Abstract: A substantially zero-carbon-emission (ZCE) process for making propylene polymers and copolymers including: converting alkanes to the olefin monomers ethylene, propylene, and butene or combinations thereof, using renewable electric power and scrubbing the stack gases from any fired heaters or boilers to remove carbon dioxide, in an oxidative-coupling of methane plant including the steps of passing alkanes through an ethylene plant while adding oxygen, passing a portion of the polymerization grade ethylene through a 2-butene plant, and passing the 2-butene stream and a portion of the polymerization grade ethylene stream through a propylene plant. The polymerization grade propylene is polymerized to produce isotactic homopolymer polypropylene, or ethylene-propylene random copolymer, or impact grade polypropylene containing ethylene-propylene rubber.

Abstract: A continuous process for pre-contacting coordination polymerization catalyst components with each other before they are introduced into a polymerization reactor at 130 degrees Fahrenheit to 200 degrees Fahrenheit, where the activated coordination catalyst is contacted with at least one monomer to produce amorphous poly alpha olefin (APAO), the process involving blending a Ziegler-Natta pro-catalyst with a liquid carrier forming a Ziegler-Natta pro-catalyst slurry and flowing a co-catalyst mixture into the Ziegler-Natta pro-catalyst slurry continuously in a pre-contacting device, forming an activated Ziegler-Natta catalyst; continuously injecting the activated Ziegler-Natta catalyst into the heated polymerization reactor while simultaneously, and continuously, injecting propylene monomer and any other alpha-olefin monomers, and hydrogen gas for molecular weight control, initiating an exothermic reaction forming a monomer-polymer-catalyst slurry then continuously stirring the monomer-polymer-catalyst slurry for

Abstract: A hot-melt formulation includes a butene-1-co-hexene-1 copolymer formed from butene-1 and hexene-1 monomers synthesized using a supported Ziegler-Natta catalyst reacted with an organometallic cocatalyst, a styrenic block copolymer with less than 15 percent bound styrene, a high melt viscosity metallocene catalyzed polyolefin, a high melt viscosity polypropylene with a melt viscosity above 18,000 cps, and a low molecular weight polyethylene wax, wherein the melt viscosity of the wax is less than 1,000 centipoise at a temperature of 350 degrees Fahrenheit.

Abstract: A method to make a hot-melt polymer formulation with from 50 wt % to 100 wt % of a propylene-co-butene-1-co-hexene-1 terpolymer or a propylene-co-hexene-1 copolymer, each polymer made using a metal chloride supported Ziegler-Natta catalyst, at a process temperature between about 130 degrees Fahrenheit and about 200 degrees Fahrenheit and at a reactor pressure sufficient to maintain the propylene in a liquid phase without solvent; using 1 wt % to 20 wt % of at least one of: a metallocene-catalyst made polymer; a homopolymer of propylene with 0.1%-5% functionality; and a styrene block copolymer; and wherein the melt viscosity of the terpolymer or copolymer formulation is controlled by addition of hydrogen gas as a chain transfer agent.

Abstract: Adding a compatible high melt flow rate (MFR), low melt viscosity, hydrogenated styrene block copolymer to amorphous poly alpha-olefins (APAOs) results in adhesives that show acceptably high elongation and tensile strength, and which, when applied by different hot melt application methods onto elastic strands, result in personal hygiene article components that perform comparably to such components assembled using just styrene block copolymer components formulated with compatible tackifiers, processing oils and other additives.

Abstract: Adding a low molecular weight (or alternatively, high melt flow rate), functionalized, isotactic polypropylene (iPP) to a hot melt adhesive (HMA), composition containing a propylene-butene-1, and/or a propylene-ethylene amorphous poly alpha olefin (APAO) copolymer, in addition to other co-adjuvants (such as a tackifier or a plasticizer), results in an APAO-based HMA that shows improved tensile strength and bonding properties, over an HMA that contains only the propylene-butene-1 and/or the propylene-ethylene APAO copolymer (with or without a tackifier and/or a plasticizer).

Abstract: A low viscosity, high tensile strength polymer having a bi-modal molecular weight distribution is produced using a combination of high molecular weight polymer and low molecular weight polymer. The polymer chains have a high content of meso dyads that results in a greater amount of crystalline regions when the polymer is solidified. The low molecular weight chains provide high flow characteristics when the polymer is molten. The process for producing the high content of meso dyads includes the use of an external donor catalyst during the reaction.