Patents Assigned to Sanko Kaihatsu Kagaku Kenkyusho
  • Patent number: 6040470
    Abstract: There is provided a developer composition including at least one of sulfonyl compounds represented by formula (1) and at least one of sulfonyl compounds represented by formula 2: ##STR1## wherein X is H or lower alkyl, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 which may be the same or different, present H, halogen or lower alkyl and Y represents alkyl, benzenesulfonyl, benzoyl et al, A thermalsensitive recording medium having the above developer is of high sensitivity, less surface-blushing with lapse of time and is excellent in storage stability of a recorded image, particularly in heat resistance, humidity resistance and anti-plasticizer.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: March 21, 2000
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Shigeru Oda, Eiji Kawabata
  • Patent number: 5840652
    Abstract: There is provided a developer composition including at least one of sulfonyl compounds represented by formula (1) and at least one of sulfonyl compounds represented by formula 2: ##STR1## wherein X is H or lower alkyl, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 which may be the same or different, present H, halogen or lower alkyl and Y represents alkyl, benzenesulfonyl, benzoyl et al, A thermalsensitive recording medium having the above developer is of high sensitivity, less surface-blushing with lapse of time and is excellent in storage stability of a recorded image, particularly in heat resistance, humidity resistance and anti-plasticizer.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: November 24, 1998
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Shigeru Oda, Eiji Kawabata
  • Patent number: 5393332
    Abstract: Herein disclosed is a method for preparing a nuclear-substituted salicylic acid or a metal salt thereof represented by the following general formula (1): ##STR1## [wherein R.sub.1 and R.sub.2 each represents a t-butyl group, a t-amyl group, a t-octyl group, an isononyl group or an isododecyl group, provided that at least one of R.sub.1 and R.sub.2 represents an isononyl group or an isododecyl group; M represents a hydrogen atom or a metal atom; and n is the atomic valency of the metal atom M] which comprises the step of subjecting, to a Kolbe-Schmitt reaction, an alkali metal salt of a nuclear-substituted phenol represented by the following general formula (2): ##STR2## [wherein R.sub.1 and R.sub.2 are the same as those defined above] in which 100 to 50% of the alkali metal salt is potassium salt and 0 to 50% thereof is sodium salt, in a substantially water-insoluble solvent as a reaction medium.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: February 28, 1995
    Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Toranosuke Saito, Takashi Ishibashi, Eiji Kawabata, Masato Tanaka, Toshio Kimura
  • Patent number: 5328884
    Abstract: The present invention provides a color developer composition characterized in that the composition contains a color developer comprising as its main component a nucleus-substituted salicylic acid salt represented by the formula (1) given below, and at least one amide compound selected from the group consisting of the compounds of represented by the formula (2) and formula (3) given below. ##STR1## wherein R.sub.1 to R.sub.10 are as defined in the specification.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: July 12, 1994
    Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Masato Tanaka, Tomoharu Shiozaki, Shigeru Oda, Toranosuke Saito
  • Patent number: 5250108
    Abstract: The present invention provides a color developer composition characterized in that the composition contains a color developer comprising as its main component a nucleus-substituted salicylic acid salt represented by the formula (1) given below, and at least one amide compound selected from the group consisting of the compounds of represented by the formula (2) and formula (3) given below. ##STR1## wherein R.sub.1 to R.sub.10 are as defined in the specification.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: October 5, 1993
    Assignees: Kanzaki Paper Manufacturing Co. Ltd., Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Masato Tanaka, Tomoharu Shiozaki, Shigeru Oda, Toranosuke Saito
  • Patent number: 5248828
    Abstract: A method for preparing a sulfone represented by the following formula: ##STR1## wherein R' represents a lower alkyl group, an aryl group or an aryl group whose nucleus has at least one substituent selected from the group consisting of a halogen atom, nitro group, a lower alkyl group, phenyl group and a phenyl group substituted with a halogen atom, or an alkali metal salt thereof. A sulfonic acid ester of 4-hydroxybiphenyl is condensed at a temperature of 0.degree. to 200.degree. C. in a presence of a Lewis acid or a super-strong acid with a sulfonyl chloride represented by the formula R'SO.sub.2 Cl, wherein R' is the same as that defined above.
    Type: Grant
    Filed: June 10, 1992
    Date of Patent: September 28, 1993
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toranosuke Saito, Shigeru Oda, Hiroki Tsunomachi, Daishiro Kishimoto
  • Patent number: 5236988
    Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition contains an engineering plastic material and an aliphatic polyester.
