Abstract: A polymer blend having an open time including a high molecular weight average, predominantly atactic flexible polyolefin polymer having a heat of fusion of about 15 to 60 J/g, and a low molecular weight average, atactic polyolefin polymer having a heat of fusion of about 0.1 to 20 J/g, wherein the high molecular weight polymer and low molecular weight polymer are sufficiently miscible to impart a single glass transition temperature to the polymer blend, and the low molecular weight polymer is present in an amount sufficient to impart a melt viscosity of greater than about 8,000 cPs at room temperature and a crystallinity below about 25 J/g to the polymer blend. The invention further includes methods for preparing such polymer blends, and the products produced from the polymer blends, which are useful for hot melt adhesives, asphalt and bitumen applications such as roofing membranes, polymeric modifiers and the like.

Abstract: Amorphous propylene/1-butene and ethylene/propylene copolymers having increased tensile properties produced by the process comprising:reacting propylene and 1-butene monomers or ethylene and propylene monomers in the presence of a catalyst system comprising:(a) a solid supported catalyst component is prepared by the method comprising: (i) co-comminuting magnesium halide support base and aluminum trihalide in a molar ratio from about 8:0.5 to about 8:3 in the absence of added electron donor; and (ii) then co-comminuting the product of step (i) in the absence of added electron donor with sufficient titanium tetrahalide to provide a molar ratio of magnesium halide to titanium tetrahalide from about 8:0.1 to about 8:1.0;(b) a trialkylaluminum co-catalyst, having from 1 to 9 carbon atoms in each alkyl group in an amount such that the Al/Ti ratio is between about 50:1 and about 500:1; and(c) an alkoxy silane component of the formula R.sub.n Si(OR').sub.4-n where n=1-3, R=aryl or alkyl and R'=C.sub.1-3 alkyl.

Abstract: Amorphous propylene/1-butene and ethylene/propylene copolymers having increased tensile properties produced by the process comprising:reacting propylene and 1-butene monomers or ethylene and propylene monomers in the presence of a catalyst system comprising:(a) a solid supported catalyst component is prepared by the method comprising: (i) co-comminuting magnesium halide support base and aluminum trihalide in a molar ratio from about 8:0.5 to about 8:3 in the absence of added electron donor; and (ii) then co-comminuting the product of step (i) in the absence of added electron donor with sufficient titanium tetrahalide to provide a molar ratio of magnesium halide to titanium tetrahalide from about 8:0.1 to about 8:1.0;(b) a trialkylaluminum co-catalyst, having from 1 to 9 carbon atoms in each alkyl group in an amount such that the Al/Ti ratio is between about 50:1 and about 500:1; and(c) an alkoxy silane component of the formula R.sub.n Si(OR').sub.4-n where n=1-3, R=aryl or alkyl and R'=C.sub.1-3 alkyl.

Abstract: Amorphous propylene/1-butene and ethylene/propylene copolymers having increased tensile properties produced by the process comprising:reacting propylene and 1-butene monomers or ethylene and propylene monomers in the presence of a catalyst system comprising:(a) a solid supported catalyst component is prepared by the method comprising: (i) co-comminuting magnesium halide support base and alumminum trihalide in a molar ratio from about 8:0.5 to about 8:3 in the absence of added electron donor; and (ii) then co-comminuting the product of step (i) in the absence of added electron donor with sufficient titanium tetrahalide to provide a molar ratio of magnesium halide to titanium tetrahalide from about 8:0.1 to about 8:1.0;(b) a trialkylaluminum co-catalyst, having from 1 to 9 carbon atoms in each alkyl group in an amount such that the Al/Ti ratio is between about 50:1 and about 500:1; and(c) an alkoxy silane component of the formula R.sub.n Si(OR').sub.4-n where n=1-3, R=aryl or alkyl and R'=C.sub.1-3 alkyl.

Abstract: A laminated film has layer(s) A and layer(s) B.sub.1, obtained by laminating at least one layer A and at least one layer B.sub.1. The layer A comprises a resin composition comprising (a) 20-100% by weight of an amorphous polyolefin containing at least one component, in an amount of at least 50% by weight in said amorphous polyolefin, selected from the group consisting of propylene and butene-1 and (b) 80-0% by weight of a crystalline polypropylene, (B) the layer B.sub.1 comprises a crystalline polypropylene. At least one of the two outermost layer is the layer B.sub.1. The laminated films can be used in various applications by themselves, but may be laminated with a polyester film, a nylon film, a stretched polypropylene film or the like to improve the mechanical strengths, gas-barrier property, printability, etc.

