Patents Assigned to Rohm & Haas Company
  • Patent number: 11846912
    Abstract: Embodiments of the present disclosure are directed to printing systems and methods that may include an ink composition including electrically charged ink particles dispersed in a hydrocarbon liquid and a multilayer film. The multilayer film may include a polymeric core layer; and one or more printing layers adjacent to the polymeric core layer. The one or more printing layers may include at least 50 wt. % of an ethylene vinyl acetate copolymer having acid and acrylate functional groups. The ethylene vinyl acetate copolymer having acid and acrylate functional groups may include from 0.5 wt. % to 4 wt. % methacrylic or acrylic acid; from 0.5 wt. % to 4 wt. % acrylate, from 7 wt. % to 40 wt. % vinyl acetate; and the balance ethylene, based on the total weight of the ethylene vinyl acetate copolymer having acid and acrylate functional groups.
    Type: Grant
    Filed: April 27, 2020
    Date of Patent: December 19, 2023
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Juan Carlos Casarrubias, Nicolas Cardoso Mazzola, Barry Alan Morris, Jorge Caminero Gomes
  • Patent number: 11845829
    Abstract: A two-component polyurethane composition comprising: a specific emulsion polymer, and a water-dispersible polyisocyanate; the emulsion polymer comprising, by weight based on the weight of the emulsion polymer, (a) greater than 15% to less than 30% of structural units of tert-butyl methacrylate, (b) greater than 10% of structural units of a hydroxy-functional alkyl (meth)acrylate, (c) structural units of a phosphorous-containing acid monomer and/or a salt thereof, (d) structural units of an additional acid monomer and/or a salt thereof, and (e) structural units of an additional monoethylenically unsaturated nonionic monomer; wherein the weight ratio of (d)/(c) is in the range of from 7.1:1 to 9.9:1; and a process of preparing the two-component polyurethane composition.
    Type: Grant
    Filed: August 15, 2019
    Date of Patent: December 19, 2023
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY
    Inventors: Xiaohong Yang, Fengzhe Shi, Jinfei Wang, Juan Zhao, Li Zhou
  • Publication number: 20230398044
    Abstract: Described herein are aspherical hollow silica particles, processes for making aspherical hollow silica particles, and uses of aspherical hollow silica particles in sun care compositions. To form the aspherical hollow silica particles, deposition of a silica shell on a calcium carbonate template using a sol-gel chemistry is employed. Subsequent dissolution of the calcium carbonate template forms voids (e.g., a hollow interior) in the aspherical hollow silica particles.
    Type: Application
    Filed: October 28, 2021
    Publication date: December 14, 2023
    Applicants: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY
    Inventors: Jie XIONG, Fanwen ZENG, Wenjun XU, Dean M. MILLAR
  • Patent number: 11834780
    Abstract: Provided are a process, the process includes (i) first, contacting a textile with an aqueous solution containing a cationic hydroxyethylcellulose polymer to form a modified textile component; (ii) subsequently, impregnating the modified textile component with an aqueous polyurethane dispersion externally stabilized with an anionic surfactant, the aqueous polyurethane dispersion including a second surfactant; and (iii) precipitating the polyurethane in the modified textile component. Also disclosed are a synthetic leather produced by the process.
    Type: Grant
    Filed: August 21, 2018
    Date of Patent: December 5, 2023
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Yunlong Guo, Yi Zhang, Zhaohui Qu, Xiangyang Tai
  • Publication number: 20230383112
    Abstract: The present invention relates to a composition comprising 1) an aqueous dispersion of multistage opacifying polymer particles with a superposing binder layer; 2) a colorant; and 3) inorganic opacifying pigment particles. The composition of the present invention is useful for one coat hide paint formulations.
    Type: Application
    Filed: September 24, 2021
    Publication date: November 30, 2023
    Applicant: Rohm and Haas Company
    Inventors: Qing Zhang, Yujie Lu
  • Patent number: 11814512
    Abstract: A multi-stage flexible acrylic resin comprises a branched polymer which is a reaction product of reactants comprising one or more monoethylenically unsaturated ester monomers, a chain transfer agent in an amount of 0.1 to 10 wt. %, and a crosslinker in an amount of 0.1 to 10 wt. %, wherein wt. % is based on total amount of reactants, provided the amount of crosslinker in moles is less than the amount of chain transfer agent in moles. A process for producing the multi-stage flexible acrylic resin is also disclosed.
