Abstract: The present invention provides a device and method for testing wear and friction properties of different materials under various experimental conditions representative of real usage conditions. In general, the device according to the invention is based on contacting a sample with a rotating disk with intermittent contact, in “open cycle” conditions, where dynamic loads are applied to the sample for the contact to occur. The control of dynamic loading is fully independent of the disk rotation.
Type:
Grant
Filed:
September 7, 2017
Date of Patent:
July 20, 2021
Assignees:
RHODIA OPERATIONS, Centre National de la Recherche Scientifique
Inventors:
Paul Sotta, Matthieu Guibert, Jean-Luc Loubet, Jean Thevenet, Loïc Vanel, Menglong Huang
Abstract: The present disclosure relates to a process for the production of aromatic primary amines, by reacting an aromatic dialdehyde with hydrogen and ammonia or an ammonia-liberating compound, in the presence of a hydrogenation catalyst and an amine, wherein the molar ratio of the amine to the aromatic dialdehyde is no less than 1:4 at the start of the reaction.
Abstract: The present invention relates to a new process of vanillin production from a substrate by bioconversion and that allows a continuously producing and removing vanillin from the fermentation broth as it is formed. In particular, the invented process advantageously allows to reduce the residence time of vanillin in the fermenter and to maintain the vanillin concentration, in the fermentation broth, below its toxic level for the microorganism.
Type:
Grant
Filed:
July 28, 2016
Date of Patent:
July 13, 2021
Assignee:
RHODIA OPERATIONS
Inventors:
Marie Chauve, Stéphanie Foucher, Sophie Galinat, Guillaume Pireau
Abstract: Compositions and methods for fracturing a subterranean formation are presented. Also provided are compositions and methods for reducing friction-related losses in a well treatment fluid. In general, the compositions include a copolymer that includes one or more vinylphosphonic acid (“VPA”) monomers.
Type:
Application
Filed:
March 18, 2021
Publication date:
July 8, 2021
Applicant:
RHODIA OPERATIONS
Inventors:
Subramanian Kesavan, Genyao Lin, Jian Zhou, Hoang Van Le, Changmin Jung, Qi Qu
Abstract: The present invention relates to a non-cellulosic polysaccharide derivative: i) having a mean average molecular weight (Mw) from about 100,000 g/mol, preferably from about 150,000 g/mol and more preferably from about 200,000 g/mole to about 2,000,000 g/mol, preferably to about 1,800,000 g/mol and more preferably to about 1,400,000 g/mole; and ii) containing at least one cationic group, with a cationic degree of substitution (DScat.)extraction, from about 0.20 to about 0.30.
Abstract: The invention relates to a novel solid form of diphenol compound. A process for the preparation of diphenol prills having a spherical shape is disclosed. Said process comprising providing a molten composition comprising from 50 to 100 wt. % of a diphenol compound or a mixture of at least two diphenol compounds, and less than 0.1 wt. % of water; forcing said molten composition through at least one droplet generator means to form droplets; and cooling said droplets to form solid diphenol prills. The diphenol prills obtainable by said process are also one subject-matter of the invention.
Type:
Grant
Filed:
February 21, 2018
Date of Patent:
June 29, 2021
Assignee:
RHODIA OPERATIONS
Inventors:
Cédric Humblot, David Vanzin, Lars Fischer, Rodolphe Sapey-Triomphe
Abstract: Provided are: a complex oxide that exhibits high redox ability even at low temperatures, has excellent heat resistance, and stably retains these characteristics even on repeated oxidation and reduction at high temperature; a method for producing the same; and an exhaust gas purification catalyst. The inventive complex oxide contains more than 0 but no more than 20 parts by mass of Si, calculated as SiO2, per total 100 parts by mass of rare earth metal elements including Ce, calculated as oxides; and has a characteristic such that when it is subjected to temperature-programmed reduction (TPR) measurement in a 10% hydrogen-90% argon atmosphere at from 50° C. to 900° C. with the temperature increasing at a rate of 10° C./min, followed by oxidation treatment at 500° C. for 0.5 hours, and then temperature-programmed reduction measurement is performed again, its calculated reduction rate at and below 400° C. is at least 1.5%.
