Patents Assigned to Roman Cement, LLC
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Patent number: 11746048Abstract: Method of efficiently manufacturing cement-SCM compositions having improved strength compared to cement-SCM compositions made using conventional methods. The cement-SCM compositions may contain: (A) a fine interground particulate component with (1) a hydraulic cement fraction and (2) a supplementary cementitious material (SCM) fraction; (B) a coarse particulate component comprised of coarse SCM particles not interground with the fine interground particulate component; and optionally (C) an auxiliary particulate component not interground with the fine interground particulate component or the coarse particulate component. A method of manufacturing a cement-SCM composition may be performed by: (A) intergrinding hydraulic cement (e.g.Type: GrantFiled: July 31, 2020Date of Patent: September 5, 2023Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 11655186Abstract: An activated pozzolan composition includes a fine interground particulate blend of an initially unactivated natural pozzolan and a supplementary cementitious material (SCM) different than the initially unactivated natural pozzolan. The initially unactivated natural pozzolan may include volcanic ash or other natural pozzolanic deposit having a moisture content of at least 3%, and the activated pozzolan composition can have a moisture content less than 0.5% The initially unactivated natural pozzolan may have a particle size less than 1 mm before intergrinding with the SCM.Type: GrantFiled: January 8, 2019Date of Patent: May 23, 2023Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 11472737Abstract: A non-conforming (or barely conforming) fly ash is converted into conforming (or better conforming) fly ash by: (1) obtaining an initial fly ash with at least one non-conforming (or barely conforming) characteristic selected from excess carbon content, low strength activity index, or low SAF as defined by ASTM C-618 and having a D10, D50 and D90; (2) classifying the initial fly ash using one or more air classifiers to produce at least two separate fly ash streams, including fine fly ash and coarse fly ash; (3) collecting the fine fly ash and the coarse fly ash, the fine fly ash having a D90 less than the D90 of the initial fly ash; (4) combining the fine fly ash with an aluminosilicate source to form a modified fly ash having a conforming carbon content, a conforming reactivity index, and a conforming SAF as defined by ASTM C-618.Type: GrantFiled: February 25, 2021Date of Patent: October 18, 2022Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 11168029Abstract: Mineral fines are used to reduce clinker content in concrete, mortar and other cementitious compositions, typically in combination with one or more pozzolanically active SCMs. Mineral fines can replace and/or augment a portion of hydraulic cement binder and/or fine aggregate. Mineral fines can advantageously replace a portion of cement binder and fine aggregate, acting as an intermediate that fills a particle size void between the largest cement particles and smallest fine aggregate particles. Supplemental lime can advantageously maintain or enhance balance of calcium ions in the mix water and/or pore solution. Supplemental sulfate can advantageously address sulfate deficiencies caused by high clinker reduction, use of water reducers and/or superplasticizers, and SCMs containing aluminates. Such systematic approach to beneficially using mineral fines, SCMs, lime, and sulfate addresses many issues and permits high clinker reduction with similar or increased strength.Type: GrantFiled: July 6, 2020Date of Patent: November 9, 2021Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 10968137Abstract: A non-conforming fly ash is converted into conforming fly ash by: (1) obtaining an initial fly ash with at least one non-conforming characteristic selected from excess carbon or low reactivity index as defined by ASTM C-618 and having a D10, D50 and D90; (2) classifying the initial fly ash using one or more air classifiers to produce at least two separate fly ash streams, including fine fly ash and coarse fly ash; and (3) collecting the fine fly ash and the coarse fly ash, (4) the fine fly ash having a D90 approximately equal to or less than the D50 of the initial fly ash and a conforming carbon content and a conforming reactivity index as defined by ASTM C-618.Type: GrantFiled: April 30, 2018Date of Patent: April 6, 2021Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 10737980Abstract: Quarry fines and/or limestone powder are used to reduce clinker content in concrete, mortar and other cementitious compositions, typically in combination with one or more pozzolanically active SCMs. Quarry