Abstract: Process for preparing moulding materials MM with improved optical and colour properties, consisting of a polymer PM which contains units of the formula I in which R1 and R2 are each hydrogen and methyl and R3 is hydrogen, C1-C18-alkyl, C5-C8-cycloalkyl, C6-C10-aryl, C6-C10-aryl-C1-C4-alkyl, where these radicals may be up to trisubstituted by radicals selected from the group consisting of C1-C4-alkoxy and halogen, prepared in an imidation reaction known per se in a reactive extruder, in which, on completion of the imidation reaction, an amount of one or more reducing phosphorus compounds P which is effective for colour stabilization is added to the polymer PM, characterized in that the phosphorus compounds are organic phosphorus compounds OP selected from the group consisting of compounds of the formula II in which R4 and R5 are each independently hydrogen or an aromatic 6-membered ring which may be up to pentasubstituted by a C1-C4-alkyl and/or C5-C8-cycloalkyl groups.
Type:
Application
Filed:
February 27, 2009
Publication date:
January 20, 2011
Applicant:
Evonik Roehm GmbH
Inventors:
Victor Khrenov, Krzysztof Sado, Nils Mehler, Klaus Schultes, Klaus Albrecht
Abstract: A method for forming a laminated product includes providing a film (2) having a first surface embossed with optical structures and an opposite second surface; guiding the film to a nip point of a pair of lamination rolls (5, 6); feeding a polymer sheet (4) to the nip point (7), wherein the polymer sheet has a surface temperature effective to enable thermal bonding between the polymer sheet and the film; and laminating the polymer sheet to the second surface of the film. The present process reduces the cost and environmental impact associated with laminating fresnel lens film to acrylic sheet versus existing industry technology.
Type:
Application
Filed:
March 16, 2009
Publication date:
January 20, 2011
Applicant:
Evonik Roehm GmbH
Inventors:
Grant Bernard Lafontaine, Michael Thomas Pasierb
Abstract: The present invention relates to a plastics mixture comprising at least one thermoplastic polyurethane A) and at least one impact-modified poly(meth)acrylate B), where the impact-modified poly(meth)acrylate comprises a hard phase whose glass transition temperature is at least 70° C. and a tough phase whose glass transition temperature is at most ?10° C., the average particle size of the tough phase is at most 130 nm, and at least a portion of the tough phase has covalent linkage to the hard phase.
Type:
Application
Filed:
February 27, 2009
Publication date:
January 20, 2011
Applicant:
EVONIK ROEHM GMBH
Inventors:
Uwe Numrich, Peter Battenhausen, Guenther Dickhaut, Claude Guenanten
Abstract: A pharmaceutical form, contains an active compound-containing core, which is covered with a coating layer of a gastric juice-resistant, intestinal juice-soluble (meth)acrylate copolymer, a separating layer situated between said core and said coating layer, the separating layer containing a film-forming water-soluble polymer, wherein the separating layer contains at least two layers: an inner layer containing a water-repellent substance, and thereon a layer comprising the film-forming water-soluble polymer.
Abstract: The invention relates to a flameproof PMMA moulding material, mouldings produced therefrom and the use thereof. Small amounts of an organo-phosphorus compound are sufficient to increase the glow wire flammability index by 300° C.
Type:
Application
Filed:
February 26, 2009
Publication date:
January 13, 2011
Applicant:
EVONIK ROEHM GMBH
Inventors:
Thorsten Goldacker, Klaus Koralewski, Michael Wicker
Abstract: The invention relates to a process for preparing (meth)acrylate-based ABA triblock copolymers with an olefinic functionalization of the A blocks.
Type:
Grant
Filed:
August 30, 2006
Date of Patent:
January 11, 2011
Assignee:
Evonik Roehm GmbH
Inventors:
Gerd Loehden, Sven Balk, Monika Maerz, Christine Troemer
Abstract: The present invention relates to a method for producing methacrylic acid by reacting methacrylamide with water, wherein said reaction is performed continuously in a tube reactor and a pressure differential exists in the flow direction of the reaction mixture inside said tube reactor. Furthermore, the present invention discloses a facility for carrying out the method according to the invention.
Type:
Application
Filed:
January 3, 2009
Publication date:
December 30, 2010
Applicant:
Evonik Roehm GmbH
Inventors:
Udo Gropp, Stefanie Sohnemann, Guido Protzmann, Thomas Mertz
Abstract: The present invention relates to a process for purifying methacrylic acid, wherein the reaction mixture obtained by a reaction of methacrylamide with water is cooled by mixing with an aqueous medium and then passed into a phase separator. The present invention further describes a system for performing the process according to the invention.
