Abstract: Highly efficient and universal biomass conversion methods are described. Methods utilize a base-catalyzed decarboxylation reaction in a conversion process carried out in the presence of excess base to overcome carbonate formation from CO2. Methods can efficiently convert all components of a biomass feedstock to liquid hydrocarbons and carbon dioxide byproduct. The process has several versions: hydrolysis and alcoholysis, etc. The chemical process can be carried out with nearly 100% conversion for any type of biomass feedstock and requires no expensive or complicated pretreatment. The conversion reactions can be carried out at moderate temperatures of 170-300° C. and form a product that can include a mixture of hydrocarbons and oxygenated hydrocarbons, including alcohols and phenol derivatives.

Abstract: Methods and systems directed to the separation of tritium from an aqueous stream are described. The separation method is a multi-stage method that includes a first stage during which tritium of a tritium-contaminated aqueous stream is adsorbed onto a separation phase, a second stage during which the adsorbed tritium is exchanged with hydrogen in a gaseous stream to provide a gaseous stream with a high tritium concentration, and a third stage during which the tritium of the gaseous stream is separated from the gaseous stream as a gaseous tritium product.

Abstract: Alpha/beta radiation barrier materials and structures formed to include the barrier materials are described. Barrier materials include a matrix and particulate materials contained in the matrix. The particulates include alpha/beta radiation absorbers. Alpha/beta radiation absorbers of the barrier materials can be molecular, particulates, or defined nanostructures that are capable of absorbing incident alpha/beta particle energies. Matrix materials can include organic or inorganic materials including thermoplastic polymers, thermoset polymers, glasses, ceramics, etc.

Abstract: Supported catalysts having an atomic level single atom structure are provided such that substantially all the catalyst is available for catalytic function. Processes of forming a catalyst unto a porous catalyst support is also provided.

Abstract: A device for improving the accuracy and precision of measuring equipment changes due to corrosion, erosion, build-up of material, and combinations thereof. Increased control over the placement and removal of a coupon within the equipment is provided. Embodiments of the coupon provide multiple approaches for such measurements such as e.g., weight changes, thickness changes, inspection and analysis of the contacting surface of the coupon, and combination. Improved measurements with coupons using probes such as e.g., ultrasonic transducers is also described.

Abstract: Systems and methods for monitoring microorganisms on a surface are provided. In particular, a flat, patterned sensing electrode can be positioned proximate a surface in non-contact relationship with the surface. The sensing electrode can include a working electrode and a counter electrode. The surface and the sensing electrode can be submerged in an aqueous medium. An alternating current signal can be applied at the working electrode. The signal can propagate through the aqueous medium and can be measured at the counter electrode. The presence of microorganisms on the surface can cause changes in the signal as the signal propagates through the aqueous medium. Such changes in the signal can be used to determine impedance parameters, which can correspond to microbial characteristics associated with the surface. For instance, the microbial characteristics can be associated with a biofilm, corrosion and/or bio-corrosion on the surface.

Abstract: Radiological containment bags for use in storing alpha particle emitting waste are described. The radiological containment bags are formed of a multilayer film with an inner layer of the film being a sacrificial layer that lies between the interior of the bag and a structural polymeric layer. The sacrificial layer includes a flexible composite material that in turn includes a polymeric matrix and an alpha particle energy absorber incorporated in the polymeric matrix. The sacrificial layer can include a chromophore that can detect early degradation of the sacrificial material.

Abstract: Devices, systems and methods for use of an autonomously powered inductive time domain reflectometer sensor device are provided. A sensor device for a power line can include a first induction coil and a second induction coil coupled to the power line and a control device. The first induction coil can be configured to inject a first signal on a power line by inducing a first current on the power line. The second induction coil can be configured to inject a second signal on the power line by inducing a second current on the power line. The control device can be configured to control the second induction coil to inject the second signal to cancel a portion of the first signal. As a result of the second signal cancelling a portion of the first signal, the first signal can be configured to propagate in a single direction on the power line.

Abstract: Spectrophotometers and spectroscopy processes are described that can provide for in-line calibration at every spectral acquisition as well as for continuous response correction during sample processing. The spectrophotometers include multiple polychromatic light sources that include characteristic emission spectra for use as an internal wavelength drift calibration system that is independent of environmental factors. Correction functions provided by the internal calibration process can be applied continuously and across an entire sample spectrum. The intensity response of each spectrometer in a spectrophotometer can also be monitored and continuously corrected for stray light, dark current, readout noise, etc.

