Abstract: The present invention relates to compounds according to formula I: wherein: each R1-R10 may individually be H, a halogen, an alkoxy moiety, a siloxy moiety, a nitrogen-containing moiety, an alkyl moiety, an aryl moiety, or an aralkyl moiety, wherein each R1-R10 comprises ?10 carbon atoms, wherein each of R1-R10 may form a cyclic moiety with an adjacent R1-R10 moiety; Y is O or N—R11, wherein R11 is an alkyl, cycloalkyl, aryl or aralkyl moiety comprising 1-12 carbon atoms; M is a group 3 or 4 transition metal; X is a sigma-bonded ligand, or a diene; z is the number of ligands X that are bonded to M. Such compounds may be used in a catalyst system for olefin polymerisation.

Abstract: The invention relates to a polypropylene composition comprising a terpolymer composition comprising (A) a first terpolymer fraction containing propylene, ethylene and 1-hexene, wherein the first terpolymer fraction has a melt flow rate of 0.005 to 0.20 dg/min determined by ISO 1133-1:2011 (230° C., 2.16 kg) and (B) a second terpolymer fraction containing propylene, ethylene and 1-hexene, wherein the second terpolymer fraction has a melt flow rate of 0.30 to 70 dg/min determined by ISO 1133-1:2011 (230° C., 2.16 kg), wherein the first terpolymer fraction is prepared using a first set of reaction conditions, the second terpolymer fraction is prepared using a second set of reaction conditions and the first and second set of reaction conditions are different, wherein the polypropylene composition (i) has a melt flow rate of 0.10 to 0.70 dg/min determined by ISO 1133-1:2011 (230° C., 2.16 kg), (ii) has a content of ethylene derived units in the range from 1.6 to 3.

Abstract: The present invention related to a film comprising multiple co-extruded film layers, the film having a length and a width, and a thickness defined as the dimension of the film perpendicular to the plane defined by the length and the width, wherein the film is a bi-axially oriented film comprising at least a core layer A, having a first and a second surface, and one or two sealing layer(s) B, wherein the core layer A comprises a polypropylene, and wherein the sealing layer B comprises >50.0 wt % of a polyethylene comprising moieties derived from ethylene and moieties derived from an ?-olefin comprising 4 to 10 carbon atoms, the polyethylene having a density of ?870 and ?920 kg/m3 as determined in accordance with ASTM D1505 (2010), with regard to the total weight of the sealing layer B, wherein the sealing layer B directly adheres to one of the first or second surface of the core layer A.

Abstract: Systems, devices, and methods for preventing damage of components of a heat exchanger. In some aspects, a system includes an impingement device for the distribution of fluid flow through an inlet of a heat exchanger that includes a first set of members configured to be disposed between an inlet and one or more process tubes of a heat exchanger and arranged in a first orientation, and a second set of members disposed between the first set of members and the inlet. Each member of the second set of members is arranged in a second orientation that is angularly disposed relative to the first orientation.

Abstract: The present invention relates to a pipe comprising an ethylene-based polymer, wherein the ethylene-based polymer: ? comprises ?0.10 mol % of units derived from 1-hexene, with regard to the total molar quantity of polymeric units of the ethylene-based polymer; ? has an Mw/Mn as determined in accordance with ASTM D6474 (2012) of ?2.5 and ?4.0, preferably of ?2.5 and ?3.4; ? has a density as determined in accordance with ASTM D792 (2008) of ?925 and ?945 kg/m3; and ? in the molecular weight range of log(Mw) between 4.0 and 5.5, has a comonomer branch content of between 2 and 15 comonomer-derived branches per 1000 carbon atoms in the polymer, as determined via 13C NMR. Such pipe provides a desirably high long-term strength, as demonstrated by its high strain hardening modulus, as well as desirably high impact strength, as demonstrated by its high Charpy impact strength. Further, such pipe may be compliant with the PE-RT requirements of ISO 22391-1 (2009).