Type:
Application
Filed:
January 13, 2009
Publication date:
December 16, 2010
Applicant:
EVONIK ROEHM GMBH
Inventors:
Udo Gropp, Stefanie Sohnemann, Guido Protzmann, Thomas Mertz
Abstract: The invention relates to a process for preparing polymers for coating applications by polymerizing esters of acrylic acid or of methacrylic acid or vinyl aromatics or other free-radically polymerizable vinyl compounds or monomer mixtures composed predominantly of such monomers by means of a continuous polymerization process. In particular, the invention relates to a solvent-free preparation process for polymers, through which the binder can be prepared for coating applications with superior processing properties, very good thermal stability, improved pigment wetting and a higher gloss.
Type:
Application
Filed:
February 2, 2009
Publication date:
November 25, 2010
Applicant:
Evonik Roehm GmbH
Inventors:
Helmut Schwind, Uwe-Martin Wiesler, Cornelia Borgmann, Heike Leuninger, Thomas Schmied, Stefanie Maus, Werner Friedrich, Sven Balk
Abstract: The present invention relates to a process for the preparation of methacrylic acid or methacrylic esters, comprising the process steps of IA) preparation of 3-hydroxyisobutyric acid by a process comprising the process step of bringing a cell which has been genetically modified in comparison with its wild type in such a way that it is capable of forming more 3-hydroxyisobutyric acid, or polyhydroxyalkanoates based on 3-hydroxyisobutyric acid in comparison with its wild type, into contact with a nutrient medium comprising, as carbon source, carbohydrates, glycerol, carbon dioxide, methanol, L-valine or L-glutamate under conditions under which 3-hydroxyisobutyric acid or polyhydroxyalkanoates based on 3-hydroxyisobutyric acid are formed from the carbon source, if appropriate, isolation of the 3-hydroxyisobutyric acid from the nutrient medium and also, if appropriate, neutralization of the 3-hydroxyisobutyric acid, IB) dehydration of the 3-hydroxyisobutyric acid with formation of methacrylic acid and also, where
Type:
Application
Filed:
May 30, 2008
Publication date:
November 18, 2010
Applicant:
Evonik Roehm GmbH
Inventors:
Achim Marx, Markus Poetter, Stefan Buchholz, Alexander May, Hermann Siegert, Birgit Alber, Georg Fuchs, Lothar Eggeling
Abstract: The present invention relates to a pharmaceutical or nutraceutical preparation comprising a) a core containing a pharmaceutically or nutraceutically active substance and a substance that acts in a modulatory manner with regard of the release of pharmaceutically or nutraceutically active substances; and b) a controlling layer surrounding the core comprising i) 55 to 92% by weight based on the total weight of (meth)acrylic copolymers present in the layer of one or a mixture of a plurality of (meth)acrylate copolymers composed of 80 to 98% by weight based on the weight of the (meth)acrylic copolymer of structural units derived from C1 to C4 alkyl esters of (meth)acrylic acid and 2 to 20% by weight based on the weight of the (meth)acrylic copolymer of structural units derived from (meth)acrylate monomers with a quaternary ammonium group in the alkyl radical; and ii) 8 to 45% by weight based on the total weight of (meth)acrylic copolymers present in the layer of one or a mixture of a plurality of (meth)acrylate co
Type:
Application
Filed:
February 1, 2008
Publication date:
November 18, 2010
Applicant:
EVONIK ROEHM GMBH
Inventors:
Hema Ravishankar, Shradda Bodinge, Hans-Ulrich Petereit
Abstract: The invention relates to a method for producing a pharmaceutical dosage form as tablets, pellets and/or in the form of an active ingredient-containing matrix, whereby the tablets, pellets and/or active ingredient-containing matrix contain a pharmaceutical active ingredient and a copolymer serving as a coating agent and/or binding agent, and optionally contain a core and pharmaceutically common additives. According to the invention, the copolymer, the pharmaceutical active ingredient, the optionally present core and/or the pharmaceutically common additives are processed using known techniques by melting, injection molding, extrusion, wet granulation, casting, dipping, spreading out, spraying on, or pressing to form tablets, pellets and/or an active ingredient-containing matrix. The inventive method is characterized in that a copolymer is used that consists of 20 to 34 wt. % methacrylic acid, 20 to 69 wt. % methylacrylate and 0 to 40 wt. % ethylacrylate and, optionally, of 0 to 10 wt.
