Abstract: An improvement in the Claus Process for producing sulfur by reaction of hydrogen sulfide with sulfur dioxide at elevated temperature in the presence of a porous catalyst is described. The improvement lies in employing a porous catalyst, preferably alumina, having a large surface area at least 40% of which is provided by pores having diameters over the range 40 A.degree. to 150 A.degree. or having at least 20% of its surface area provided by pores having diameters over the range 80 A.degree. to 150 A.degree..