Patents Assigned to SAN NOPCO LTD.
  • Patent number: 10252189
    Abstract: An object of the present invention is to provide an oil-in-water emulsion defoaming agent that is superior in defoaming properties (initial defoaming property and defoaming durability) and stability (emulsion stability). The present invention provides an oil-in-water emulsion defoaming agent including hydrophilic fumed silica (C), wherein an oil phase (A) is emulsified and dispersed in a water phase (B). Preferably, the content of the oil phase (A) is 10 to 50% by weight, the content of the hydrophilic fumed silica (C) is 0.1 to 6% by weight, and the content of the water phase (B) is 44 to 89.9% by weight based on the weight of the oil phase (A), the hydrophilic fumed silica (C), and the water phase (B). The weight ratio (A/C) of the oil phase (A) to the hydrophilic fumed silica (C) is preferably from 2 to 100.
    Type: Grant
    Filed: September 11, 2012
    Date of Patent: April 9, 2019
    Assignee: SAN NOPCO LTD.
    Inventors: Yohei Matsumura, Nobuo Hisada, Yoshihide Izumi
  • Patent number: 10125378
    Abstract: There is provided an additive for a bioethanol fermentation process comprising a polyoxyalkylene compound (A) having a Griffin's HLB value in the range of 0 to 6, a polyoxyalkylene polyol (B) and a base oil (C) that is liquid at 25° C. The compound (A) is preferably a mixture of a compound represented by a general formula (1) and a compound represented by a general formula (2). In the formula, R1 and R3 represent alkyl or alkenyl, R2 and R4 represent a hydrogen atom or a monovalent organic group, AO represents oxyalkylene having a carbon number of 3 to 18, a reaction residue of glycidol, a reaction residue of an alkyl glycidyl ether or a reaction residue of an alkenyl glycidyl ether, EO represents oxyethylene, m and n are 1 to 100, and p is 3 to 10.
    Type: Grant
    Filed: January 8, 2016
    Date of Patent: November 13, 2018
    Assignee: SAN NOPCO LTD.
    Inventors: Hironori Nagamatsu, Tsuyoshi Ando
  • Patent number: 10087468
    Abstract: An object of the present invention is to provide an additive that can improve the production efficiency. The present invention is an additive for a bioethanol fermentation process comprising a polyoxyalkylene compound (A) having a Griffin's HLB value in the range of 0 to 6 and a polyoxyalkylene polyol (B). The compound (A) is preferably a mixture of a compound represented by a general formula (1) and a compound represented by a general formula (2). R1O-(AO)m-R2 (1). R3O-(AO)n-(EO)p-R4 (2). R1 and R3 represent alkyl or alkenyl, R2 and R4 represent a hydrogen atom or a monovalent organic group, AO represents oxyalkylene having a carbon number of 3 to 18, or a reaction residue of glycidol, an alkyl glycidyl ether or alkenyl glycidyl ether, EO represents oxyethylene, m and n are 1 to 100, and p is 3 to 10.
    Type: Grant
    Filed: February 19, 2014
    Date of Patent: October 2, 2018
    Assignee: SAN NOPCO LTD.
    Inventors: Hironori Nagamatsu, Tsutomu Miyata
  • Publication number: 20170349916
    Abstract: There is provided an additive for a bioethanol fermentation process comprising a polyoxyalkylene compound (A) having a Griffin's HLB value in the range of 0 to 6, a polyoxyalkylene polyol (B) and a base oil (C) that is liquid at 25° C. The compound (A) is preferably a mixture of a compound represented by a general formula (1) and a compound represented by a general formula (2). In the formula, R1 and R3 represent alkyl or alkenyl, R2 and R4 represent a hydrogen atom or a monovalent organic group, AO represents oxyalkylene having a carbon number of 3 to 18, a reaction residue of glycidol, a reaction residue of an alkyl glycidyl ether or a reaction residue of an alkenyl glycidyl ether, EO represents oxyethylene, m and n are 1 to 100, and p is 3 to 10.
    Type: Application
    Filed: January 8, 2016
    Publication date: December 7, 2017
    Applicant: SAN NOPCO LTD.
