Abstract: Provided are battery modules having two different types electrochemistry connected in series, which includes a plurality of a first cell, wherein the first cell includes an anode active material of graphite, Si, SiOx, or a blend thereof as a main component (“a GSi cell”), and at least one of a second cell, wherein the second cell includes an anode active material of a lithium titanate oxide or titanate oxide able to be lithiated as a main component (“a LTO cell”). Also provided are battery systems that include a plurality of the battery modules.
Type:
Application
Filed:
October 30, 2019
Publication date:
May 6, 2021
Applicant:
SAFT AMERICA
Inventors:
Saori TOKUOKA, Thomas GRESZLER, James G. SNYDER
Abstract: Provided is a positive electrode active material for a lithium-ion battery, the positive electrode active material including a blend of a doped lithium manganese iron phosphate (dLMFP) according to the formula: LiMnxFeyM1?x?yPO4, wherein 0.9<x+y<1; and M is one or more selected from the group consisting of Mg, Ca and Ba with one or both of a lithium nickel cobalt manganese oxide (NMC) compound having a Ni content greater than 0.6 relative to a total amount of metals other than Li and a lithium nickel cobalt aluminum oxide (NCA) compound. In particular, provided is a blend at a weight ratio of dLMFP to NMC and/or NCA (i.e., dLMFP:(NMC+NCA)) of >70:<30, such as 75:25, 80:20, 85:15, 90:10, etc.
Type:
Application
Filed:
September 12, 2019
Publication date:
March 18, 2021
Applicant:
SAFT AMERICA
Inventors:
Xilin CHEN, Saori TOKUOKA, Frank CAO, Jian DONG, Carine MARGEZ, Owen OU, Thomas GRESZLER
Abstract: The invention relates to an assembly of a plurality of electrochemical elements (1), in which the electrochemical elements comprise a container (5) having a side wall, said assembly being characterized in that at least one portion of the side wall of at least one of the containers is in contact with a partition obtained by means of an additive manufacturing method, and is produced by superposing at least two strips (4) of a structural material.
Abstract: A battery made up of nickel-cadmium cells includes an indicator for displaying a state of charge comprising sensors for performing continuous measurements of voltage and current and of temperature of the battery, a memory storing at least a history of charge/discharge, a predefined reference voltage, current and temperature, and the measurements and history determined, and a control unit for determining an operation mode of the battery and determining a correction to be applied to the voltage and current measured, calculating a theoretically available capacity of the battery depending on the operating mode and the correction, determining a need for recalibration of the theoretically available capacity of the battery enabling a capacity actually available of the battery to be calculated, and based on the capacity actually available, defining the state of charge of the battery.
Abstract: A composition of active material for a positive electrode of a lithium-ion electrochemical cell is provided comprising: (a) a lithiated oxide of formula Li1+xMO2 in which: 0?x?0.15, M designates NiaMnbCocM?d where a>0; b>0; c>0; d?0 and a+b+c+d=1; M? being chosen from B, Mg, Al, Si, Ca, Ti, V, Cr, Fe, Cu, Zn, Y, Zr, Nb, Mo or a mixture of these; (b) a lithiated phosphate of formula LiMn1?yM?yPO4 where M? represents at least one element chosen from the group consisting of Fe, Ni, Co, Mg and Zn; and 0<y<0.5; the particle size distribution of the lithiated oxide being characterized by a first volume median diameter of the particles Dv501?500 nm; the particle size distribution of the lithiated phosphate being characterized by a second volume median diameter of the particles Dv502?500 nm; and Dv502/Dv501?1.5.
Abstract: The invention resolves the problem of swelling of sealing electrochemical cells of prismatic format when they are assembled side by side in a grouping box by proposing a battery comprising at least two electrochemical cells (1a, 1b) of prismatic format, wherein the electrochemical cells are separated by a rigid wedge (2) having a hardness greater than or equal to 90 Shore A according to the standard ASTM D 2240 and by a flexible wedge (3) having a hardness of up to 60 Shore A according to the standard ASTM D 2240, the rigid wedge and the flexible wedge being electrically insulating.
