Patents Assigned to Rohm & Haas Company
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Patent number: 11846912Abstract: Embodiments of the present disclosure are directed to printing systems and methods that may include an ink composition including electrically charged ink particles dispersed in a hydrocarbon liquid and a multilayer film. The multilayer film may include a polymeric core layer; and one or more printing layers adjacent to the polymeric core layer. The one or more printing layers may include at least 50 wt. % of an ethylene vinyl acetate copolymer having acid and acrylate functional groups. The ethylene vinyl acetate copolymer having acid and acrylate functional groups may include from 0.5 wt. % to 4 wt. % methacrylic or acrylic acid; from 0.5 wt. % to 4 wt. % acrylate, from 7 wt. % to 40 wt. % vinyl acetate; and the balance ethylene, based on the total weight of the ethylene vinyl acetate copolymer having acid and acrylate functional groups.Type: GrantFiled: April 27, 2020Date of Patent: December 19, 2023Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Juan Carlos Casarrubias, Nicolas Cardoso Mazzola, Barry Alan Morris, Jorge Caminero Gomes
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Patent number: 11845829Abstract: A two-component polyurethane composition comprising: a specific emulsion polymer, and a water-dispersible polyisocyanate; the emulsion polymer comprising, by weight based on the weight of the emulsion polymer, (a) greater than 15% to less than 30% of structural units of tert-butyl methacrylate, (b) greater than 10% of structural units of a hydroxy-functional alkyl (meth)acrylate, (c) structural units of a phosphorous-containing acid monomer and/or a salt thereof, (d) structural units of an additional acid monomer and/or a salt thereof, and (e) structural units of an additional monoethylenically unsaturated nonionic monomer; wherein the weight ratio of (d)/(c) is in the range of from 7.1:1 to 9.9:1; and a process of preparing the two-component polyurethane composition.Type: GrantFiled: August 15, 2019Date of Patent: December 19, 2023Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANYInventors: Xiaohong Yang, Fengzhe Shi, Jinfei Wang, Juan Zhao, Li Zhou
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Publication number: 20230398044Abstract: Described herein are aspherical hollow silica particles, processes for making aspherical hollow silica particles, and uses of aspherical hollow silica particles in sun care compositions. To form the aspherical hollow silica particles, deposition of a silica shell on a calcium carbonate template using a sol-gel chemistry is employed. Subsequent dissolution of the calcium carbonate template forms voids (e.g., a hollow interior) in the aspherical hollow silica particles.Type: ApplicationFiled: October 28, 2021Publication date: December 14, 2023Applicants: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANYInventors: Jie XIONG, Fanwen ZENG, Wenjun XU, Dean M. MILLAR
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Patent number: 11834780Abstract: Provided are a process, the process includes (i) first, contacting a textile with an aqueous solution containing a cationic hydroxyethylcellulose polymer to form a modified textile component; (ii) subsequently, impregnating the modified textile component with an aqueous polyurethane dispersion externally stabilized with an anionic surfactant, the aqueous polyurethane dispersion including a second surfactant; and (iii) precipitating the polyurethane in the modified textile component. Also disclosed are a synthetic leather produced by the process.Type: GrantFiled: August 21, 2018Date of Patent: December 5, 2023Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Yunlong Guo, Yi Zhang, Zhaohui Qu, Xiangyang Tai
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Publication number: 20230383112Abstract: The present invention relates to a composition comprising 1) an aqueous dispersion of multistage opacifying polymer particles with a superposing binder layer; 2) a colorant; and 3) inorganic opacifying pigment particles. The composition of the present invention is useful for one coat hide paint formulations.Type: ApplicationFiled: September 24, 2021Publication date: November 30, 2023Applicant: Rohm and Haas CompanyInventors: Qing Zhang, Yujie Lu