    Inventors: Hironori Nagamatsu, Tsuyoshi Ando
  • Publication number: 20170312657
    Abstract: There is provided a defoaming agent having excellent defoaming persistence. The defoaming agent includes; hydrophobic silica having a hydrophobicity (MX) of 50 to 85, and a rate of change (MY/MX) of a hydrophobicity (MY) after immersion for 1 hour in a methanol/ion-exchange aqueous solution (volume ratio of 80/20) of sodium hydroxide with a pH of 13 at 25° C. to the hydrophobicity (MX) of 0.8 to 1.0; and at least one kind of liquid selected from the group consisting of a hydrocarbon oil, a non-reactive silicone oil and a polyoxyalkylene compound.
    Type: Application
    Filed: November 19, 2015
    Publication date: November 2, 2017
    Applicants: SAN NOPCO LTD., KYOTO UNIVERSITY
    Inventors: Katsuomi Shimabayashi, Hidetaka Hario, Toyoshi Shimada, Kazuki Nakanishi
  • Publication number: 20160326003
    Abstract: There is provided hydrophobic silica that will cause no deterioration in the gloss of resin or of a coating film even when having been applied as a wear resistance-improver or a mechanical strength enhancer for resin or as a fluidizing agent for powder paint or the like and that will cause no deterioration in the gloss of a resulting coating film even when having been applied to a defoaming agent. There is provided hydrophobic particulate wet process silica resulting from subjecting hydrophilic wet process silica to hydrophobization treatment and milling treatment. The number-average particle diameter (Dn) is 0.1 to 1 ?m and the M value is 50 to 80. The milling treatment is preferably wet milling treatment. The hydrophobization treatment is preferably wet hydrophobization treatment. The ratio of the volume-average particle diameter (Dv) to the number-average particle diameter (Dn) (Dv/Dn) is preferably 1 to 4.
    Type: Application
    Filed: January 15, 2015
    Publication date: November 10, 2016
    Applicant: SAN NOPCO LTD.
    Inventor: Motoyoshi ISHIZUKA
  • Patent number: 9345991
    Abstract: The present invention provides a defoaming agent containing, as essential components, hydrophobic dry silica (S) prepared by hydrophobizing silica prepared using a dry process and having a primary particle diameter of 5 to 100 nm, water, and a hydrophobic liquid (Q) containing 1 to 25% by weight of an ester compound (E) represented by the following formula, (R1—COO)p-D, wherein R1 denotes an alkyl group or an alkenyl group; D denotes a residue resulting from the removal of a hydroxyl group contributing to an ester linkage from a compound (D?) containing 2 to 6 carbon atoms and 1 to 6 hydroxyl groups or a residue resulting from the removal of a hydroxyl group contributing to an ester linkage from an adduct prepared by adding an alkylene oxide to the compound (D?); and p denotes an integer from 1 to 3.
    Type: Grant
    Filed: June 3, 2011
    Date of Patent: May 24, 2016
    Assignee: SAN NOPCO LTD.
    Inventor: Tsuyoshi Ando
  • Publication number: 20160090609
    Abstract: An object of the present invention is to provide an additive that can improve the production efficiency. The present invention is an additive for a bioethanol fermentation process comprising a polyoxyalkylene compound (A) having a Griffin's HLB value in the range of 0 to 6 and a polyoxyalkylene polyol (B). The compound (A) is preferably a mixture of a compound represented by a general formula (1) and a compound represented by a general formula (2). R1O-(AO)m-R2 (1). R3O-(AO)n-(EO)p-R4 (2). R1 and R3 represent alkyl or alkenyl, R2 and R4 represent a hydrogen atom or a monovalent organic group, AO represents oxyalkylene having a carbon number of 3 to 18, or a reaction residue of glycidol, an alkyl glycidyl ether or alkenyl glycidyl ether, EO represents oxyethylene, m and n are 1 to 100, and p is 3 to 10.
    Type: Application
    Filed: February 19, 2014
    Publication date: March 31, 2016
    Applicant: SAN NOPCO LTD.