Type:
Grant
Filed:
February 17, 2017
Date of Patent:
November 17, 2020
Assignee:
SAFT
Inventors:
Alexandre Narbonne, Jérôme Calmejane, Marc Chesnais
Abstract: An electrolyte composition for a lithium-ion electrochemical cell, comprising: at least one tetrafluorinated or hexafluorinated lithium salt, lithium bis(fluorosulfonyl)imide LiFSI salt, vinylene carbonate, ethylene sulfate, lithium difluorophosphate, at least one organic solvent selected from the group consisting of cyclic or carbonates, cyclic or linear esters, cyclic or linear ethers and a mixture thereof, the ratio of the mass of ethylene sulfate to the mass of vinylene carbonate before addition to the solvent being strictly less than 1, the mass percentage of lithium bis(fluorosulfonyl)imidide representing less than 1% of the mass of the group consisting of said at least one tetrafluorinated or hexafluorinated lithium salt, the lithium bis(fluorosulfonyl)imidide salt and said at least one organic solvent. The use of this composition in a lithium-ion electrochemical cell increases the life of the cell, especially under low- and high-temperature cycling conditions.
Abstract: A metal foil including on at least one of its sides a layer of a material including: a metal or a metal alloy, carbon, hydrogen, and optionally oxygen, the atomic percentage of the metal or of the metals of the alloy in the material ranging from 10 to 60%, the atomic percentage of carbon in the material ranging from 35 to 70%, the atomic percentage of hydrogen in the material ranging from 2 to 20%, and the atomic percentage of oxygen if present in the material being less than or equal to 10%. The metal foil can be used in the manufacture of a cathode of a lithium-ion electrochemical cell. The deposition of this layer reduces the internal resistance of the cell.
Type:
Application
Filed:
February 20, 2020
Publication date:
August 27, 2020
Applicants:
SAFT, H.E.F.
Inventors:
Celine LAVAUD, Cecile TESSIER, Laurent DUBOST, Michel Joseph Pierre Marie MARTIN
Abstract: A lithium-ion electrochemical cell comprising: at least one negative electrode comprising an active material having an operating potential greater than or equal to 1 V with respect to the potential of the electrochemical couple Li+/Li; at least one positive electrode; the negative electrode and/or the positive electrode comprising a binder selected from polytetrafluoroethylene, polyamideimide, polyimide, styrene-butadiene rubber and polyvinyl alcohol or a mixture thereof; a liquid electrolyte comprising a solvent which is an ionic liquid; a separator having a shrinkage of less than or equal to 3% in the direction of its length and in the direction of its width, after exposure to a temperature of 200° C. for a period of at least one hour. This electrochemical cell can be used in charge or discharge at a temperature ranging from room temperature to 150° C. or higher.
Type:
Application
Filed:
October 1, 2018
Publication date:
August 20, 2020
Applicant:
SAFT
Inventors:
Erwan DUMONT, Frédéric CASTAING, Benjamin LE GUERN, Fabrice RENE, Michel ULLDEMOLINS, Cécile TESSIER, Jean-Paul PERES, Florent FISCHER
Abstract: The invention relates to an electrochemical element and a battery comprising one or more electrochemical elements, with integrated sensors and/or actuators, in particular including an application for monitoring the operation of an electrochemical element or a Li-ion battery, and/or triggering actions in such an element or such a battery, intended to secure the element or the battery. The electrochemical element (1) comprises a closed shell (2) defining an internal volume and a beam (3) arranged therein having alternating positive and negative electrodes respectively connected to two positive and negative electrical output terminals housing separators, the beam (3) being impregnated with electrolyte and further connected by connection means (4) to one (5) of the electrical output terminals.
Type:
Application
Filed:
August 22, 2018
Publication date:
August 13, 2020
Applicant:
SAFT
Inventors:
Patrick BERNARD, Philippe BOREL, Laure LE-GUENNE, Gerard RIGOBERT
Abstract: Provided are an electrolyte for low temperature operation of lithium titanate electrodes, graphite electrodes, and lithium-ion batteries as well as electrodes and batteries employing the same. The electrolyte contains 1 to 30 vol % of a low molecular weight ester having a molecular weight of less than 105 g/mol and at least one non-fluorinated carbonate. An electrolyte additive may include 0.1 to 10 wt % of fluorinated ethylene carbonate, particularly when used with a graphite anode. Another electrolyte contains a high content of the low molecular weight ester of at least 70 vol %.
Type:
Application
Filed:
February 7, 2019
Publication date:
August 13, 2020
Applicant:
SAFT AMERICA
Inventors:
Joong Sun PARK, Saori TOKUOKA, Carine MARGEZ, Thomas GRESZLER
Abstract: The invention relates to a compound of the formula Li7?xPS6?xXx?x(BH4)x in which x is selected from the group comprising Cl, Br, I, F and CN, 0?x?2, 0?z?0.50. This compound can be used as a solid electrolyte of a lithium-ion electrochemical element.