Type:
Grant
Filed:
January 30, 2003
Date of Patent:
November 16, 2010
Assignee:
Evonik Roehm GmbH
Inventors:
Hans-Ulrich Petereit, Thomas Suefke, Christian Meier, Michael Schnabel, Ingrid Blesing, Stefan Grimm
Abstract: Two-component or multicomponent system which cures by means of a redox initiator system and has a controllable pot life and comprises A) 0.8-69.94% by weight of an emulsion polymer which can be obtained by polymerization of a mixture; B) 30-99.14% by weight of one or more ethylenically unsaturated monomers; C) 0.05-10% by weight of peroxides; and if appropriate further constituents; characterized in that the component A) and the component C) are stored together and at least one constituent of the component B) is stored together from the components A) and C), with the separately stored constituent of the component B) being selected so that the ability of this constituent of the component B) to swell the polymer A) is sufficiently high for the polymer-fixed activator e) of the polymer A) to be able to react with the component C).
Type:
Application
Filed:
June 27, 2008
Publication date:
November 11, 2010
Applicant:
Evonik Roehm GmbH
Inventors:
Gerold Schmitt, Wolfgang Klesse, Joachim Knebel
Abstract: The present invention relates to a strategy for improving the permeability and solubility of pharmaceuticals, based on adding a chemically modified amino alkyl methacrylate copolymer E, wherein the chemical modification is the quaternization of a fraction of the existing amino alkyl groups.
Type:
Application
Filed:
December 12, 2008
Publication date:
November 11, 2010
Applicant:
Evonik Roehm GmbH
Inventors:
Peter Langguth, Stefan Grube, Holger Frey, Boris Obermeier
Abstract: Process for preparing an alkoxypolyoxyalkylene (meth)acrylate in which a) a metal alkoxide MetOR10 is initially charged, b) an alkylene oxide of the formula (IV) is added and reacted with the metal alkoxide and c) (meth)acrylic anhydride is added directly and reacted with the reaction product from step b). Appropriately, in step c), a stabilizer mixture is added which comprises, for example, the following components I. at least one compound of the formula (I) II. at least one compound of the formula (IIa or IIb) or of the formula (IV) III.
Type:
Grant
Filed:
January 30, 2007
Date of Patent:
November 9, 2010
Assignee:
Evonik Roehm GmbH
Inventors:
Uwe-Martin Wiesler, Joachim Knebel, Brigitte Mess
Abstract: Process for preparing (meth)acrylates of the formula (I) CH2?C(R1)—CO—O—R2 ??(I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2?C(R1)—CO—OR3 ??(II) with an alcohol of the formula (III) HO—R2 ??(III) in the presence of an amount of a suitable catalyst which catalyses the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.
Type:
Application
Filed:
September 29, 2008
Publication date:
November 4, 2010
Applicant:
Evonik Roehm GmbH
Inventors:
Joachim Knebel, Ralf Merbach, Guido Protzmann, Klaus Gottmann, John Hirsh, Gerold Schmitt, Dieter Tessmer, Wilhelm Karnbrock, Wolfgang Klesse, Volker Kerscher
Abstract: The present invention relates to a process for preparation of pure methacrylic acid, at least comprising the process steps: a) gas phase oxidation of a C4 compound to obtain a methacrylic acid-comprising gas phase, b) condensation of the methacrylic acid-comprising gas phase to obtain an aqueous methacrylic acid solution, c) separation of at least a part of the methacrylic acid from the aqueous methacrylic acid solution to obtain at least one crude methacrylic acid-comprising product; d) separation of at least a part of the methacrylic acid from the at least one crude methacrylic acid-comprising product by means of a thermal separation process to obtain a pure methacrylic acid.
Type:
Application
Filed:
November 17, 2008
Publication date:
October 28, 2010
Applicant:
EVONIK ROEHM GMBH
Inventors:
Martin Koestner, Gerhard Koelbl, Ralf Meier
Abstract: Composition for the production of mouldings having a matt and structured surface character, comprising a polymer matrix and crosslinked polymer particles, the polymer matrix comprising at least one acrylic polymer and the composition containing (i) first crosslinked polymer particles having a volume average of the particle size in the range from 30 ?m to 1500 ?m and (ii) second crosslinked polymer particles having a volume average of the particle size of less than 30 ?m, the difference between the refractive index of the first polymer particles and the refractive index of the polymer matrix, measured in each case at 25° C., being less than 0.015 as an absolute value and the difference between the refractive index of the second polymer particles and the refractive index of the polymer matrix, measured at 25° C., being greater than or equal to 0.015 as an absolute value.
Type:
Application
Filed:
August 29, 2008
Publication date:
October 28, 2010
Applicant:
Evonik Roehm GmbH
Inventors:
Klaus Schultes, Sabine Schwarz-Barac, Klaus Albrecht, Ursula Golchert, Stefan Nau, Sabrina Thomas, Michael Schnabel