Patents Assigned to Rhein-Chemie Rheinau GmbH
  • Patent number: 5565599
    Abstract: Disclosed herein are stabilized dithiophosphoric acid polysulphides of the formula (I) ##STR1## in which R is a C.sub.1 -C.sub.20 alkyl, cycloalkyl, aryl or aralkyl residue andx is an integer from 2 to 15,containing as stabilizer 1 to 20 wt.% of a carboxylic acid of the general formula R'COOH, in which R' is a C.sub.1 -C.sub.20 alkyl residue, a cycloalkyl residue, an aryl residue or an aralkyl residue, and 1 to 20 wt.% of calcium oxide or zinc oxide.
    Type: Grant
    Filed: August 24, 1995
    Date of Patent: October 15, 1996
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Hans-Joachim Graf, Lothar Steger, Klaus Kn orr, Hartmut Schulz, Volker Sch afer, Thomas Scholl, R udiger Schubart, Manfred Schweiger
  • Patent number: 5563240
    Abstract: Poly[2,5-bis(polysulphano)-1,3,4-thiadiazoles] of the formula ##STR1## wherein X signifies a number from 1 to 10 andn signifies a number from 2 to 1,000.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: October 8, 1996
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Hans-Joachim Graf, Volker Sch afer, Kurt Schilling, Clemens Schudok
  • Patent number: 5552070
    Abstract: A process for the phosphorylation of epoxides, in particular of epoxidised fatty acid esters, and the use of the phosphorylation products for the production of lubricants.
    Type: Grant
    Filed: October 11, 1994
    Date of Patent: September 3, 1996
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Volker Schafer, Robert Kohler, Gunter Schilling, Alfred Pauli, Ingo Rohrs, Joachim Korff
  • Patent number: 5482638
    Abstract: Addition products of monoepoxides or diepoxides of mono- or polyunsaturated monocyclic or bicyclic hydrocarbons and dithiophosphoric acids, a process for the production of the adducts from the corresponding dithiophosphoric acids and epoxides and the use of the addition products as lubricant additives in lubricants based on mineral oils or native oils.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: January 9, 1996
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Thomas Dimmig, Gunter Jager, Thomas Petri
  • Patent number: 5468288
    Abstract: A masticating agent for rubber consists of tallow fatty acid with an addition of 0.1 to 3% by weight (based on the masticating agent) of a 16-membered, metal-containing ring compound.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: November 21, 1995
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Lothar Steger, Horst Syrowatka, Walter Schutte
  • Patent number: 5466742
    Abstract: An aqueous outside release agent for the production of tires and other rubber articles is described, which contains 5 to 35% by wt. diatomaceous earth, 0.5 to 6% by wt. pyrogenic hydrophobic silica, 0.1 to 2% by wt. nonionic surfactant, 0.2 to 3% by wt. of a binder, 0.1 to 3% by wt. dye, 0 to 5% by wt. ethyl alcohol and the remainder water. Preferred binders are styrene-maleic acid or styrene-maleic anhydride copolymers and in particular ammonium salts thereof. Said outside release agent is used in processes for molding and vulcanizing tires and other rubber articles, it being sprayed onto the blank with the aid of air-atomizing guns before molding and vulcanization are carried out. A very good release effect is thereby achieved without vulcanization being impaired. As only very small quantities of outside release agent are needed, cleaning of the press mold and hence interruption of the production process are required very much less frequently than when conventional outside release agents are used.
    Type: Grant
    Filed: January 14, 1994
    Date of Patent: November 14, 1995
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Herbert Wagner, Karl-Heinrich Schuhmacher
  • Patent number: 5464586
    Abstract: An environment-friendly aqueous slip and mold-release agent for the manufacture of tires and other rubber articles and a process for the molding and vulcanization of tires and other rubber articles are described. The aqueous slip and mold-release agent contains 0.5 to 6 wt. % polytetrafluoroethylene, 20 to 40 wt. % mineral fillers and at least 40 wt. % water. It is sprayed onto the inside of the tire blank prior to the molding and vulcanization, so that the water contained therein evaporates, accompanied by development of a slip and release agent film. Apart from the environment-friendliness and good release effect, the new slip and mold-release agent leads, despite the high water content, to a quick evaporation of the water and thus a rapid development, desired in industrial operations, of the slip and release agent film.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: November 7, 1995
    Assignee: Rhein Chemie Rheinau GmbH
    Inventor: Herbert Wagner
  • Patent number: 5457216
    Abstract: An .alpha.-tocopherol preparation is disclosed which contains 40 to 80% by weight tocopherol, 10 to 40% by weight EPM rubber and 10 to 50% by weight neutral silicate filler or acrylate polymer. The composition is added during vulcanization of rubber to inhibit nitrosamine formation.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: October 10, 1995
    Assignee: Rhein Chemie Rheinau GmbH
    Inventor: Harald Kleinknecht
  • Patent number: 5434305
    Abstract: A process for the production of aromatic carbodiimides by carbodiimidization of aromatic monoisocyanates in the presence of distillable organic phosphorus compounds as catalyst at 120.degree. to 220.degree. C. up to a maximum degree of carbodiimidization of 80% and subsequent removal by distillation of the unreacted starting isocyanate together with the catalyst from the reaction mixture, optionally together with subsequent preparation by distillation, together with the carbodiimides obtainable in accordance with this process.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: July 18, 1995
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Hans-Joachim Hennig, Wolfgang Alter, Jorg Lussmann
  • Patent number: 5413728
    Abstract: A process for operating a compressor heat pump or a compressor refrigeration system using ammonia as the refrigerant and a refrigerant compressor lubricated with a lubricant from the polyalkylene glycol family, The polyalkylene glycols used as lubricants have a specific composition and an amine is added thereto. Monofunctional or difunctional polyalkylene glycols are used as lubricants.