    Type: Grant
    Filed: March 13, 2020
    Date of Patent: November 14, 2023
    Assignee: Rohm and Haas Company
    Inventors: Pu Luo, Hailan Guo, Morris Wills
  • Patent number: 11813593
    Abstract: A heterogeneous catalyst comprising a support and gold, wherein: (i) said support comprises alumina, (ii) said catalyst comprises from 0.1 to 5 wt % of gold, (iii) at least 90 wt % of the gold is in the outer 60% of catalyst volume, and (iv) particles of the catalyst have an average diameter from 200 microns to 30 mm; wherein weight percentages are based on weight of the catalyst.
    Type: Grant
    Filed: June 20, 2019
    Date of Patent: November 14, 2023
    Assignees: Rohm and Haas Company, Dow Global Technologies LLC
    Inventors: Kirk W. Limbach, Christopher D. Frick, Dmitry A. Krapchetov, Wen -Sheng Lee, Victor J. Sussman, Jeffrey A. Herron
  • Patent number: 11814608
    Abstract: A fabric care composition is provided including water; a cleaning surfactant; a fabric softening silicone; and a modified carbohydrate polymer having a weight average molecular weight of <500,000 Daltons and a Kjeldahl nitrogen content corrected for ash and volatiles, TKN, of ?0.5 wt %; wherein the modified carbohydrate polymer is a carbohydrate polymer functionalized with quaternary ammonium moieties; wherein the quaternary ammonium moieties on the modified carbohydrate polymer include: trimethyl ammonium moieties having formula (I) and dimethyl(alkyl) ammonium moieties having formula (II) wherein each R is independently selected from a C8-22 alkyl group.
    Type: Grant
    Filed: October 15, 2019
    Date of Patent: November 14, 2023
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, Dow Silicones Corporation, ROHM AND HAAS COMPANY
    Inventors: Emmett M. Partain, III, Jan E. Shulman, Leon Marteaux, Michael B. Clark, Jr., Aline Migliore, Yunshen Chen, Randara Pulukkody, Daniel S. Miller, John Hayes, Asghar A. Peera, Peilin Yang, Mariann Clark, Stephen J. Donovan, Jennifer P. Todd, Cynthia Leslie
  • Publication number: 20230357471
    Abstract: Disclosed is a composition comprising a polyolefin polymer and a core-shell acrylic polymer comprising a high molecular weight processing aid and a carrier resin. The high molecular weight processing aid is present in an amount ranging from 30% to less than 100% by weight relative to the total weight of the high molecular weight processing aid and the carrier resin, and the carrier resin is present in an amount ranging from greater than 0% to 70% by weight relative to the total weight of the high molecular weight processing aid and the carrier resin. The composition is in the form of particles having an average particle size of at least 2 mm.
    Type: Application
    Filed: September 24, 2021
    Publication date: November 9, 2023
    Applicant: Rohm and Haas Company
    Inventors: John E. Cornetta, Ian J. Drake, Richard J. Ketz, Hailan Guo, Theodore P. Price
  • Patent number: 11802227
    Abstract: Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) an epoxy-terminated polyester compound, (C) a phosphoric acid, and (D) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing an epoxy-terminated polyester compound, mixing the polyester-urethane resin, epoxy-terminated polyester compound, and phosphoric acid to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12.
    Type: Grant
    Filed: April 24, 2018
    Date of Patent: October 31, 2023
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Wenwen Li, Joseph J. Zupancic, William J. Harris, Paul G. Clark, Thorsten Schmidt
  • Patent number: 11800886
    Abstract: Polyesters, such as those formed using polyols and di- or tri-carboxylic acids or anhydrides or salts thereof, are used as foam control agents in foodstuff processing. The polyesters are biodegradable and biocompatible while still providing excellent foam control capacity. In addition, polyesters foam control agents of the disclosure can be used with various apparatus while avoiding forming films that otherwise affect apparatus function. The polyesters can be used at various stages during industrial processing of vegetables (e.g., potatoes and beets) and fruits.