    Type: Grant
    Filed: September 25, 1990
    Date of Patent: August 17, 1993
    Assignees: Sekisui Chemical Co., Ltd., Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Kazuo Doyama, Makoto Yamaguchi, Makoto Ohsuga, Akihiro Niki, Toranosuke Saito, Hiroki Tsunomachi, Daishiro Kishimoto
  • Patent number: 5235084
    Abstract: A method for preparing a sulfone represented by the following formula: ##STR1## wherein R and R' each represent a lower alkyl group, an aryl group or an aryl group whose nucleus has at least one substituent selected from the group consisting of a halogen atom, nitro group, a lower alkyl group, phenyl group and a phenyl group substituted with a halogen atom, comprises the step of condensing a sulfonic acid ester of 4-hydroxybiphenyl represented by the following formula: ##STR2## with a sulfonyl chloride of R'SO.sub.2 Cl at a temperature of 0.degree. to 200.degree. C. in the presence of a Lewis acid or a superstrong acid.
    Type: Grant
    Filed: April 7, 1992
    Date of Patent: August 10, 1993
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toranosuke Saito, Shigeru Oda, Hiroki Tsunomachi, Daishiro Kishimoto
  • Patent number: 5235024
    Abstract: A polyester is provided that comprises as main monomer components thereof a dicarboxylic acid and a diol, including a p-quaterphenyl derivative of specific formula. The use of appropriate kinds of dicarboxylic acid for the polyester makes it possible to obtain a thermoplastic elastomer or an engineering platic material (i.e., liquid-crystal polymer).
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: August 10, 1993
    Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Akihiro Niki, Makoto Ohsuga, Toshio Uesaka, Toranosuke Saito, Hiroki Tsunomachi, Kazuo Doyama, Makoto Yamaguchi, Daishiro Kishimoto
  • Patent number: 5191057
    Abstract: A polyester is provided that comprises as main monomer components thereof a dicarboxylic acid and a diol, including a p-quaterphenyl derivative of specific formula. The use of appropriate kinds of dicarboxylic acid for the polyester makes it possible to obtain a thermoplastic elastomer or an engineering plastic material (i.e., liquid-crystal polymer).
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: March 2, 1993
    Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Akihiro Niki, Makoto Ohsuga, Toshio Uesaka, Toranosuke Saito, Hiroki Tsunomachi, Kazuo Doyama, Makoto Yamaguchi, Daishiro Kishimoto
  • Patent number: 5164001
    Abstract: Herein disclosed are a method for preparing an aqueous developer dispersion which comprises the steps of dissolving, in an organic solvent, a developer which comprises a nuclear-substituted salicylic acid salt represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group having not more than 15 carbon atoms, a cycloalkyl group, a phenyl group, a nuclear-substituted phenyl group, an aralkyl group or a nuclear-substituted aralkyl group, or two adjacent groups selected from R.sub.1 to R.sub.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: November 17, 1992
    Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Toranosuke Saito, Shigeru Oda, Tomoharu Shiozaki, Masato Tanaka
  • Patent number: 5143890
    Abstract: The present invention provides a heat sensitive recording material, including a substrate and a heat sensitive recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor reactive with the dye to form a color when contacted therewith, the recording material also including 1-(4-methoxyphenoxy)-2-(2-methylphenoxy)ethane in the heat sensitive recording layer.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: September 1, 1992
    Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kenkyusho Corporation
    Inventors: Tetsuo Tsuchida, Yukihiro Abe, Tomoyuki Okimoto, Toranosuke Saito
  • Patent number: 5118443
    Abstract: A developer comprising at least one polyvalent metal salt of a nuclear substituted salicylic acid of the following general formula is provided. ##STR1## In the formula, R.sub.1 represents an alkyl group having from 1 to 12 carbon atoms, R.sub.2 represents a hydrogen atom or an alkyl group having from 1 to 12 carbon atoms, R.sub.3 represents a hydrogen atom or a methyl group provided that at least one of R.sub.1 and R.sub.2 is a secondary butyl group, a secondary hexyl group, an isohexyl group, a secondary octyl group, an isononyl group, a secondary decyl group, a secondary dodecyl group or an isododecyl group and the total number of the carbon atoms in R.sub.1, R.sub.2 and R.sub.3 is from 9 to 18, M is a polyvalent metal atom, and m is a valence of M. An aqueous dispersion containing the developer and a method for preparing the developer are also described.