Abstract: The present invention relates a polycarbonate composition comprising polycarbonate, acid stabiliser and at least one anthraquinone based colorant having at least one hydroxyl group, wherein the composition has a transmission of at least 80% in an infrared light wavelength range of from 760-1120 nm, wherein transmission is determined on an injection moulded plaque having a thickness of 2 mm prepared by injection moulding the composition at a maximum temperature of 320° C. and at a residence time of 10 minutes. Preferably the composition has a transmission of at most 10% in the visible light wavelength range of from 380-740 nm.

Abstract: A method to produce olefins may include supplying a hydrocarbon feed to an outer tube of a thermal energy recovery assembly; heating the hydrocarbon feed in the outer tube of the thermal energy recovery assembly to output a preheated hydrocarbon feed; supplying the preheated hydrocarbon feed to an electrically powered cracking furnace comprising a reaction zone to heat the preheated hydrocarbon feed; cracking the preheated hydrocarbon feed in the reaction zone of the electrically heated cracking furnace using heat generated by electricity to output hot reactor effluent comprising cracked hydrocarbons and olefins; supplying the hot reactor effluent to an inner tube of the thermal energy recovery assembly; and cooling the hot reactor effluent in the inner tube of the thermal energy recovery assembly by transferring heat to the hydrocarbon feed.

Abstract: A piezoelectric composite material is formed from a cellulosic material and an inorganic piezoelectric material dispersed in a piezoelectric polymer. The piezoelectric polymer of the composite material has a dielectric constant of from 10 or more. A method of making a piezoelectric is also disclosed wherein a matrix of a cellulosic material, an inorganic piezoelectric material, and a piezoelectric polymer material is formed. The matrix is formed into a piezoelectric composite body.

Abstract: The invention relates to a photovoltaic module comprising (a) a front layer (1) arranged on the sunlight facing side of the photovoltaic module, wherein the front layer (1) comprises a first polypropylene composition, comprising a polypropylene, wherein the transmission of the front layer for light in the wavelength range of 350 nm to 1200 nm is on average at least 65% as compared to a situation without the front layer as determined according to ASTM D1003-13, (b) a sealing layer (2,4) which at least partly encapsulates a plurality of photovoltaic cells (3), wherein the sealing layer (2, 4) comprises a polyolefin elastomer composition comprising an ethylene-?-olefin copolymer and (c) a back layer (5), wherein the back layer (5) comprises a first reinforced polypropylene layer comprising a second polypropylene composition comprising a polypropylene and optionally a reinforcing filler, wherein the sealing layer is arranged between the front layer and the back layer.

Abstract: The invention relates to an ethylene copolymer obtained by copolymerizing ethylene and an ion pair compound consisting of a cation of formula (I) and an anion selected from formulas (II), (III), (IV) and (V), wherein (I) where R1=H or C1-C10 alkyl; X?O or NH; R2=C1-C40 alkyl; R3, R4=H or C1-C10 alkyl which can be connected through a cyclic structure, R5=H or C1-C20, (II) (III) (IV) (V) where R6, R7, R9=H or C1-C10 alkyl; R8, R10=C1-C40 alkyl; Y, V, W?O or NH; n=1 to 20; Z?—SO3 or —C(O)O.

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a first hydrogenation unit producing a first process stream; passing the first process stream through a distillation unit; withdrawing a 2-butene stream from the distillation unit: passing the 2-butene stream through a second hydrogenation unit producing a 1-butene stream; passing at least a portion of the 1-butene stream through a separation unit; and passing the 1-butene stream through a hydration unit producing the fuel additive.

Abstract: The invention is directed to a chemical reactor (100) having (a) two or more gas reactor elements (12) with each gas reactor element (12) having (i) a first reaction chamber (38), and (ii) a feed assembly unit (36), (b) a second reaction chamber (20) coupled with each of the two or more gas reactor elements (12) and configured to independently receive two or more product streams from the two or more gas reactor elements (12); and optionally, (c) a gas converging section (40) located downstream to the second reaction chamber (20). The invention is further directed to a method of producing chemical products using the chemical reactor (100) of the present invention.