fines and/or limestone powder can replace and/or augment a portion of hydraulic cement binder and/or fine aggregate. Quarry fines and/or limestone powder can advantageously replace a portion of cement binder and fine aggregate, acting as an intermediate that fills a particle size void between the largest cement particles and smallest fine aggregate particles. Supplemental lime can advantageously maintain or enhance balance of calcium ions in the mix water and/or pore solution. Supplemental sulfate can advantageously address sulfate deficiencies caused by high clinker reduction, use of water reducers and/or superplasticers, and SCMs containing aluminates.Type: GrantFiled: November 5, 2018Date of Patent: August 11, 2020Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 10730805Abstract: Quarry fines and/or limestone powder are used to reduce clinker content in concrete, mortar and other cementitious compositions, typically in combination with one or more pozzolanically active SCMs. Quarry fines and/or limestone powder can replace and/or augment a portion of hydraulic cement binder and/or fine aggregate. Quarry fines and/or limestone powder can advantageously replace a portion of cement binder and fine aggregate, acting as an intermediate that fills a particle size void between the largest cement particles and smallest fine aggregate particles. Supplemental lime can advantageously maintain or enhance balance of calcium ions in the mix water and/or pore solution. Supplemental sulfate can advantageously address sulfate deficiencies caused by high clinker reduction, use of water reducers and/or superplasticers, and SCMs containing aluminates.Type: GrantFiled: July 5, 2018Date of Patent: August 4, 2020Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 10526248Abstract: A cementitious composition includes (i) white Portland cement having a fineness of about 350-550 m2/kg, D90 between about 11-50 ?m, and total combined iron oxide, manganese oxide, and chromium oxide <1.0% by weight (ii) light color pozzolan such as white silica fume, and (iii) at least one light color particulate material, such as ground granulated blast furnace slag (GGBFS) having a fineness greater than that of the white Portland cement, a D90 less than that of the white Portland cement, and total combined iron oxide, manganese oxide, and chromium oxide content <3.0% by weight and/or coarse limestone powder having a D90 greater than that of the white cement. The cementitious composition may include one or more of aggregates, fibers, or admixture. The cementitious composition can be a dry blend, fresh cementitious mixture, or hardened cementitious composition. The cementitious composition can be precast concrete, stucco, GFRC, UHPC or SCC.Type: GrantFiled: April 11, 2018Date of Patent: January 7, 2020Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 10494298Abstract: Cement-SCM compositions have improved strength compared to cement-SCM compositions made using conventional blended cements and methods. The cement-SCM compositions may contain: (A) a fine interground particulate component with (1) a hydraulic cement fraction and (2) a supplementary cementitious material (SCM) fraction; (B) a coarse particulate component comprised of coarse SCM particles not interground with the fine interground particulate component; and optionally (C) an auxiliary particulate component not interground with the fine interground particulate component or the coarse particulate component. A method of manufacturing a cement-SCM composition may be performed by: (A) intergrinding hydraulic cement (e.g.Type: GrantFiled: October 24, 2016Date of Patent: December 3, 2019Assignee: ROMAN CEMENT LLCInventor: John M. Guynn
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Patent number: 10233116Abstract: An activated pozzolan composition includes a fine interground particulate blend of an initially unactivated natural pozzolan and a supplementary cementitious material (SCM) different than the initially unactivated natural pozzolan. The initially unactivated natural pozzolan may include volcanic ash or other natural pozzolanic deposit having a moisture content of at least 3%, and the activated pozzolan composition can have a moisture content less than 0.5% The initially unactivated natural pozzolan may have a particle size less than 1 mm before intergrinding with the SCM.Type: GrantFiled: January 5, 2018Date of Patent: March 19, 2019Assignee: ROMAN CEMENT, LLCInventor: John M. Guynn