    Type: Grant
    Filed: January 22, 1991
    Date of Patent: June 2, 1992
    Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Toranosuke Saito, Takashi Ishibashi, Tomoharu Shiozaki, Tetsuo Shiraishi
  • Patent number: 5107006
    Abstract: The clathrate compound according to the present invention which comprises, as host crystals, crystals of a polyvalent metal salt of a specific nuclear-substituted salicylic acid or a hydrate thereof and, as a gest molecule, an organic compound having 1 to 12 carbon atoms is well soluble in organic solvents or organic compounds having relatively low polarity and has good stability to light rays and NO.sub.x gases and, therefore, the clathrate compound has excellent properties favorable for use as antibiotics, stabilizers for polymeric compounds and developers for recording materials.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: April 21, 1992
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventor: Toranosuke Saito
  • Patent number: 5049685
    Abstract: A nuclear substituted salicylic acid represented by the following general formula (I): ##STR1## (in the formula (I), R.sub.1 represents a methyl group, an isopropyl group, a tert-butyl group, a tert-amyl group, a tert-hexyl group, a tert-octyl group, an .alpha., .alpha.-dialkylbenzyl group or a nuclear substituted .alpha., .alpha.-dialkylbenzyl group; and R.sub.2 represents a tert-butyl group, a tert-amyl group, a tert-hexyl group, a tert-octyl group, an .alpha., .alpha.-dialkylbenzyl group or a nuclear substituted .alpha., .alpha.-dialkylbenzyl group) and a salt thereof are herein disclosed. The novel nuclear substituted salicylic acids and salts thereof according to the present invention have good solubility in water, organic solvents or organic polymeric compounds and, therefore, these compounds are very favorable as bactericidal and germicidal agents, stabilizers for polymeric compounds or color developing agents for recording materials.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: September 17, 1991
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventor: Toranosuke Saito
  • Patent number: 5041604
    Abstract: A process for producing a high quality di(aryloxy)alkane with a high yield by the use of readily commercially available materials, without using any particular solvent or agent and by means of a simple operation and a general apparatus is provided, which process comprises subjecting a halogenated alkane of the formula (II)X--A--Y (II)wherein X and Y each represent a halogen atom and A represents a lower alkylene group, and a phenol of the formula (III) ##STR1## wherein R.sub.1 to R.sub.5 each are same or different, represent hydrogen, halogen, lower alkyl, lower alkoxy, carboxylic acid salt, acyl or nitro group, and may form a ring in conjunction of two adjacent groups,to condensation reaction in the presence of an alkali in an aqueous medium to form a di(aryloxy)alkane of the formula (I) ##STR2## and is characterized (i) by carrying out the condensation reaction in a molar ratio of the compound of the formula (II): the phenol of the formula (III): the alkali in terms of monovalent base of 1:1.5 to 3.0:1.
    Type: Grant
    Filed: June 20, 1990
    Date of Patent: August 20, 1991
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi
  • Patent number: 5019548
    Abstract: A heat sensitive recording material comprising a substrate and a recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor reactive with the dye to form a color when contacted therewith, the recording material being characterized in that, as the color acceptor is used at least one compound selected from the group consisting of 4-hydroxy-4'-isopropyloxydiphenylsulfone, 4,4'-(1,3-dimethylbutylidene) bisphenol, 4,4'-(1-phenylethylidene)bisphenol, 4,4'-(p-phenylenediisopropylidene)bisphenol and 4,4'-(m-phenylenediisopropylidene) bisphenol, and to the recording layer is added at least one of a heat-fusible substance represented by the formula [I] ##STR1## wherein X is hydrogen atom, halogen atom, C.sub.1.about.4 alkyl or C.sub.1.about.4 alkoxy.
    Type: Grant
    Filed: August 24, 1989
    Date of Patent: May 28, 1991
    Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kenkyusho Corporation
    Inventors: Toshitake Suzuki, Fumio Seyama, Shuki Okauchi, Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi
  • Patent number: 5011879
    Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition comprises an engineering plastic material and at least one p-quaterphenyl derivative of specific formula.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: April 30, 1991
    Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toshio Uesaka, Akihiro Niki, Makoto Ohsuga, Toranosuke Saito, Hiroki Tsunomachi, Makoto Yamaguchi, Kazuo Doyama, Daishiro Kishimoto
  • Patent number: 4973720
    Abstract: There is provided a process of producing p-benzoquinone, wherein hydroquinone and hydrogen peroxide are reacted in water, an aqueous inorganic acid solution, an inert organic polar solvent or a mixture of water with an inert organic polar solvent in the presence of a catalyst selected from the group consisting of iodine, hydrogen iodide, and iodine compounds of metals.According to the process, p-benzoquinone can be obtained from hydroquinone with the yield and the quality of the p-benzoquinone being high without requiring any special facilities, equipments and operations.
    Type: Grant
    Filed: October 4, 1988
    Date of Patent: November 27, 1990
    Assignee: Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toranosuke Saito, Kenichi Ikemoto, Hiroki Tsunomachi, Katsuya Sakaguchi
  • Patent number: 4950330
    Abstract: An aqueous dispersion of a developer for pressure-sensitive recording sheet, having superior handling performance and storage stability in a high concentration and a process for producing the dispersion are provided, which developer is expressed by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and represent H, halogen, alkyl of 1 to 9 carbon atoms, alkylene, cycloalkyl, cycloalkylene, phenyl, nucleus-substituted phenyl, aralkyl or nucleus-aralkyl; adjacent two of R.sub.1 to R.sub.4 may form a ring; n is an integer of one or more; and M is Mg, Ca, Zn, Al, Fe, Co, Ni or a basic ion of the foregoing, and which developer has a softening point of 30.degree. C. or higher and is dispersed in water, containing a dispersing agent, the size of particles of the developer being 0.3 to 5.mu.
    Type: Grant
    Filed: September 7, 1989
    Date of Patent: August 21, 1990
    Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Toranosuke Saito, Shouichi Murata, Eiji Kawabata, Tomoharu Shiozaki, Tetsuo Shiraishi