Abstract: Disclosed is a heat resistant composite comprising a refractory coating on a metal substrate. The refractory coating is provided by mixing a refractory mortar with water, impregnating a water absorbent web of fibrous material with the liquid mixture, placing at least one layer of the impregnated web on a surface of the substrate as a coating, and drying the coating to remove the water and cause the refractory mixture to chemically bond. The substrate may be a pipe protected by the coating for use in injecting a refining agent beneath the surface of a molten metal composition comprising a scrap metal such as copper or aluminum.