Patents Assigned to Sennics Co., Ltd.
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Patent number: 12466797Abstract: A compound having anti-aging and discoloration resistance effects and a preparation method therefor are provided. The structure of the compound is represented by formula (I). The compound provides longer-lasting anti-aging performance, and has discoloration resistance. The compound may be used as an anti-aging agent in rubber products, especially rubber tires, and can prevent the aging and deterioration of rubber products or rubber tires due to light, heat, oxygen, and fatigue, during use.Type: GrantFiled: May 3, 2022Date of Patent: November 11, 2025Assignee: Sennics Co., Ltd.Inventors: Xiangyun Guo, Jinguo Xing, Yanxiang Liu, Hui Li, Yang Gao, Zhimin Tang, Haibo Zhu, Qi Qi
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Patent number: 12172943Abstract: A polyalkyl p-phenylenediamine antidegradant having a structure represented by Formula I, its intermediates and a preparation method thereof are provided. The polyalkyl p-phenylenediamine antidegradant provides good thermal oxidative aging resistance and UV aging resistance.Type: GrantFiled: October 27, 2023Date of Patent: December 24, 2024Assignee: Sennics Co., Ltd.Inventors: Jinguo Xing, Xiangyun Guo, Gan Liang, Jiaqiang Zhang, Zhimin Tang
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Patent number: 12037303Abstract: A method for preparing a diaryl-p-phenylenediamine compound of Formula I comprises the steps of reacting a compound of Formula II and a compound of Formula III in a condensation dehydrogenation reaction in the presence of a solvent, a hydrogen acceptor, a water-carrying agent, and a catalyst; wherein R1, R2 and R3 are independently selected and each is H, a C1-C8 alkyl, a C3-C8 cycloalkyl, a C1-C8 alkoxy, a C3-C8 cycloalkoxy, or phenyl; a and c are independently selected and each is an integer of 0 to 5, and b is an integer of 0 to 4:Type: GrantFiled: December 29, 2022Date of Patent: July 16, 2024Assignee: Sennics Co., Ltd.Inventors: Jinguo Xing, Xiangyun Guo, Zhimin Tang
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Patent number: 12031036Abstract: A formulation for rubber composition with reduced odor and good thermal oxidative aging-resistance and tension fatigue resistance comprising 100 parts by weight of a diene elastomer, 30 to 70 parts by weight of a reinforcing filler, 0.1 to 8 parts by weight of an antidegradant composition, and 0.5 to 3 parts by weight of a crosslinker, wherein the antidegradant composition includes a 6PPD antidegradant with a purity of equal to or greater than about 98% and an S-TMQ. The rubber composition has no added odor inhibitor/adsorbent or deodorizing additive, while by using combination of 6PPD with purity of equal to or greater than about 98% and an S-TMQ instead of traditional combination of 6PPD and a TMQ, the VOC emission of the rubber composition is effectively reduced, the odor grade is reduced, and the thermal oxidative aging-resistance and tension fatigue resistance is improved.Type: GrantFiled: October 13, 2021Date of Patent: July 9, 2024Assignee: Sennics Co., Ltd.Inventors: Yang Gao, Jin Zhang, Zhimin Tang
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Patent number: 12031037Abstract: A rubber protective wax, comprising hydrocarbon compounds, a polyethylene wax and an antidegradant. The rubber protective wax of the present invention can render rubber good thermal oxidative aging resistance, static ozone aging resistance, dynamic ozone aging resistance, flex cracking resistance and tensile fatigue resistance, and has good protection effects in both static environment and dynamic load environment.Type: GrantFiled: December 9, 2021Date of Patent: July 9, 2024Assignee: Sennics Co., Ltd.Inventors: Hao Wang, Yang Gao, Yousheng He
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Patent number: 12031012Abstract: An antidegradant composition, an antidegradant master batch comprising the antidegradant composition and a rubber composition comprising the antidegradant composition or the antidegradant master batch. The antidegradant composition comprises antidegradant TMPPD and one or two selected from antidegradant N3100-B and an antidegradant N3100-C. The antidegradant composition and antidegradant master batch render a rubber compound and a rubber article excellent discoloration resistance, fatigue resistance, ozone resistance, and mechanical properties before and after thermal oxidative aging and enables the rubber compound to be used in the manufacture of all or part of the rubber matrix, especially as a tire sidewall rubber composition and a tire tread rubber composition.Type: GrantFiled: November 15, 2021Date of Patent: July 9, 2024Assignee: Sennics Co., Ltd.Inventors: Yang Gao, Hui Li, Hao Wang