Abstract: The present invention relates to a process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams of chemical products comprising ethylene, propylene, isobutene, 1-butene, 2-butene, 1,2-butadiene, 1,3-butadiene, benzene, styrene, toluene, ethylbenzene and xylenes; wherein in step (d): ? the coil outlet temperature is ?800 and ?870° C., preferably ?805 and ?835° C.

Abstract: Systems and methods for carrying out metathesis reaction by utilizing one or more side reactors to a reactive distillation column is disclosed. The one or more side reactors is used to effect a reactive pump-around process. The systems and methods are used for equilibrium limited reactions such as the metathesis of C4 olefins.

Abstract: A process for producing isooctane by introducing a butane feed stream (containing n-butane, i-butane) and hydrogen into a catalytic hydrogenolysis reactor to produce a hydrogenolysis product stream; separating the hydrogenolysis product stream into a butane stream (i-butane, optionally n-butane); feeding the butane stream to a catalytic dehydrogenation reactor to produce a dehydrogenation product stream comprising saturated and unsaturated four-carbon hydrocarbons; and feeding the dehydrogenation product stream to an oligomerization unit to produce isooctene and dehydrogenating the isooctene to produce isooctane.

Abstract: Methods of producing lead-free piezoelectric composites are described. The method can include adding a lead-free piezoelectric additive to a solution that includes a solvent and polymer solubilized therein. The solvent can have i) a boiling point ?80° C. at 0.1 MPa and ii) a solubility in water of ?0.1 g/g and/or a dielectric constant ?20. The solvent can be removed to form a polymeric matrix having the lead-free piezoelectric particles dispersed therein. Electrical treatment of the polymeric matrix can form the piezoelectric component. Lead-free piezoelectric composites and devices that include the lead-free piezoelectric composites are also described.

Abstract: Piezoelectric composites are described. A piezoelectric composite can include a polymeric matrix, piezoelectric additive(s), and polyol. Methods of making and using the piezoelectric composite are also described.

Abstract: The invention relates to a process for the preparation of an ethylene-based polymer, the process comprising: a) suspension polymerizing ethylene and an optional comonomer to obtain a suspension (11) comprising the ethylene-based polymer and wax in a suspension medium comprising a diluent, b) separating the ethylene-based polymer (13) from the suspension (11) to obtain a liquid stream (12) comprising the diluent and the wax, c) feeding at least part of the liquid stream (25) to a forced circulation reboiler (Q) for separating the diluent and the wax to obtain an evaporated stream (27) comprising the diluent, wherein the evaporated stream (27) is recycled to step a).

Abstract: Systems and methods for processing a C3 and C4 hydrocarbon mixture have been disclosed. The C3 and C4 hydrocarbon mixture is separated to remove propane from C4 hydrocarbons. The resulting C4 hydrocarbons are then processed in an isomerization unit to produce additional isobutane. The isobutane of the isomerization unit effluent is dehydrogenated in a dehydrogenation unit to produce isobutene. The resulting isobutene is reacted with an alkanol to produce an alkyl tert-butyl ether.

Abstract: Systems and methods for producing light olefins and BTX (benzene, toluene, and xylene). Crude oil is first separated to produce light naphtha and heavy naphtha. Light naphtha is fed to a steam cracking unit and heavy naphtha is fed to a catalytic cracking unit. The effluent from the steam cracking unit and the effluent from the catalytic cracking unit are flowed into an oil quench tower and are further separated in a separation unit to produce an ethylene stream, a propylene stream, and a BTX stream. The C4 hydrocarbons, ethane, and propane from the effluent of the steam cracking unit and the effluent from the catalytic cracking unit are recycled to the steam cracking unit. The non-BTX C6+ hydrocarbons from the effluent of the steam cracking unit and the effluent from the catalytic cracking unit are recycled to the catalytic cracking unit.