Abstract: The present disclosure is directed to a detection assembly for detecting radiation emitted by radionuclides present within an animal. The detection assembly includes a housing having one or more walls defining a chamber. The detection assembly also includes a cover removably positioned over the top end of the housing, with the cover being configured for receipt of the animal. Furthermore, the detection assembly includes a radiation sensor positioned within the chamber. The radiation sensor is configured to detect the radiation emitted by the radionuclides present within the animal. Additionally, the detection assembly includes a shield positioned around a first portion of the radiation sensor, with the shield being configured to at least partially shield the radiation sensor from environmental radiation. A second portion of the radiation sensor is unshielded to permit the radiation sensor to receive radiation emitted by the radionuclides present within the animal.

Abstract: Methods for forming alane are described. The method drives the alane producing chemical reaction by a mechanical energy source such as a ball mill and includes stabilization of the product with solvent. At least one of the reactants is insoluble in the solvent. Thus, the product is both stabilized and phase-separated from the reactant(s) immediately upon formation. The method can be used to form ?-alane, for instance for use in hydrogen storage.

Abstract: Systems and methods for examining spectral data over the course of a high speed event are described. The systems and methods can enable observation of the spectral evolution of a transient phenomenon into segment intervals on the order of, milliseconds or microseconds. The methods include reflecting light from an event off of a rotating mirror and sequentially delivering light from the mirror to a series of optical waveguides for sequential spectral analysis. The systems and methods can be useful in a wide variety of applications such as, LIBS applications; examination of high energy devices such as explosions or simulations of explosions; examination of deposition processes, e.g., coating formations; examination of chemical reactions; etc.

Abstract: A process of producing electrically conductive pathways within additively manufactured parts and similar parts made by plastic extrusion nozzles. The process allows for a three-dimensional part having both conductive and non-conductive portions and allows for such parts to be manufactured in a single production step.

Abstract: A system for detecting high-energy photons includes a pixelated image detector exposed to visible light and high-energy photons, and the pixelated image detector generates one or more images from the exposure to the visible light and high-energy photons. The system further includes one or more processors operably connected to the pixelated image detector and configured to perform operations on the one or more images to discriminate between visible light and high-energy photons. A method for detecting high-energy photons includes exposing a pixelated image detector to visible light and high-energy photons and discriminating between the visible light that interacts with the pixelated image detector and the high-energy photons that interact with the pixelated image detector.

Abstract: Methods and systems for thermal ionization of a sample and formation of an ion beam are described. The systems incorporate a thermal ionization filament that is formed of a graphene-based material such as graphite, graphene, graphene oxide, reduced graphene oxide or combinations thereof. The filament material can be doped or chemically modified to control and tune the work function of the filament and improve ionization efficiency of a system incorporating the filament. The systems can be utilized in forming an ion beam for target bombardment or analysis via, e.g., mass spectrometry.

Abstract: A LiBH4—C60 nanocomposite that displays fast lithium ionic conduction in the solid state is provided. The material is a homogenous nanocomposite that contains both LiBH4 and a hydrogenated fullerene species. In the presence of C60, the lithium ion mobility of LiBH4 is significantly enhanced in the as prepared state when compared to pure LiBH4. After the material is annealed the lithium ion mobility is further enhanced. Constant current cycling demonstrated that the material is stable in the presence of metallic lithium electrodes. The material can serve as a solid state electrolyte in a solid-state lithium ion battery.

Abstract: The present invention is directed to a method of cleaning a diesel particulate filter. The method requires a step of contacting the diesel particulate filter with a cleaning composition containing one or more fatty acids or a derivative thereof. The one or more fatty acids or a derivative thereof may include a natural oil, such as a plant-based oil.

Abstract: The present invention is directed to multifunctional nanomaterials for photothermal heating and catalytic applications. The present invention discloses a method of photothermally heating a solution. The present method also discloses a method of catalyzing a reaction. Both methods require a step of exposing a solution to at least one wavelength of the electromagnetic spectrum. A gold-iron oxide nanomaterial comprising an iron oxide substrate and discrete gold particles deposited on the substrate is also disclosed.

Abstract: A LiBH4—C60 nanocomposite that displays fast lithium ionic conduction in the solid state is provided. The material is a homogenous nanocomposite that contains both LiBH4 and a hydrogenated fullerene species. In the presence of C60, the lithium ion mobility of LiBH4 is significantly enhanced in the as prepared state when compared to pure LiBH4. After the material is annealed the lithium ion mobility is further enhanced. Constant current cycling demonstrated that the material is stable in the presence of metallic lithium electrodes. The material can serve as a solid state electrolyte in a solid-state lithium ion battery.

Abstract: Vessel assemblies, heat transfer units for prefabricated vessels, and methods for heat transfer prefabricated vessel are provided. A heat transfer unit includes a central rod, and a plurality of peripheral rods surrounding the central rod and connected to the central rod. The plurality of peripheral rods are movable between a first collapsed position and a second bowed position, wherein in the second bowed position a midpoint of each of the plurality of peripheral rods is spaced from the central rod relative to in the first position. The heat transfer unit further includes a heat transfer element connected to one of the plurality of peripheral rods.