Abstract: Methods of acidizing a subterranean formation penetrated by a wellbore that include the steps of (a) injecting into the wellbore at a pressure below subterranean formation fracturing pressure a treatment fluid having a first viscosity and including an aqueous acid and a gelling agent selected from the group consisting of Formulas I-XI and combinations thereof; (b) forming at least one void in the subterranean formation with the treatment fluid; and (c) allowing the treatment fluid to attain a second viscosity that is greater than the first viscosity.
Type:
Grant
Filed:
February 21, 2019
Date of Patent:
June 22, 2021
Assignee:
RHODIA OPERATIONS
Inventors:
Rose Ndong, Olivier Back, Pascal Herve, Jian Zhou
Abstract: The present invention relates to a method for conditioning a fabric comprising the step of contacting the fabric with an aqueous medium comprising a composition, wherein the composition comprises: (a) a quaternary ammonium compound; (b) a cationic polysaccharide; and (c) a nonionic polysaccharide. In particular, the quaternary ammonium compound is a biodegradable quaternary ammonium compound. The composition has excellent softening performance and improved perfume longevity. The present invention also relates to use of said composition for conditioning a fabric.
Type:
Grant
Filed:
January 15, 2015
Date of Patent:
June 15, 2021
Assignee:
RHODIA OPERATIONS
Inventors:
Hai Zhou Zhang, Nikolay Christov, Da Wei Jin
Abstract: The present invention relates to cerium oxide particles that have excellent heat resistance especially useful for catalysts, functional ceramics, solid electrolyte for fuel cells, polishing, ultraviolet absorbers and the like, and particularly suitable for use as a catalyst or co-catalyst material, for instance in catalysis for purifying vehicle exhaust gas. The present invention also relates to a method for preparing such cerium oxide particles, and a catalyst, such as for purifying exhaust gas, utilizing these cerium oxide particles.
Abstract: Disclosed are a liquid pearlescent composition (e.g., a liquid pearlescent concentration) that is free of a preservative, a personal product including the composition, and a method of use the same.
Abstract: The present invention relates to a suspension of cerium oxide particles in a liquid phase, in which said particles comprise secondary particles comprising primary particles, and a process for preparing said liquid suspension in which the cerium IV/total cerium molar ratio before precipitation is comprised between 1/10000 and 1/500000 and that the thermal treatment is being carried out under an inert atmosphere.
Abstract: A method for extracting a crude oil contained in a geological formation comprises a step of fracturing the geological formation, by injection of a specific aqueous extraction fluid under pressure, which contains at least one surfactant that reduces the interfacial tension between the extraction fluid and the crude oil to be extracted to below 0.1 mN/m; followed by a discharge step (“flowback”). Additionally, the original fracturing fluids used in this method, and the additives used in these fracturing fluids include a surfactant or a surfactant mixture which make it possible to reduce the interfacial tension between the fluid and a petroleum oil below 0.1 mN/m.
Abstract: The instant invention relates to primary coating compositions that comprises a cationic polysaccharide, to be applied on a hydrophobic surface before a subsequent application of a polar or water based coating composition, such a as a paint or an adhesive.
Abstract: The invention relates to a novel process for the preparation of silicate comprising: reacting rice husk ash with a silicate precursor P1 to obtain a silicate S2 having a SiO2/MxO molar ratio MR2, in which the precursor P1 is either a silicate S1 having a SiO2/MxO molar ratio MR1 such that MR2>MR1, or a mixture of sand with metal hydroxide.