    Inventors: Hironori Nagamatsu, Tsutomu Miyata
  • Patent number: 9018265
    Abstract: The present invention is a defoaming agent comprising a fatty acid amide (A), a base oil (B) that is liquid at 25° C., an oil thickening agent (C), and a surfactant (D), wherein the content of the fatty acid amide (A) is 1 to 10% by weight, the content of the base oil (B) that is liquid at 25° C. is 71 to 97.9% by weight, the content of the oil thickening agent (C) is 0.1 to 10% by weight, and the content of the surfactant (D) is 1 to 9% by weight based on the weight of the fatty acid amide (A), the base oil (B) that is liquid at 25° C., the oil thickening agent (C), and the surfactant (D), and the viscosity (25° C.) at a shear rate of 1000 s?1 is 0.1 to 1.0 Pa·s.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: April 28, 2015
    Assignee: San Nopco Ltd.
    Inventors: Yohei Matsumura, Nobuo Hisada, Yoshihide Izumi
  • Publication number: 20140221508
    Abstract: An object of the present invention is to provide an oil-in-water emulsion defoaming agent that is superior in defoaming properties (initial defoaming property and defoaming durability) and stability (emulsion stability). The present invention provides an oil-in-water emulsion defoaming agent including hydrophilic fumed silica (C), wherein an oil phase (A) is emulsified and dispersed in a water phase (B). Preferably, the content of the oil phase (A) is 10 to 50% by weight, the content of the hydrophilic fumed silica (C) is 0.1 to 6% by weight, and the content of the water phase (B) is 44 to 89.9% by weight based on the weight of the oil phase (A), the hydrophilic fumed silica (C), and the water phase (B). The weight ratio (A/C) of the oil phase (A) to the hydrophilic fumed silica (C) is preferably from 2 to 100.
    Type: Application
    Filed: September 11, 2012
    Publication date: August 7, 2014
    Applicant: SAN NOPCO LTD.
    Inventors: Yohei Matsumura, Nobuo Hisada, Yoshihide Izumi
  • Publication number: 20140100293
    Abstract: The present invention provides a defoaming agent containing, as essential components, hydrophobic dry silica (S) prepared by hydrophobizing silica prepared using a dry process and having a primary particle diameter of 5 to 100 nm, water, and a hydrophobic liquid (Q) containing 1 to 25% by weight of an ester compound (E) represented by the following formula, (R1—COO)p-D, wherein R1 denotes an alkyl group or an alkenyl group; D denotes a residue resulting from the removal of a hydroxyl group contributing to an ester linkage from a compound (D?) containing 2 to 6 carbon atoms and 1 to 6 hydroxyl groups or a residue resulting from the removal of a hydroxyl group contributing to an ester linkage from an adduct prepared by adding an alkylene oxide to the compound (D?); and p denotes an integer from 1 to 3.
    Type: Application
    Filed: June 3, 2011
    Publication date: April 10, 2014
    Applicant: SAN NOPCO LTD.
    Inventor: Tsuyoshi Ando
  • Publication number: 20110281985
    Abstract: The object of the present invention is to provide a defoaming agent that is superior in defoaming properties (foam-breaking, foam-inhibiting effect, defoaming durability). The present invention is a defoaming agent comprising a fatty acid amide (A), a base oil (B) that is liquid at 25° C., an oil thickening agent (C), and a surfactant (D), wherein the content of the fatty acid amide (A) is 1 to 10% by weight, the content of the base oil (B) that is liquid at 25° C. is 71 to 97.9% by weight, the content of the oil thickening agent (C) is 0.1 to 10% by weight, and the content of the surfactant (D) is 1 to 9% by weight based on the weight of the fatty acid amide (A), the base oil (B) that is liquid at 25° C., the oil thickening agent (C), and the surfactant (D), and the viscosity (25° C.) at a shear rate of 1000 s?1 is 0.1 to 1.0 Pa·s.
    Type: Application
    Filed: January 29, 2010
    Publication date: November 17, 2011
    Applicant: SAN NOPCO LTD.
    Inventors: Yohei Matsumura, Nobuo Hisada, Yoshihide Izumi