Abstract: The present invention provides a resin composition including (a) 20-80% by weight of an amorphous polyolefin having a propylene and/or butene-1 component content of 50% by weight or more, and (b) 80-20% by weight of a crystalline polypropylene. This resin composition is well balanced in mechanical strength and flexibility and gives rise to no environmental pollution.

Abstract: Heat-sealable thermoplastic elastomeric films comprise from approximately 35% to about 65% of an A-B-A block copolymer wherein "A" blocks are derived from polystrene or a polystrene homolog and said "B" blocks being derived from lower alkenes and from about 25% to about 55% of an ethylene vinyl acetate copolymer, the ethylene vinyl acetate copolymer comprising approximately 28% vinyl acetate. The films are heat-sealable to various substrates including polyvinyl chloride. Once sealed to the substrate, the film may be readily peeled from the substrate by the application of a low and relatively constant peel force. A method for measuring the peel strengths of the film is disclosed. The films are especially adapted to being heat-sealed to a substrate which forms, together with the substrate a package, or multiple serially connected packages.

Abstract: Polymer compositions having improved resistance to thermoforming sag are disclosed. The compositions comprise a first and second portion selected from the group comprising polypropylene, propylene-ethylene copolymers and mixtures thereof wherein a first portion of the composition is (1) mixed with from about 500 to about 3000 ppm of antioxidant; and (2) irradiated with a dosage of from about 10 to about 20 Mrads gamma or electron beam of ionizing radiation in air, and the second portion of said polymer composition is non-irradiated. The first portion is present in an amount effective, from about 1.0% to about 10.0%, to increase the elasticity of the polymer composition in the molten state by at least 10% as compared to the second portion of said polymer composition.

Abstract: Packaging and/or storing atactic polypropylene or other amorphous poly alpha olefins is accomplished by first heating a mass of the olefin material to a molten state and then cooling the molten mass of olefin material to an extrusion temperature. Next, the formless mass of atactic polypropylene is extruded and cut into a succession of pellets. Inert dust-like material is sprayed onto the cutting surfaces and the surface of the olefin material so that the natural tendency of the material to stick to itself and to other objects is avoided.

Abstract: A laminated film has layer(s) A and layer(s) B.sub.1, obtained by laminating at least one layer A and at least one layer B.sub.1. The layer A comprises a resin composition comprising (a) 20-100% by weight of an amorphous polyolefin containing at least one component, in an amount of at least 50% by weight in said amorphous polyolefin, selected from the group consisting of propylene and butene-1 and (b) 80-0% by weight of a crystalline polypropylene, (B) the layer B.sub.l comprises a crystalline polypropylene. At least one of the two outermost layer is the layer B.sub.1. The laminated films can be used in various applications by themselves, but may be laminated with a polyester film, a nylon film, a stretched polypropylene film or the like to improve the mechanical strengths, gas-barrier property, printability, etc.

Abstract: A process for the production of propylene/1-butene copolymers comprising:reacting propylene and 1-butene monomers in the presence of a catalyst system comprising:(a) a solid supported catalyst component is prepared by the method comprising: (i) co-comminuting magnesium halide support base and aluminum trihalide in a molar ratio from about 8:0.5 to about 8:3 in the absence of added electron donor; and (ii) then co-comminuting the product of step (i) in the absence of added electron donor with sufficient titanium tetrahalide to provide a molar ratio of magnesium halide to titanium tetrahalide from about 8:0.1 to about 8:1.0.(b) a trialkylaluminum co-catalyst, having from 1 to 9 carbon atoms in each alkyl group in an amount such that the Al/Ti ratio is between about 50:1 and about 500:1.(c) an alkoxy silane component of the formula R.sub.n Si(OR').sub.4-n where n=1-3, R=aryl or alkyl and R'=C.sub.

Abstract: Polyethylene films having improved diecutability and compositions for the production thereof comprise from approximately 75% to about 95% of a polyethylene polymer and from about 5% to about 25% of a calcium carbonate filler. Preferably, the calcium carbonate filler comprises polybutylene and solid calcium carbonate having a particle size less than about 3.0 microns. The film produced from the composition is from approximately 1 mil to about 10 mils in thickness. The film can be produced using conventional blown film technology and equipment and has improved diecutability and printability. Thus, the film is readily adaptable to the production of diecut labels.