    Type: Grant
    Filed: August 26, 1993
    Date of Patent: May 9, 1995
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Klaus Mall, Siegfried Kussi
  • Patent number: 5412140
    Abstract: Alkyl glycidol ether/dithiophosphoric acid addition products corresponding to the following general formula:[R.sup.1 ]O[C(H)(H)][C(H)C(H)(H)(OH)(R.sup.4)] (I)in whichR.sup.4 =[(R.sup.2 O)(R.sup.3 O)]P(S)S,R.sup.1 . . . R.sup.3 =alkyl, aryl,a process for the production of the adducts from the corresponding dithiophosphoric acids and glycidol ethers and the use of the addition products as lubricant additives in lubricants based on mineral oils or native oils.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: May 2, 1995
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Thomas Dimmig, Gunter Jager, Thomas Petri, Wolfram Radig, Gunther Schilling, Jurgen Braun, Volker Schafer
  • Patent number: 5368776
    Abstract: A method for improving the corrosion inhibition of lubricating oils especially those of vegetable origin which comprises adding an efficient amount of the reaction product of an epoxidized fatty acid ester, especially an epoxidized methyl ester of an unsaturated fatty acid and a sulphonic acid and a process for producing these reaction products.
    Type: Grant
    Filed: October 20, 1993
    Date of Patent: November 29, 1994
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Volker Schafer, Robert Kohler, Alfred Pauli, Achim Fessenbecker
  • Patent number: 5360888
    Abstract: Polyamides stabilized to hydrolysis at high temperatures, particularly in an acidic medium, containing 0.1 to 5% by weight based on polyamide of a polymeric aromatic carbodiimide.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: November 1, 1994
    Assignee: Rhein Chemie Rheinau GmbH
    Inventor: Volker Ullrich
  • Patent number: 5250625
    Abstract: The cross-linking of halogenated polymers such as chlorinated polyethylene with bis-(2,5-dimercapto-1,3,4-thiadiazole) in the presence of a basic substance may easily be carried out and leads to improved properties of the vulcanisate, in particular when amidamines such as, for example, tetraethylene pentamine distearate are used as basic substances.
    Type: Grant
    Filed: April 16, 1991
    Date of Patent: October 5, 1993
    Assignee: Rhein Chemie Rheinau GmbH
    Inventor: Helfried Ehrend
  • Patent number: 5158805
    Abstract: A method for reducing the formation of nitrosamines during the vulcanization of rubber mixes which includes treating of the inorganic additives used for the rubber mix to be vulcanized--primarily carbon blacks, zinc oxide and/or silicates--with ammonia or with a primary amine.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: October 27, 1992
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Rudolf Preussmann, Bertold Spiegelhalder
  • Patent number: 5155248
    Abstract: Reaction products of dibutyl tin oxide with selected aromatic aminocarboxylic acids, a process for their preparation and their use as catalysts for the preparation of polyurethanes.
    Type: Grant
    Filed: November 29, 1991
    Date of Patent: October 13, 1992
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Volker Ullrich, Clemens Schudok
  • Patent number: 5141978
    Abstract: An addition of 1 to 10% by weight and preferably 2 to 5% by weight, based on polyurethane rubber, of a fatty acid ester of pentaerythritol or a mixture of an alkane with a fatty acid to the polyurethane rubber mix eliminates the tendency towards sticking and improves the flow properties.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: August 25, 1992
    Assignee: Rhein Chemie Rheinau GmbH
    Inventor: Helfried Ehrend
  • Patent number: 5130360
    Abstract: Polyesters and polyester urethanes are stabilized against discoloration and hydrolytic degradation by inclusion therein of an aromatic carbodiimide and either a benzohydroquinone or a naphthohydroquinone compound, and at the same time, the quantity of isocyanate eliminated from polyester urethanes is considerably reduced.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: July 14, 1992
    Assignee: Rhein Chemie Rheinau GmbH
    Inventor: Volker Ulrich
  • Patent number: 4599425
    Abstract: Bis-[2,5-dithio-1,3,4-thiadiazole] corresponding to the following formula: ##STR1## is obtained by reacting 2,5-dimercapto-1,3,4-thiadiazole and hydrogen peroxide in the absence of other reactants.
    Type: Grant
    Filed: October 18, 1984
    Date of Patent: July 8, 1986
    Assignee: Rhein-Chemie Rheinau GmbH
    Inventors: Peter Hugo, Rainer Noack
  • Patent number: 4591645
    Abstract: 2-(Hydrocarbyldithio)-5-mercapto-1,3,4-thiadiazoles are obtained by reacting bis-(2,5-dithio-1,3,4-thiadiazole with a tert.-hydrocarbyl mercaptan of which the hydrocarbyl moiety contains from 4 to 60 carbon atoms.
    Type: Grant
    Filed: August 14, 1984
    Date of Patent: May 27, 1986
    Assignee: Rhein-Chemie Rheinau GmbH
    Inventors: Peter Hugo, Rainer Noack