Patents Assigned to Saint-Gobain Centre de Recherches et d'Etudes Europeen
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Patent number: 12146738Abstract: A device that includes a piece of armor made from a material that has a domain of plastic deformation under bad before breaking and an elastic deformation domain. The plastic deformation domain represents less than 1% of the elastic deformation domain. The device includes a deformation sensor fixed to the piece of armor and configured to deform plastically under the effect of at least a stress applied to the piece of armor and leading to damage of the piece of armor.Type: GrantFiled: December 10, 2020Date of Patent: November 19, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Vincent Gleize, Alexane Margossian, Matthieu Graveleau, Mickael Boinet
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Patent number: 12050088Abstract: A screening element in the form of a sintered monolithic body has an outer face and an opposing inner face with an area of the faces greater than 100 cm2 and the mean thickness Em between the faces greater than 4 mm. At least a portion of the outer face is textured such that Ai decreases from the inner face from a value of i greater than at least 50, A75?0.2×A0 and A95<0.9×A0, 0.03×A0<A95<0.5×A0 and A100<0.1×A0. Ai being the area occupied by the material alone along a plane i of internal section at the intermediate thickness Ei and i corresponding in percentage to the fraction of the mean thickness Em at plane i.Type: GrantFiled: July 2, 2021Date of Patent: July 30, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Jérôme Brulin, Matthieu Graveleau, Alexane Margossian
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Patent number: 12043582Abstract: A process for marking a surface of a refractory ceramic part, known as the “surface to be marked.” The part has a microstructure of grains including more than 50% by mass of ZrO2, bound by a silicate binder phase, and a total porosity of less than 5% by volume. The process involves irradiation of the surface with a laser beam. The beam is emitted by a laser device set to comply with relationship: a.V2+b.F2+c.VF+d.V+e. F+f<0, in which: a=104. D+2×106, b=0.5×106. D?150×106, c=0.5×106. D?300×106, d=5×103. D?2.5×106, e=?5×103. D+2.0×106, and f=?5×109. D+1.8×1012. V is expressed in mm/second, D is expressed in mm and F is expressed in kHz.Type: GrantFiled: July 26, 2019Date of Patent: July 23, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventor: Olivier Bories
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Patent number: 12037295Abstract: A sintered ceramic foam that has a total porosity of greater than 60% by volume and the following phase composition, in mass percent based on the crystallized phases: 25 to 55% mullite, 20 to 65% corundum, 10 to 40% zirconia, mullite, corundum and zirconia together representing more than 80% of the mass of the crystallized phases. Also, a furnace that has a thermal insulator such ceramic foam.Type: GrantFiled: September 18, 2018Date of Patent: July 16, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Laurie San-Miguel, Yannick Millot
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Patent number: 11964900Abstract: Fused tuckstone defining lower and upper surfaces. The lower surface includes a support surface to rest on metallic structure of a glass furnace, a tank surface intended to face an upper edge of a tank of the furnace, and a lower transition surface connecting the support and tank surfaces. The upper surface includes a superstructure surface to receive a side wall of a superstructure of the furnace and an upper transition surface connecting the superstructure and lower surfaces. At least a part of the lower transition surface has a crystal density of more than four times the crystal density at a depth of 4 centimeters below the lower transition surface, a crystal density being evaluated by the number of crystals having a surface area of more than 12 ?m2 per mm2 of surface after polishing, the crystal density at the depth being evaluated after cutting of the tuckstone.Type: GrantFiled: December 19, 2018Date of Patent: April 23, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Isabelle Cabodi, Pierrick Vespa
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Patent number: 11951592Abstract: Shot-peening powder that has ceramic particles. The powder having more than 95% by mass of beads. The beads having a median size D50 greater than 50 ?m and less than 1200 ?m, and having a value (D90?D10)/D50, or “S”, such that S??0.126·ln(D50)+0.980.Type: GrantFiled: May 28, 2019Date of Patent: April 9, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Julien Cabrero, Anne-Laure Beaudonnet, Yves Léon Marcel Boussant-Roux, Benjamin Gilbert Robert Levy