    Type: Grant
    Filed: November 19, 2019
    Date of Patent: October 31, 2023
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Wei Gao, Tianlan Zhang, Xue Chen
  • Patent number: 11802174
    Abstract: Provided is a polymer particle comprising (a) a core polymer comprising (i) polymerized units of one or more Si-containing monomers; (ii) polymerized units of one or more monovinyl acrylic monomers (ii); and (iii) polymerized units of one or more graftlinkers that have no silicon atoms; (b) a shell polymer comprising polymerized units of one or more acrylic monomers. Also provided is a composition comprising polyvinyl chloride and a plurality of the polyer particles.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: October 31, 2023
    Assignees: Rohm and Haas Company, Dow Silicones Corporation
    Inventors: Yang Cheng, Morris Wills, Hailan Guo, Nanguo Liu
  • Publication number: 20230322999
    Abstract: The present invention relates to a composition comprising an aqueous dispersion of opacifying pigment-binder hybrid polymer particles and a dispersant functionalized with a sulfur acid monomer absorbed to opacifying pigment particles. The composition of the present invention is useful for improving wet-hide performance in paints.
    Type: Application
    Filed: August 19, 2021
    Publication date: October 12, 2023
    Applicants: Rohm and Haas Company, Rohm and Haas Company
    Inventors: Jonathan DeRocher, Antony K. Van Dyk, Qing Zhang
  • Patent number: 11773303
    Abstract: Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) a phosphate ester compound, and (C) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing a phosphate ester compound, mixing the polyester-urethane resin and phosphate ester compound to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content of from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12. Laminates prepared comprising the solvent-based adhesives and according to the disclosed methods are also disclosed.
    Type: Grant
    Filed: April 4, 2018
    Date of Patent: October 3, 2023
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Wenwen Li, Joseph J. Zupancic, Paul Clark, Thorsten Schmidt
  • Patent number: 11760822
    Abstract: Disclosed is a method comprising: a) dispersing a first monomer mixture comprising least one least monomer, the first monomer mixture having a total glass transition temperature (Tg) in the range of from ?10° C. to ?65° C. with a surfactant and an initiator in an aqueous medium; b) when the first monomer mixture is completely dispersed, adding a second monomer mixture comprising at least one monomer, the second monomer mixture having a Tg at least 20° C. greater than the Tg of the first monomer mixture, to the aqueous medium; c) when the second monomer mixture is completely dispersed, adding a third monomer mixture comprising at least one monomer, the third monomer mixture having a Tg in the range of from ?25° C. to 50° C.; and d) forming a polymer with the first, second, and third monomer mixtures. Also disclosed is a pressure sensitive adhesive comprising the polymer formed by this method.
    Type: Grant
    Filed: March 2, 2016
    Date of Patent: September 19, 2023
    Assignee: Rohm and Haas Company
    Inventors: Melinda L. Einsla, Steven R. Patrick, William B. Griffith, Jr., Paul Nedwick
  • Patent number: 11760713
    Abstract: The present invention relates to a compound which is a benzophenone substituted with a hydroxyl-terminated alkylene oxide group (R) of formula 1: where R is a combination of from 1 to 13 propylene oxide groups and from 5 to 20 ethylene oxide groups, with the proviso that the sum of the propylene oxide groups and the ethylene oxide groups is not greater than 25. The compound of the present invention provides a non-volatile, non-toxic photoinitiator that provides excellent gloss retention in exterior architectural coatings.
    Type: Grant
    Filed: December 2, 2019
    Date of Patent: September 19, 2023
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Matthew E. Belowich, Alvin M. Maurice, Jordan Stracke, Mark D. Westmeyer
  • Patent number: 11753555
    Abstract: A dispersion contains: (a) a polyorganosiloxane with at least 90 mole % dimethyl D units and viscosity of one kPa*s or more dispersed as 0.5-20 micrometer particles; (b) a condensation product of: (i) a polysiloxane resin (Mw of 4,000-50,000) with composition: (R3SiO1/2)a(SiO4/2)b(ZO1/2)c where a is 0.30-0.60, b is 0.40-0.70, c is 0.05-0.20, a+b is one, R is selected from hydrogen, C1?30 alkyl groups and aryl groups, and Z is selected from H, and C18 alkyls; and (ii) a polyoxyalkylene polymer (Mn of 4,500-50,000) with composition: A—O—(C2H4O)e(C3H6O)p—A? where e/p is 1-9, A and A? are selected from hydrogen, alkyl, substituted alkyl, aryl, and substituted aryl groups and at least one of A and A? is H; (c) non-aqueous fluid carrier miscible with (a); and (d) monoterpene; the weight-ratio of (c) to (b) is 0.5-1; weight-ratio of (b) and (c) to (a) is 0.01-0.50; and the composition contains below one ppm aromatic solvent.