Type:
Grant
Filed:
September 30, 2016
Date of Patent:
June 8, 2021
Assignee:
RHODIA OPERATIONS
Inventors:
Philippe Jost, Leo Ricardo Bedore Dos Santos, Daniella De Villefort Grossi
Abstract: The instant invention relates to surfactants having the following formula (I) wherein: each of Ra and Rb is a linear or branched, saturated or unsaturated, hydrocarbon chain, each of Rc and Rd is a alkyl chain having 1 to 10 carbon atoms, each of (E1) and (E2) is a divalent hydrocarbon radical, A is: a group a carboxylate group —COO? (optionally in all or part in the form —COOH); or a sulfonate group —SO3? (optionally in all or part in the form —SO3H). The invention also relate to the preparation of these surfactants and their use in oil extraction, especially in EOR applications.
Type:
Grant
Filed:
March 30, 2017
Date of Patent:
June 8, 2021
Assignee:
RHODIA OPERATIONS
Inventors:
Olivier Back, Philippe Marion, Mikel Morvan
Abstract: The invention relates to the use, as fluxing agent for the production of a hot surface dressing, of an additive for hydrocarbon binder including at least one compound having the formula CH3—X—R—Y—R2 where: R2 is a C1-C11 chain of alkyl type, advantageously methyl; —X— and —Y— are each an ester or amide group with R??H or C1-C4 alkyl; and —R— is a C1-C10 divalent hydrocarbon chain, optionally interrupted by one or more oxygen atoms; and where the STV pseudo-viscosity measured for said hydrocarbon binder to which has been added 10% by weight of said additive is below 500 seconds.
Type:
Application
Filed:
April 27, 2018
Publication date:
April 22, 2021
Applicant:
RHODIA OPERATIONS
Inventors:
Arnaud BOURDETTE, Frédéric DELFOSSE, Marie-Pierre LABEAU, Thomas LEBARBE, Hélène MARTIN, Simon ROUSSEAU, Marie-Laure PIERRE
Abstract: The invention relates to the manufacture of a bituminous product type mix or surface dressing which includes bringing into contact, at a temperature below 110° C., mineral particles with an emulsion (i) derived from emulsification of a hydrocarbon binder in an aqueous phase at a mixing temperature above the contacting temperature, and (ii) which includes an additive which: forms a homogeneous mixture with the hydrocarbon binder at the mixing temperature; is not compatible with the hydrocarbon binder at the contacting temperature; is used at a content above its solubility in the aqueous medium of the emulsion at the contacting temperature.
Type:
Application
Filed:
April 27, 2018
Publication date:
April 22, 2021
Applicant:
RHODIA OPERATIONS
Inventors:
Arnaud BOURDETTE, Frédéric DELFOSSE, Marie-Pierre LABEAU, Thomas LEBARBE, Hélène MARTIN, Simon ROUSSEAU, Pierre-Jean MERCIER
Abstract: An antimicrobial composition that includes: an antimicrobial component having at least one quaternary ammonium compound; a synthetic polymer that includes: at least one cationic monomer Ab, optionally, at least one anionic monomer Ba, and optionally, at least one non-ionic monomer Ca; an organic acid; and a surfactant selected from cationic surfactants, amphoteric surfactants and combinations thereof, wherein the composition is free of non-ionic surfactants. This composition when applied to a surface provides robust long lasting disinfection.
Type:
Grant
Filed:
April 9, 2019
Date of Patent:
April 20, 2021
Assignee:
Rhodia Operations
Inventors:
Amit Sehgal, Kamel Ramdani, Christopher Plummer, Huw Evans
Abstract: Compositions and methods for fracturing a subterranean formation are presented. Also provided are compositions and methods for reducing friction-related losses in a well treatment fluid. In general, the compositions include a copolymer that includes one or more vinylphosphonic acid (“VPA”) monomers.
Type:
Grant
Filed:
September 13, 2017
Date of Patent:
April 20, 2021
Assignee:
RHODIA OPERATIONS
Inventors:
Subramanian Kesavan, Genyao Lin, Jian Zhou, Hoang Van Le, Changmin Jung, Qi Qu