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Patent number: 11814512Abstract: A multi-stage flexible acrylic resin comprises a branched polymer which is a reaction product of reactants comprising one or more monoethylenically unsaturated ester monomers, a chain transfer agent in an amount of 0.1 to 10 wt. %, and a crosslinker in an amount of 0.1 to 10 wt. %, wherein wt. % is based on total amount of reactants, provided the amount of crosslinker in moles is less than the amount of chain transfer agent in moles. A process for producing the multi-stage flexible acrylic resin is also disclosed.Type: GrantFiled: March 13, 2020Date of Patent: November 14, 2023Assignee: Rohm and Haas CompanyInventors: Pu Luo, Hailan Guo, Morris Wills
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Patent number: 11813593Abstract: A heterogeneous catalyst comprising a support and gold, wherein: (i) said support comprises alumina, (ii) said catalyst comprises from 0.1 to 5 wt % of gold, (iii) at least 90 wt % of the gold is in the outer 60% of catalyst volume, and (iv) particles of the catalyst have an average diameter from 200 microns to 30 mm; wherein weight percentages are based on weight of the catalyst.Type: GrantFiled: June 20, 2019Date of Patent: November 14, 2023Assignees: Rohm and Haas Company, Dow Global Technologies LLCInventors: Kirk W. Limbach, Christopher D. Frick, Dmitry A. Krapchetov, Wen -Sheng Lee, Victor J. Sussman, Jeffrey A. Herron
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Patent number: 11814608Abstract: A fabric care composition is provided including water; a cleaning surfactant; a fabric softening silicone; and a modified carbohydrate polymer having a weight average molecular weight of <500,000 Daltons and a Kjeldahl nitrogen content corrected for ash and volatiles, TKN, of ?0.5 wt %; wherein the modified carbohydrate polymer is a carbohydrate polymer functionalized with quaternary ammonium moieties; wherein the quaternary ammonium moieties on the modified carbohydrate polymer include: trimethyl ammonium moieties having formula (I) and dimethyl(alkyl) ammonium moieties having formula (II) wherein each R is independently selected from a C8-22 alkyl group.Type: GrantFiled: October 15, 2019Date of Patent: November 14, 2023Assignees: DOW GLOBAL TECHNOLOGIES LLC, Dow Silicones Corporation, ROHM AND HAAS COMPANYInventors: Emmett M. Partain, III, Jan E. Shulman, Leon Marteaux, Michael B. Clark, Jr., Aline Migliore, Yunshen Chen, Randara Pulukkody, Daniel S. Miller, John Hayes, Asghar A. Peera, Peilin Yang, Mariann Clark, Stephen J. Donovan, Jennifer P. Todd, Cynthia Leslie
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Publication number: 20230357471Abstract: Disclosed is a composition comprising a polyolefin polymer and a core-shell acrylic polymer comprising a high molecular weight processing aid and a carrier resin. The high molecular weight processing aid is present in an amount ranging from 30% to less than 100% by weight relative to the total weight of the high molecular weight processing aid and the carrier resin, and the carrier resin is present in an amount ranging from greater than 0% to 70% by weight relative to the total weight of the high molecular weight processing aid and the carrier resin. The composition is in the form of particles having an average particle size of at least 2 mm.Type: ApplicationFiled: September 24, 2021Publication date: November 9, 2023Applicant: Rohm and Haas CompanyInventors: John E. Cornetta, Ian J. Drake, Richard J. Ketz, Hailan Guo, Theodore P. Price
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Patent number: 11802227Abstract: Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) an epoxy-terminated polyester compound, (C) a phosphoric acid, and (D) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing an epoxy-terminated polyester compound, mixing the polyester-urethane resin, epoxy-terminated polyester compound, and phosphoric acid to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12.Type: GrantFiled: April 24, 2018Date of Patent: October 31, 2023Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Wenwen Li, Joseph J. Zupancic, William J. Harris, Paul G. Clark, Thorsten Schmidt
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Patent number: 11800886Abstract: Polyesters, such as those formed using polyols and di- or tri-carboxylic acids or anhydrides or salts thereof, are used as foam control agents in foodstuff processing. The polyesters are biodegradable and biocompatible while still providing excellent foam control capacity. In addition, polyesters foam control agents of the disclosure can be used with various apparatus while avoiding forming films that otherwise affect apparatus function. The polyesters can be used at various stages during industrial processing of vegetables (e.g., potatoes and beets) and fruits.Type: GrantFiled: November 19, 2019Date of Patent: October 31, 2023Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Wei Gao, Tianlan Zhang, Xue Chen