    Type: Grant
    Filed: October 11, 2021
    Date of Patent: September 12, 2023
    Assignees: DOW SILICONES CORPORATION, ROHM AND HAAS COMPANY
    Inventors: Patrick J. Fryfogle, Julie Cook, Tim Mitchell, Yihan Liu, Rebecca Beeson, Miroslav Janco, Mikayla T. Miller, Brad J. Phillips
  • Patent number: 11746236
    Abstract: A composition contains the following components: (a) 15 to 49.8 volume-percent of a first polysiloxane that is has a viscosity in a range of 50 centiStokes to 550 Stokes as determined according to ASTM D4283-98; (b) 0.2 to 5 volume-percent of an organoclay; (c) 50-74 volume-percent roundish or crushed thermally conductive fillers including: (i) 5 to 15 volume-percent small thermally conductive fillers having a median particle size in a range of 0.1 to 1.0 micrometers; (ii) 10 to 25 volume-percent medium thermally conductive fillers having a median particle size in a range of 1.1 to 5.0 micrometers; (iii) 25 to 50 volume-percent large thermally conductive fillers having a median particle size in a range of 5.1 to 50 micrometers; and (d) 0 to 5 volume-percent of an alkoxy functional linear polysiloxane different from the first polysiloxane and/or an alkoxy functional linear silane; where volume-percent values are relative to composition volume.
    Type: Grant
    Filed: February 11, 2021
    Date of Patent: September 5, 2023
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, DOW SILICONES CORPORATION, ROHM AND HAAS COMPANY
    Inventors: Erica A. Frankel, Andrés E. Becerra, Andrew J. Swartz, Darren Hansen
  • Publication number: 20230265222
    Abstract: An interpolymer, which comprises at least one siloxane group, and prepared by polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one siloxane monomer, in the presence of a catalyst system comprising a Group 3-10 metal complex, and the siloxane monomer is selected from the following Formula 1: Aa-Si(Bb)(Cc)(Hh0)—O—(Si(Dd)(Ee) (Hh1)—O)x—Si(Ff)(Gg)(Hh2), described herein. An ethylene/siloxane interpolymer comprising at least one chemical unit of Structure 1, or at least one chemical unit of Structure 2, each described herein. A process to form an interpolymer, which comprises, in polymerized form, at least one siloxane monomer, or at least one silane monomer without a siloxane linkage, said process comprising polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one monomer of Formula 4, described herein, in the presence of a catalyst system comprising a metal complex from Formula A or Formula B, each described herein.
    Type: Application
    Filed: June 23, 2021
    Publication date: August 24, 2023
    Applicants: Dow Global Technologies LLC, Dow Silicones Corporation, Rohm and Haas Company
    Inventors: Liam Spencer, Zachary S. Kean, David D. Devore, Jordan C. Reddel, Bethany M. Neilson, Matthew Olsen, Zhanjie Li, Phillip D. Hustad
  • Patent number: 11732119
    Abstract: A semiconductive composite material consisting essentially of a polar organic copolymer and an electrical conducting effective amount of an ultra-low-wettability carbon black. Also a method of making the composite material; a crosslinked polyethylene product made by curing the composite material; manufactured articles comprising a shaped form of the inventive composite material or product; and methods of using the inventive composite material, product, or articles.
    Type: Grant
    Filed: March 22, 2019
    Date of Patent: August 22, 2023
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY
    Inventors: Tian Lan, Xindi Yu, Michael Q. Tran, Paul J. Brigandi, Jeffrey M. Cogen, Timothy J. Person, Yichi Zhang