Abstract: The present invention relates to an emeraldine base composite, its preparation, and use as an effective anticorrosive pigment additive for corrosion inhibition. The emeraldine base composite comprises an insulating form of polyaniline or its derivatives adhered to an inorganic or organic material substrate such that the emeraldine base covers from about 1-100% surface of the material. Inter alia, the emeraldine base composite can be added to a coating as an anticorrosive pigment additive that inhibits corrosion and as a filler material that increases strength and barrier properties of coating.