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Patent number: 11932568Abstract: An insulated tuckstone that includes a basic tuckstone and an insulating layer exhibiting a thermal conductivity lower than 2.0 W·m 1·K?1 between 20° C. and 500° C., exhibiting enough rigidity to be self-supporting and covering an insulated surface of the basic tuckstone. The insulated surface is included in the lower surface of the basic tuckstone, extending into the lower transition surface and representing more than 20% of the lower transition surface. The insulating layer has a chemical composition, as a percentage by mass on the basis of the oxides, such that Al2O3+SiO2+ZrO2+CaO+Na2O+MgO+K2O+TiO2+Fe2O3+HfO2+P2O5+Y2O3>80%.Type: GrantFiled: April 10, 2019Date of Patent: March 19, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Isabelle Cabodi, Pierrick Vespa, Franceline Marguerite Louise Villermaux, Christian His
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Patent number: 11912626Abstract: A polycrystalline fused product based on brownmillerite, includes, for more than 95% of its weight, of the elements Ca, Sr, Fe, O, M and M?, the contents of the elements being defined by the formula XyMzFetM?uO2.5, wherein the atomic indices are such that 0.76?y?1.10, z?0.21, 0.48?t?1.15 and u?0.52, 0.95?y+z?1.10, and 0.95?t+u?1.10, X being Ca or Sr or a mixture of Ca and Sr, M being an element chosen from the group formed by La, Ba and mixtures thereof, M? being an element chosen from the group formed by Ti, Cu, Gd, Mn, Al, Sc, Ga, Mg, Ni, Zn, Pr, In, Co, and mixtures thereof, the sum of the atomic indices of Ti and Cu being less than or equal to 0.1.Type: GrantFiled: September 19, 2019Date of Patent: February 27, 2024Assignees: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Helena Kaper, Pierre-Alexis Repecaud
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Patent number: 11905198Abstract: A glass furnace including an additive-containing product including an additive selected from: phosphorus compounds other than glasses and vitroceramics, tungsten compounds other than glasses and vitroceramics, molybdenum compounds other than glasses and vitroceramics, iron in the form of metal, aluminum in the form of metal, silicon in the form of metal, and their mixtures, silicon carbide, boron carbide, silicon nitride, boron nitride, glasses including elemental phosphorus and/or iron and/or tungsten and/or molybdenum, vitroceramics including elemental phosphorus and/or iron and/or tungsten and/or molybdenum, and their mixtures, and having the following chemical analysis, exclusively of the additive, as a percentage by weight on the basis of the oxides: Cr2O3?2%, and Cr2O3+Al2O3+CaO+ZrO2+MgO+Fe2O3+SiO2+TiO2?90%, and Cr2O3+Al2O3+MgO?60%, the content by weight of additive being in the range 0.01% to 6%.Type: GrantFiled: December 20, 2018Date of Patent: February 20, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Thibault Champion, Pierrick Vespa, Lionel Moitrier, Olivier Citti, Julien Pierre César Fourcade, Nabil Nahas
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Patent number: 11878933Abstract: A process for treating a fused refractory product including more than 10% by mass of ZrO2, or “base product.” The process includes heating at least a portion of the surface of the product, so as to melt ZrO2 crystals in a superficial region extending to a depth of less than 2000 ?m. The process includes cooling the molten superficial region obtained in the preceding step so as to obtain a protective layer.Type: GrantFiled: July 26, 2019Date of Patent: January 23, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Isabelle Cabodi, Frédéric Hoffmann, Pierrick Fabien Vespa
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Patent number: 11873257Abstract: An antiballistic armor-plating component, includes a ceramic body made of a material including, as percentages by volume, between 20% and 75% of boron carbide, between 5% an d 30% of a metallic silicon phase or of a metallic phase including silicon and between 20% and 70% of silicon carbide and wherein, as percentages by volume: more than 60% of the grains with an equivalent diameter greater than 60 micrometers are boron carbide grains, the boron carbide grains with an equivalent diameter greater than 30 micrometers represent more than 20%, the silicon carbide grains with an equivalent diameter greater than or equal to 10 micrometers represent more than 10%, the silicon carbide grains with an equivalent diameter less than 10 micrometers represent more than 10%.Type: GrantFiled: July 31, 2020Date of Patent: January 16, 2024Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Jérôme Brulin, Jérôme Sant