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Patent number: 12024482Abstract: Antidegradant composition comprising a first compound of Formula I: and a second antidegradant that is not the compound of Formula I; and rubber composition comprising the antidegradant composition. The rubber composition has good resistance to appearance discoloration while maintaining the mechanical and anti-aging properties, thus, are suitable for making the entire tire or as part of the rubber matrix.Type: GrantFiled: April 9, 2021Date of Patent: July 2, 2024Assignee: Sennics Co., Ltd.Inventors: Yang Gao, Hui Li
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Patent number: 11008281Abstract: Antidegradant compound of Formula I: and antidegradant composition comprising the same and rubber composition comprising the antidegradant compound or composition. The rubber composition has good resistance to appearance discoloration while maintaining the mechanical and anti-aging properties, thus, are suitable for making the entire tire or as part of the rubber matrix.Type: GrantFiled: December 19, 2019Date of Patent: May 18, 2021Assignee: Sennics Co., Ltd.Inventors: Yang Gao, Hui Li
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Patent number: 10829615Abstract: Novel and long-acting rubber anti-degradant and rubber composition comprising the same for tires. The anti-degradant comprises at least two compounds, each of which is selected from a compound of Formula I, II, III-a, or III-b: and each of the compounds have different formulae from others, and can't be compounds of formula III-a and III-b at the same time when the anti-degradant consists of only 2 compounds. The anti-degradant is used to provide a rubber composition with improved long-term resistance to thermo-oxidative aging and ozone aging.Type: GrantFiled: December 11, 2018Date of Patent: November 10, 2020Assignee: Sennics Co., Ltd.Inventors: Yang Gao, Biao Zou
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Patent number: 10793510Abstract: A method for preparing an aryl substituted p-phenylenediamine substance is provided. A structural formula of the aryl substituted p-phenylenediamine substance is shown as Formula (I?), where each of R? and R? is phenyl or o-methylphenyl, and R? is same as or different from R?; and the method comprises that: a raw material A and a raw material B are reacted in the presence of a hydrogen acceptor and a catalyst to form the aryl substituted p-phenylenediamine substance, the raw material A having a structure shown as Formula (I), the raw material B being cyclohexanone and/or o-methylcyclohexanone and the hydrogen acceptor being a hydrogen acceptor capable of accepting hydrogen for conversion into the raw material B. Raw materials are low in cost and readily available; use of a large amount of water for post-treatment is avoided. The reaction condition is relatively mild, and corrosion to equipment is avoided.Type: GrantFiled: April 18, 2018Date of Patent: October 6, 2020Assignee: Sennics Co., Ltd.Inventors: Xiangyun Guo, Jinguo Xing, Xiaomin Ruan, Xinmin Chen
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Patent number: 10106513Abstract: A method for preparing 2-mercaptobenzothiazole where the aniline method is adopted to perform reaction in the presence of a catalyst, and the catalyst includes sulfonic acid type imidazolium ionic liquid. The sulfonic acid type imidazolium ionic liquid is a type of acidic functionalized ionic liquid, and has the advantages of both a solid acid and a liquid acid. The sulfonic acid type imidazolium ionic liquid is adopted as an active ingredient of the catalyst, and may remarkably improve a conversion rate of the reaction raw materials and increase a yield of the 2-mercaptobenzothiazole. Meanwhile, due to the characteristics of high catalytic activity, no volatilization, low corrosion, high thermal stability and the like of the 2-mercaptobenzothiazole, the preparation method also has the comprehensive advantages of simple process, low cost, low tar yield, high environment friendliness and the like.Type: GrantFiled: April 9, 2018Date of Patent: October 23, 2018Assignee: Sennics Co., Ltd.Inventors: Xinmin Chen, Libao Wu, Song Shi, Shang Gao