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Patent number: 11802174Abstract: Provided is a polymer particle comprising (a) a core polymer comprising (i) polymerized units of one or more Si-containing monomers; (ii) polymerized units of one or more monovinyl acrylic monomers (ii); and (iii) polymerized units of one or more graftlinkers that have no silicon atoms; (b) a shell polymer comprising polymerized units of one or more acrylic monomers. Also provided is a composition comprising polyvinyl chloride and a plurality of the polyer particles.Type: GrantFiled: July 26, 2019Date of Patent: October 31, 2023Assignees: Rohm and Haas Company, Dow Silicones CorporationInventors: Yang Cheng, Morris Wills, Hailan Guo, Nanguo Liu
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Publication number: 20230322999Abstract: The present invention relates to a composition comprising an aqueous dispersion of opacifying pigment-binder hybrid polymer particles and a dispersant functionalized with a sulfur acid monomer absorbed to opacifying pigment particles. The composition of the present invention is useful for improving wet-hide performance in paints.Type: ApplicationFiled: August 19, 2021Publication date: October 12, 2023Applicants: Rohm and Haas Company, Rohm and Haas CompanyInventors: Jonathan DeRocher, Antony K. Van Dyk, Qing Zhang
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Patent number: 11773303Abstract: Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) a phosphate ester compound, and (C) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing a phosphate ester compound, mixing the polyester-urethane resin and phosphate ester compound to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content of from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12. Laminates prepared comprising the solvent-based adhesives and according to the disclosed methods are also disclosed.Type: GrantFiled: April 4, 2018Date of Patent: October 3, 2023Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Wenwen Li, Joseph J. Zupancic, Paul Clark, Thorsten Schmidt
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Patent number: 11760822Abstract: Disclosed is a method comprising: a) dispersing a first monomer mixture comprising least one least monomer, the first monomer mixture having a total glass transition temperature (Tg) in the range of from ?10° C. to ?65° C. with a surfactant and an initiator in an aqueous medium; b) when the first monomer mixture is completely dispersed, adding a second monomer mixture comprising at least one monomer, the second monomer mixture having a Tg at least 20° C. greater than the Tg of the first monomer mixture, to the aqueous medium; c) when the second monomer mixture is completely dispersed, adding a third monomer mixture comprising at least one monomer, the third monomer mixture having a Tg in the range of from ?25° C. to 50° C.; and d) forming a polymer with the first, second, and third monomer mixtures. Also disclosed is a pressure sensitive adhesive comprising the polymer formed by this method.Type: GrantFiled: March 2, 2016Date of Patent: September 19, 2023Assignee: Rohm and Haas CompanyInventors: Melinda L. Einsla, Steven R. Patrick, William B. Griffith, Jr., Paul Nedwick
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Patent number: 11760713Abstract: The present invention relates to a compound which is a benzophenone substituted with a hydroxyl-terminated alkylene oxide group (R) of formula 1: where R is a combination of from 1 to 13 propylene oxide groups and from 5 to 20 ethylene oxide groups, with the proviso that the sum of the propylene oxide groups and the ethylene oxide groups is not greater than 25. The compound of the present invention provides a non-volatile, non-toxic photoinitiator that provides excellent gloss retention in exterior architectural coatings.Type: GrantFiled: December 2, 2019Date of Patent: September 19, 2023Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Matthew E. Belowich, Alvin M. Maurice, Jordan Stracke, Mark D. Westmeyer