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Patent number: 11731883Abstract: A powder of melted particles, more than 95% by number of the particles exhibiting a circularity of greater than or equal to 0.85. The powder including more than 99.8% of a rare earth metal oxide and/or of hafnium oxide and/or of an aluminum oxide, as percentage by mass based on the oxides. The powder has a median particle size D50 of less than 15 ?m, a 90 percentile of the particle sizes, D90, of less than 30 ?m, and a size dispersion index (D90?D10)/D10 of less than 2, and a relative density of greater than 90%. The Dn percentiles of the powder are the particle sizes corresponding to the percentages, by number, of n %, on the cumulative distribution curve of the size of the particles in the powder and the particle sizes are classified by increasing order.Type: GrantFiled: January 31, 2019Date of Patent: August 22, 2023Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Alain Allimant, Howard Wallar
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Patent number: 11712818Abstract: A method for producing a glass furnace, including a refractory portion, a waveguide with a measurement portion extending into the refractory portion and an interrogator connected to an input of the waveguide to inject an interrogation signal. The measurement portion incorporating a sensor to send a response signal to the interrogator in response to the injection. The interrogator analyzing the response signal and sending a message. Arranging, inside a mold, a temporary part configured to leave space for a compartment for the measurement portion. Preparing a starting feedstock and introducing the starting feedstock into the mold such that the part is embedded therein to obtain a preform. Hardening the preform to form the refractory portion. Removing the temporary part to make the compartment. Assembling the refractory portion with other constituent elements and introducing the measurement portion into the compartment and connecting the interrogator to the input of the waveguide.Type: GrantFiled: July 26, 2019Date of Patent: August 1, 2023Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Isabelle Cabodi, Olivier Citti, Jean-Gaël Vuillermet
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Patent number: 11635281Abstract: Antiballistic armour plate includes a ceramic body including a hard material, provided, on its inner face, with a back energy-dissipating coating. The ceramic body is monolithic. The constituent material of the ceramic body includes grains of ceramic material having a Vickers hardness that is higher than 15 GPa, and a matrix binding the grains, the matrix including a silicon nitride phase and/or a silicon oxynitride phase, the matrix representing between 5 and 40% by weight of the constituent material of the ceramic body. The maximum equivalent diameter of the grains of ceramic material is smaller than or equal to 800 micrometres. The constituent material of the ceramic body has an open porosity that is higher than 5% and lower than 14%. The metallic silicon content in the material, expressed per mm of thickness of the body, is lower than 0.5% by weight.Type: GrantFiled: July 7, 2017Date of Patent: April 25, 2023Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Malte Moeller, Gilles Rossiquet
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Patent number: 11634362Abstract: A process for the manufacture of a refractory block including more than 80% zirconia, in percentage by weight based on the oxides. The process includes the following successive stages: melting, under reducing conditions, of a charge including more than 50% zircon, in percentage by weight, such as to reduce the zircon and obtain a molten material, application of oxidizing conditions to the molten material, casting of the molten material, and cooling until at least partial solidification of the molten material in the form of a block. Also, the process can include heat treatment of the block.Type: GrantFiled: October 9, 2018Date of Patent: April 25, 2023Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Isabelle Cabodi, Pierrick Vespa, Laurent Battu, Olivier Citti