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Patent number: 10131575Abstract: Quarry fines and/or limestone powder are used to reduce clinker content in concrete, mortar and other cementitious compositions, typically in combination with one or more pozzolanically active SCMs. Quarry fines and/or limestone powder can replace and/or augment a portion of hydraulic cement binder and/or fine aggregate. Quarry fines and/or limestone powder can advantageously replace a portion of cement binder and fine aggregate, acting as an intermediate that fills a particle size void between the largest cement particles and smallest fine aggregate particles. Supplemental lime can advantageously maintain or enhance balance of calcium ions in the mix water and/or pore solution. Supplemental sulfate can advantageously address sulfate deficiencies caused by high clinker reduction, use of water reducers and/or superplasticers, and SCMs containing aluminates.Type: GrantFiled: January 9, 2018Date of Patent: November 20, 2018Assignee: Roman Cement, LLCInventor: John M. Guynn
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Patent number: 9957196Abstract: A cementitious composition includes (i) white Portland cement having a Blaine fineness between about 350 m2/kg and about 550 m2/kg, a D90 between about 11 ?m and about 50 ?m, and a total combined iron oxide, manganese oxide, and chromium oxide content of less than 1.0% by weight and (ii) a light color ground granulated blast furnace slag (GGBFS) having a Blaine fineness greater than the Blaine fineness of the white Portland cement, a D90 less than the D90 of the white Portland cement, and a total combined iron oxide, manganese oxide, and chromium oxide content of less than 2.0% by weight. The cementitious composition may optionally include at least one of additional SCM, aggregate, fibers, or admixture. The cementitious composition can be a dry blend, a fresh cementitious mixture, or hardened cementitious composition. The cementitious composition can be precast concrete, stucco, GFRC, UHPC or SCC.Type: GrantFiled: May 17, 2017Date of Patent: May 1, 2018Assignee: ROMAN CEMENT LLCInventor: John M. Guynn
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Publication number: 20180037501Abstract: Methods for producing a blended pozzolan having one or more characteristics, such as one or more chemical and/or physical characteristic, in an established amount or range from two or more different pozzolans. Two or more pozzolans having different chemical and/or physical characteristics can be blended together and a chemical analyzer used to determine a chemical and/or physical characteristic of the blended pozzolan. Upon determining that the chemical and/or physical characteristic of the blended pozzolan is outside the established amount or range, modifying a blending ratio of the two or more pozzolans to restore the chemical and/or physical characteristic to the established amount or range.Type: ApplicationFiled: June 29, 2015Publication date: February 8, 2018Applicant: Roman Cement, LLCInventors: John M. Guynn, Andrew S. Hansen
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Patent number: 9272953Abstract: Hydraulic cements, such as Portland cements and other cements that include substantial quantities of tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and/or tetracalcalcium alumino-ferrite (C4AF), are particle size optimized to have increased reactivity compared to cements of similar chemistry and/or decreased water demand compared to cements of similar fineness. Increasing hydraulic cement reactivity increases early strength development and release of reactive calcium hydroxide, both of which enhance SCM replacement and 1-28 day strengths compared to blends of conventional Portland cement and one or more SCMs, such as coal ash, slag or natural pozzolan. Decreasing the water demand can improve strength by decreasing the water-to-cement ratio for a given workability. The narrow PSD cements are well suited for making blended cements, including binary, ternary and quaternary blends.Type: GrantFiled: June 16, 2014Date of Patent: March 1, 2016Assignee: Roman Cement, LLCInventors: John M. Guynn, Andrew S. Hansen
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Patent number: 9238591Abstract: Cement-SCM blends employ particle packing principles to increase particle packing density and reduce interstitial spacing between the cement and SCM particles. Particle packing reduces the amount of water required to obtain a cement paste having a desired flow, lowers the water-cementitious material ratio (w/cm), and increases early and long-term strengths. This may be accomplished by providing a hydraulic cement fraction having a narrow PSD and at least one SCM fraction having a mean particle size that differs from the mean particle size of the narrow PSD cement by a multiple of 3.0 or more to yield a cement-SCM blend having a particle packing density of at least 57.0%.Type: GrantFiled: January 22, 2015Date of Patent: January 19, 2016Assignee: ROMAN CEMENT, LLCInventors: John M. Guynn, Andrew S. Hansen
