more than about 0.7% by weight on the basis of sodium oxide, a zinc content of about 0.5-5% by weight on the basis of zinc oxide, a phosphorus content of about 0.05-10% by weight on the basis of phosphorus pentoxide, a framework silica-alumina ratio of about 7-14 calculated on the basis of SiO2/Al2O3 molar ratio, a percentage of non-framework aluminum content to the total aluminum content of no more than about 20%, and a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 15-30%. The modified Y-type molecular sieve has a high crystallinity, a structure comprising secondary pores, and a high thermal and hydrothermal stability.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: September 28, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Hao Sha, Lingping Zhou, Shuai Yuan, Weilin Zhang, Zhenyu Chen, Mingde Xu, Huiping Tian
  • Patent number: 11111191
    Abstract: A method for preparing hexadecahydropyrene includes the step of carrying out the hydrogenation reaction to hydrocarbon oil containing pyrene compounds in the presence of a hydrogenation catalyst. The pyrene compounds are selected from at least one of pyrene and unsaturated hydrogenation products thereof. The hydrogenation catalyst contains a carrier and an active metal component loaded on the carrier. The active metal component is Pt and/or Pd and the carrier contains a small crystal size Y zeolite, alumina and amorphous silica-alumina. The small crystal size Y zeolite has an average grain diameter of 200-700 nm, a molar ratio of SiO2 to Al2O3 of 40-120, a relative crystallinity of ?95%, and a specific surface area of 900-1,200 m2/g. The pore volume of secondary pores in 1.7-10 nm diameter is more than 50% of the total pore volume.
    Type: Grant
    Filed: November 30, 2017
    Date of Patent: September 7, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC CORP.
    Inventors: Guoquan Sun, Xiangchen Fang, Hongfei Fan, Chunlei Yao, Hui Quan
  • Patent number: 11091372
    Abstract: The present invention relates to a molecular sieve, particularly to an ultra-macroporous molecular sieve. The present invention also relates to a process for the preparation of the molecular sieve and to its application as an adsorbent, a catalyst, or the like. The molecular sieve has a unique X-ray diffraction pattern and a unique crystal particle morphology. The molecular sieve can be produced by using a compound represented by the following formula (I), wherein the definition of each group and value is the same as that provided in the specification, as an organic template. The molecular sieve is capable of adsorbing more/larger molecules, thereby exhibiting excellent adsorptive/catalytic properties.
    Type: Grant
    Filed: July 11, 2020
    Date of Patent: August 17, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yongrui Wang, Jincheng Zhu, Mingyi Sun, Xuhong Mu, Xingtian Shu
  • Patent number: 11078434
    Abstract: Disclosed is a process and system for upgrading low-quality oils. The upgrading process comprises: (1) subjecting a low-quality oil to a conversion reaction in the presence of hydrogen and optionally in the presence of a conversion catalyst to obtain a conversion product, (2) processing the conversion product to obtain a first processed product, wherein the first processed product comprises a specific amount of a special component, and (3) subjecting the first processed product to extraction separation to obtain an upgraded oil and a pitch. The upgrading process and the upgrading system have the advantages of stable operation, high upgrading efficiency, environmental friendliness, low coke yield or high yield of upgraded oil.
    Type: Grant
    Filed: September 11, 2017
    Date of Patent: August 3, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jun Long, Huandi Hou, Zijun Wang, Haiping Shen, Ming Dong, Lishun Dai, Jianhong Gong, Jiguang Li, Shuhong Zhang, Cuihong Wang, Yucheng She, Yuzhang Wang, Mengying Tao
  • Patent number: 11052381
    Abstract: A modified Y-type molecular sieve has a rare earth oxide content of about 4% to about 12% by weight, a phosphorus content of about 0% to about 10% by weight, a sodium oxide content of no more than about 1.0% by weight, a total pore volume of about 0.36 to 0.48 mL/g, a percentage of the pore volume of secondary pores to the total pore volume of about 20% to about 40%, a lattice constant of about 2.440 nm to about 2.455 nm, a percentage of the non-framework aluminum content to the total aluminum content of no more than about 10%, a lattice collapse temperature of not lower than about 1060° C., and a ratio of Brønsted acid to Lewis acid of no less than about 3.50. The preparation of the molecular sieve includes ion-exchange with rare earth, hydrothermal roasting, gas phase ultra-stabilization, acid treatment, and an optional phosphorus modification.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: July 6, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Lingping Zhou, Weilin Zhang, Mingde Xu, Zhenyu Chen, Huiping Tian, Yuxia Zhu
  • Patent number: 11053129
    Abstract: A magnesium modified Y-type molecular sieve has a rare earth oxide content of about 4% to about 11% by weight, a magnesium oxide content of about 0.1% to about 4% by weight, a sodium oxide content of about 0.3% to about 0.8% by weight, a total pore volume of about 0.33 mL/g to about 0.39 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of the modified Y-type molecular sieve of about 10% to about 30%, a lattice constant of about 2.440 nm to about 2.455 nm, a percentage of non-framework aluminum content to the total aluminum content of the modified Y-type molecular sieve of no more than about 20%, and a lattice collapse temperature of not lower than about 1045° C.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: July 6, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Lingping Zhou, Weilin Zhang, Mingde Xu, Zhenyu Chen, Huiping Tian, Yuxia Zhu
  • Patent number: 11041131
    Abstract: The present application relates to a process for treating gasoline, comprising the steps of: splitting a gasoline feedstock into a light gasoline fraction and a heavy gasoline fraction; optionally, subjecting the resulting light gasoline fraction to etherification to obtain an etherified oil; contacting the heavy gasoline fraction with a mixed catalyst and subjecting it to desulfurization and aromatization in the presence of hydrogen to obtain a heavy gasoline product; wherein the mixed catalyst comprises an adsorption desulfurization catalyst and an aromatization catalyst. The process of the present application is capable of reducing the sulfur and olefin content of gasoline and at the same time increasing the octane number of the gasoline while maintaining a high yield of gasoline.