Type:
Application
Filed:
September 20, 2018
Publication date:
July 16, 2020
Applicants:
SAFT, UNIVERSITE PARIS-EST CRETEIL VAL DE MARNE UPEC, Centre National de la Recherche Scientifique (CNRS)
Inventors:
Christian JORDY, Pedro LOPEZ-ARANGUREN, Ha Anh DAO, Michel LATROCHE, Junxian ZHANG, Fermin CUEVAS
Abstract: A method may include activating two or more bypassable battery modules in succession through a current-limiting circuit to precharge an application bus from a power source.
Abstract: The invention concerns a multi-battery assembly, and a container comprising such an assembly, for use in particular in the field of high energy-density assemblies comprising a plurality of Ni—Cd, Ni-MH, lead-acid or Li-ion stationary batteries stored in a container or a library-like room. The multi-battery assembly comprises at least three rows (1 to 4) of batteries (12 to 23) connected in series and/or parallel, including two end rows (1, 4) and at least two intermediate rows (2, 3), each row being connected in series and/or parallel to at least one adjacent row, extending in a first direction (d1), and comprising at least one level (36 to 38) of a plurality of batteries connected in series and/or parallel, each of the levels extending in the first direction (d1).
Abstract: A sacrificial positive active material for a lithium-ion electrochemical element which is a compound of formula (Li2O)x (MnO2)y(MnO)z(MOa)t in which: x+y+z+t=1; 1?x?y?0; 0.97?x?0.6; y?0.45; x ?0.17; y?0; y+z>0; t?0; 1?a<3. M is selected from the group consisting of Fe, Co, Ni, B, Al, Ti, Si, V, Mo, Zr and a mixture thereof.
Type:
Application
Filed:
May 22, 2018
Publication date:
April 30, 2020
Applicants:
SAFT, ENSICAEN, UNICAEN, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)
Inventors:
Christian JORDY, Melanie FREIRE, Valerie PRALONG
Abstract: A Lithium-Ion monoblock battery assembly including a housing having a cavity for receiving an electrode assembly. Also including a cover sealingly attached to the housing, and a bussing integrally molded with at least one of the housing and the cover.
Type:
Grant
Filed:
September 6, 2018
Date of Patent:
April 7, 2020
Assignee:
SAFT GROUPE SA
Inventors:
Michael C. Duffield, Daniel E. Kelley, Gerard Rigobert, Alexandre Beugnon
Abstract: Leaktight box for alkaline electrolyte battery, comprising an assembly of metal plates, where: a first and a second plate overlap in a zone of overlap and are assembled with rivets each comprising a head, a stem and a bulb; the stem of the rivets is deformed in such a way as to occupy in a leaktight manner substantially all of the volume of said holes of the first and second plates; preferably an elastomer seal comprising a material chosen from among a butyl rubber, an ethylene-propylene-diene terpolymer and a nitrile rubber, where said seal is disposed in continuity with the overlap zone in continuous contact with the first and the second plate in such a way as to complete the leaktightness of the box.
Abstract: The invention relates to a self-supported activation device for an electromechanical switch, which can be used for the isolation of a faulty element of a battery, comprising a set of electrically connected elements. The activation device (1) is intended to activate switching in a switching device (2) of the type having electrical contact means (3) that can move between first and second electrical positions. The activation device comprises a current sensor (6a, 6b), a retaining element (7), and at least two movable elements (8, 9) solidly connected to a coil (10).
Abstract: An electromechanical element (1) comprising: a recipient (2) including an aperture allowing at least one set of plates (4) to be inserted; and a cover (3) intended to be assembled on the aperture of the recipient, comprising: i) a first wall (17) including at least one aperture for the passage of a current output terminal (6), this first wall making an angle ranging front 80 to 10° to the horizontal, ii) a second wall (19) making an angle ranging from 5° to 85° to the horizontal, the zone of contact between the recipient and the cover defining a plane of closure (16) of the element, which plane of closure makes an angle ranging from 5° to 85° to the horizontal. The design of the recipient and of the cover allows a plurality of electrochemical elements to be stacked to form a battery (10).
Abstract: A safety device (19) for a battery (12) being designed so that an electrical connector (18) can be connected to the positive (14) and negative (16) electrical terminals of the battery (12) in a first (A+, A?) or a second (B+, B?) connection position, the safety device (19) being adapted to be selectively positioned in a first or a second safety position so that only the desired connection positions are accessible to an electrical connector (18). A battery including the safety device or a set of such batteries and a method for making such a set of batteries safe.
Type:
Grant
Filed:
July 6, 2016
Date of Patent:
August 27, 2019
Assignee:
SAFT
Inventors:
Alexandre Narbonne, Christophe Dos Reis