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Patent number: 9102567Abstract: Engineered cements are described that include an engineered clinker fraction designed for use with one or more supplementary cementitious material (“SCM”) fractions. The engineered clinker fraction has a narrow particle size distribution (“PSD”) with a relatively high tricalcium silicate (“C3S”) content as compared to traditional ordinary Portland cement (“OPC”). The high C3S content and narrow PSD provide desired reactivity and set time when combined with the one or more SCMs. The clinker fraction may be combined with one or more ultrafine SCM fractions and/or one or more coarser SCM fractions to achieve a desired wide particle size distribution. By engineering the chemistry and the particle size of the clinker fraction and the SCM fraction to work together, the engineered cements can have superior packing density, water demand, reactivity, set time, sulfate resistance, and strength development as compared to conventional OPC-SCM blends.Type: GrantFiled: May 30, 2013Date of Patent: August 11, 2015Assignee: ROMAN CEMENT, LLCInventors: Andrew S. Hansen, John M. Guynn
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Patent number: 9067824Abstract: The present disclosure relates to methods for controlling the chemical composition of a first pozzolan by blending it with a different pozzolan having a different chemical composition. The method includes intimately mixing the two pozzolans and using a chemical analyzer to determine a chemical characteristic of the pozzolan fraction being produced. The output from the chemical analyzer is then used to control the blending of the first and second outputs to maintain the chemical characteristic within a desired range.Type: GrantFiled: February 17, 2011Date of Patent: June 30, 2015Assignee: ROMAN CEMENT, LLCInventors: Andrew S. Hansen, John M. Guynn
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Patent number: 8974593Abstract: Cement-SCM blends employ particle packing principles to increase particle packing density and reduce interstitial spacing between the cement and SCM particles. Particle packing reduces the amount of water required to obtain a cement paste having a desired flow, lowers the water-cementitious material ratio (w/cm), and increases early and long-term strengths. This may be accomplished by providing a hydraulic cement fraction having a narrow PSD and at least one SCM fraction having a mean particle size that differs from the mean particle size of the narrow PSD cement by a multiple of 3.0 or more to yield a cement-SCM blend having a particle packing density of at least 57.0%.Type: GrantFiled: October 17, 2012Date of Patent: March 10, 2015Assignee: Roman Cement, LLCInventors: John M. Guynn, Andrew S. Hansen
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Patent number: 8551245Abstract: Hydraulic cements, such as Portland cements and other cements that include substantial quantities of tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and/or tetracalcalcium alumino-ferrite (C4AF), are particle size optimized to have increased reactivity compared to cements of similar chemistry and/or decreased water demand compared to cements of similar fineness. Increasing hydraulic cement reactivity increases early strength development and release of reactive calcium hydroxide, both of which enhance SCM replacement and 1-28 day strengths compared to blends of conventional Portland cement and one or more SCMs, such as coal ash, slag or natural pozzolan. Decreasing the water demand can improve strength by decreasing the water-to-cement ratio for a given workability. The narrow PSD cements are well suited for making blended cements, including binary, ternary and quaternary blends.Type: GrantFiled: March 13, 2013Date of Patent: October 8, 2013Assignee: Roman Cement LLCInventors: John M. Guynn, Andrew S. Hansen
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Patent number: RE49415Abstract: Cement-SCM blends employ particle packing principles to increase particle packing density and reduce interstitial spacing between the cement and SCM particles. Particle packing reduces the amount of water required to obtain a cement paste having a desired flow, lowers the water-cementitious material ratio (w/cm), and increases early and long-term strengths. This may be accomplished by providing a hydraulic cement fraction having a narrow PSD and at least one SCM fraction having a mean particle size that differs from the mean particle size of the narrow PSD cement by a multiple of 3.0 or more to yield a cement-SCM blend having a particle packing density of at least 57.0%.Type: GrantFiled: March 6, 2019Date of Patent: February 14, 2023Assignee: ROMAN CEMENT, LLCInventors: John M. Guynn, Andrew S. Hansen