    Type: Grant
    Filed: October 20, 2017
    Date of Patent: June 22, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Youhao Xu, Junyi Mao, Xin Wang, Qing Yuan, Jingchuan Yu, Hong Nie, Dadong Li
  • Patent number: 11034932
    Abstract: The present invention relates to the field of biotechnology, and discloses a composition capable of promoting the growth of denitrifying microorganisms and uses thereof. The composition contains a glycolipid, an alditol, and a salt of organic acid, wherein the glycolipid is at least one of trehalose glycolipid, sophorolipid and rhamnolipid. The composition provided in the present invention can promote the growth of denitrifying microorganisms, and thereby improve the denitrification activity of the denitrifying microorganisms, promote a smooth denitrification process, and shorten the processing time.
    Type: Grant
    Filed: November 27, 2017
    Date of Patent: June 15, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC CORP.
    Inventors: Huijie Gao, Danfeng Sun, Zhihua Guo, Mingxiang Chen
  • Patent number: 11028334
    Abstract: A gradient copolymer comprises or consists of n polymer components. The n polymer components each independently represents an addition polymer of a monomer of the formula (I), and/or a mixture thereof, or the n polymer components each independently comprises or consists essential of one or more structural units represented by the formula (I-1), The symbol n represents an integer within the closed interval [5, ?]. The average side chain carbon number of the i-th polymer component as determined according to the nuclear magnetic resonance method is expressed as Xi, with the symbol i representing an arbitrary integer from 1 to n, the relationship X1<X2< . . . <Xn?1<Xn holds.
    Type: Grant
    Filed: June 27, 2017
    Date of Patent: June 8, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yao Zhang, Qinghua Duan, Kecheng Wei, Yinong Liu, Hongwei Sun
  • Patent number: 11001768
    Abstract: A heavy oil hydrotreating system has a prehydrotreating reaction zone, a transition reaction zone, and a hydrotreating reaction zone that are connected in series successively, sensor units, and a control unit. In the initial reaction stage, the prehydrotreating reaction zone includes at least two prehydrotreating reactors connected in parallel, and the transition reaction zone includes or doesn't include prehydrotreating reactors; in the reaction process, the control unit controls material feeding to and material discharging from each prehydrotreating reactor in the prehydrotreating reaction zone according to pressure drop signals of the sensor units, so that when the pressure drop in any of the prehydrotreating reactors in the prehydrotreating reaction zone reaches a predetermined value, the prehydrotreating reactor in which the pressure drop reaches the predetermined value is switched from the prehydrotreating reaction zone to the transition reaction zone.
    Type: Grant
    Filed: November 1, 2016
    Date of Patent: May 11, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC CORP.
    Inventors: Tiebin Liu, Xinguo Geng, Yanbo Weng, Hongguang Li
  • Patent number: 10982137
    Abstract: The present disclosure discloses a fluorescent dispersed particle gel, a fluorescent gel, a fluorescent modified polyacrylamide composite, and a preparation method and use thereof.
    Type: Grant
    Filed: June 12, 2020
    Date of Patent: April 20, 2021
    Assignees: China University of Petroleum (East China), The Research Institute of Petroleum Exploration and Development (RIPED) of the Petro China Company Limited (Petro China), China University of Geosciences (Beijing)
    Inventors: Guang Zhao, Caili Dai, Xu Jin, Ning Yang, Qing You, Mingwei Zhao