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Patent number: 11628404Abstract: A monolithic membrane-type filtration structure for filtering liquids, includes a support formed of a porous inorganic material of permeability Ks, the support having a tubular overall shape with a main axis, an upstream base, a downstream base, a peripheral wall delimiting an internal part and a plurality of passages parallel to the main axis of the support, formed in the internal part of the support, a membrane of permeability Km and of mean thickness tm covering the internal surface of the passages; the external hydraulic diameter of the structure satisfying the relationship Øf=?×[A+B×log10 (Ks×tm/Km)]; in which ? is a coefficient between 0.85 and 1.15, and A=?21570×entint2?18.6×Dh+19.0×eint?2.5×eext+0.1244 B=?11760×Dh×eint+9.7×eint+3.1×eext+0.04517. Dh is the mean hydraulic diameter of the passages, eint is the minimum thickness of the internal walls between the passages, eext is the minimum thickness of the peripheral wall of the filter.Type: GrantFiled: November 29, 2018Date of Patent: April 18, 2023Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Sébastien Pinson, Paul Leplay, Malte Moeller, Ronald Neufert, Michael Faber
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Patent number: 11578005Abstract: Sintered product having a relative density of greater than 90%, with, to more than 80% of the volume thereof, a stack of flat ceramic platelets, the assembly of the platelets having a mean thickness of less than 3 ?m, having a width of greater than 50 mm, and including more than 20% of alumina, as a percentage on the basis of the weight of the product. The width of the product is the largest dimension measured in the plane in which the length of the product is measured, along a direction perpendicular to the direction of the length. The length of the product is the largest dimension thereof in a plane parallel to the general plane in which the platelets extend.Type: GrantFiled: January 30, 2018Date of Patent: February 14, 2023Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Nassira Benameur, Christian His, Jérôme Leloup
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Patent number: 11472743Abstract: A sintered bead with the following crystal phases, in percentages by mass based on crystal phases: 25%?zircon, or “Z1”, ?94%; 4%?stabilized zirconia+stabilized hafnia, or “Z2”, ?61%; monoclinic zirconia+monoclinic hafnia, or “Z3”?50%; corundum?57%; crystal phases other than Z1, Z2, Z3 and corundum<10%; the following chemical composition, in percentages by mass based on oxides: 33%?ZrO2+HfO2, or “Z4”?83.4%; HfO2?2%; 10.6%?SiO2?34.7%; Al2O3?50%; 0%?Y2O3, or “Z5”; 0%?CeO2, or “Z6”; 0.3%?CeO2+Y2O3?19%, provided that (1) CeO2+3.76*Y2O3?0.128*Z, and (2) CeO2+1.3*Y2O3?0.318*Z, with Z=Z4+Z5+Z6?(0.67*Z1*(Z4+Z5+Z6)/(0.67*Z1+Z2+Z3)); MgO?5%; CaO?2%; oxides other than ZrO2, HfO2, SiO2, Al2O3, MgO, CaO, CeO2 and Y2O3<5.0%.Type: GrantFiled: July 18, 2018Date of Patent: October 18, 2022Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventor: Emmanuel Nonnet
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Patent number: 11390532Abstract: A powder formed of fused particles. More than 95% by number of the feed particles exhibiting a circularity of greater than or equal to 0.85. The powder contains more than 88% of a silicate of one or more elements chosen from Zr, Hf, Y, Ce, Sc, In, La, Gd, Nd, Sm, Dy, Er, Yb, Eu, Pr, Ho and Ta, less than 10% of a dopant, as percentage by weight based on the oxides. The powder has a median particle size D50 of less than 15 ?m, a 90 percentile particle size, D90, of less than 30 ?m, and a size dispersion index (D90-D10)/D10 of less than 2. The powder has a relative density of greater than 90%. The Dn percentiles of the powder are the particle sizes corresponding to the percentages, by number, of n %, on the cumulative distribution curve of the size of the particles of the powder. The particle sizes are classified in increasing order.Type: GrantFiled: January 31, 2019Date of Patent: July 19, 2022Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Alain Allimant, Howard Wallar
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Patent number: 11390786Abstract: A sintered material exhibiting the following chemical composition, as percentages by weight: iron oxide(s), expressed in the Fe2O3 form, ?85%, CaO: 0.1%-6%, SiO2: 0.1%-6%, 0.05% ?TiO2, 0?Al2O3, TiO2+Al2O3?3%, and constituents other than iron oxides, CaO, SiO2, TiO2 and Al2O3: ?5%. The CaO/SiO2 ratio by weight is between 0.2 and 7. The TiO2/CaO ratio by weight is between 0.2 and 1.5.Type: GrantFiled: April 19, 2017Date of Patent: July 19, 2022Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: Christian His, Franceline Villermaux