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Patent number: 11753555Abstract: A dispersion contains: (a) a polyorganosiloxane with at least 90 mole % dimethyl D units and viscosity of one kPa*s or more dispersed as 0.5-20 micrometer particles; (b) a condensation product of: (i) a polysiloxane resin (Mw of 4,000-50,000) with composition: (R3SiO1/2)a(SiO4/2)b(ZO1/2)c where a is 0.30-0.60, b is 0.40-0.70, c is 0.05-0.20, a+b is one, R is selected from hydrogen, C1?30 alkyl groups and aryl groups, and Z is selected from H, and C18 alkyls; and (ii) a polyoxyalkylene polymer (Mn of 4,500-50,000) with composition: A—O—(C2H4O)e(C3H6O)p—A? where e/p is 1-9, A and A? are selected from hydrogen, alkyl, substituted alkyl, aryl, and substituted aryl groups and at least one of A and A? is H; (c) non-aqueous fluid carrier miscible with (a); and (d) monoterpene; the weight-ratio of (c) to (b) is 0.5-1; weight-ratio of (b) and (c) to (a) is 0.01-0.50; and the composition contains below one ppm aromatic solvent.Type: GrantFiled: October 11, 2021Date of Patent: September 12, 2023Assignees: DOW SILICONES CORPORATION, ROHM AND HAAS COMPANYInventors: Patrick J. Fryfogle, Julie Cook, Tim Mitchell, Yihan Liu, Rebecca Beeson, Miroslav Janco, Mikayla T. Miller, Brad J. Phillips
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Patent number: 11746236Abstract: A composition contains the following components: (a) 15 to 49.8 volume-percent of a first polysiloxane that is has a viscosity in a range of 50 centiStokes to 550 Stokes as determined according to ASTM D4283-98; (b) 0.2 to 5 volume-percent of an organoclay; (c) 50-74 volume-percent roundish or crushed thermally conductive fillers including: (i) 5 to 15 volume-percent small thermally conductive fillers having a median particle size in a range of 0.1 to 1.0 micrometers; (ii) 10 to 25 volume-percent medium thermally conductive fillers having a median particle size in a range of 1.1 to 5.0 micrometers; (iii) 25 to 50 volume-percent large thermally conductive fillers having a median particle size in a range of 5.1 to 50 micrometers; and (d) 0 to 5 volume-percent of an alkoxy functional linear polysiloxane different from the first polysiloxane and/or an alkoxy functional linear silane; where volume-percent values are relative to composition volume.Type: GrantFiled: February 11, 2021Date of Patent: September 5, 2023Assignees: DOW GLOBAL TECHNOLOGIES LLC, DOW SILICONES CORPORATION, ROHM AND HAAS COMPANYInventors: Erica A. Frankel, Andrés E. Becerra, Andrew J. Swartz, Darren Hansen
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Publication number: 20230265222Abstract: An interpolymer, which comprises at least one siloxane group, and prepared by polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one siloxane monomer, in the presence of a catalyst system comprising a Group 3-10 metal complex, and the siloxane monomer is selected from the following Formula 1: Aa-Si(Bb)(Cc)(Hh0)—O—(Si(Dd)(Ee) (Hh1)—O)x—Si(Ff)(Gg)(Hh2), described herein. An ethylene/siloxane interpolymer comprising at least one chemical unit of Structure 1, or at least one chemical unit of Structure 2, each described herein. A process to form an interpolymer, which comprises, in polymerized form, at least one siloxane monomer, or at least one silane monomer without a siloxane linkage, said process comprising polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one monomer of Formula 4, described herein, in the presence of a catalyst system comprising a metal complex from Formula A or Formula B, each described herein.Type: ApplicationFiled: June 23, 2021Publication date: August 24, 2023Applicants: Dow Global Technologies LLC, Dow Silicones Corporation, Rohm and Haas CompanyInventors: Liam Spencer, Zachary S. Kean, David D. Devore, Jordan C. Reddel, Bethany M. Neilson, Matthew Olsen, Zhanjie Li, Phillip D. Hustad
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Patent number: 11732119Abstract: A semiconductive composite material consisting essentially of a polar organic copolymer and an electrical conducting effective amount of an ultra-low-wettability carbon black. Also a method of making the composite material; a crosslinked polyethylene product made by curing the composite material; manufactured articles comprising a shaped form of the inventive composite material or product; and methods of using the inventive composite material, product, or articles.Type: GrantFiled: March 22, 2019Date of Patent: August 22, 2023Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANYInventors: Tian Lan, Xindi Yu, Michael Q. Tran, Paul J. Brigandi, Jeffrey M. Cogen, Timothy J. Person, Yichi Zhang