Abstract: A method of reactive extrusion copolymerization of vinyl monomer consisting of (1) feeding vinyl monomer or at least one vinyl monomer together with an initiator into the first screw of twin-screw extruder, and modified resin into the subsequent screw section; (2) feeding the above monomer into the screw segment after auto-acceleration zone and feeding the initiator corresponding to the temperature of barrel and micro/nano inorganic modified fillers after the half-life period of the initiator; (3) feeding the antioxidant and anti-UV agent at the end of the polymerization, and then removing unpolymerized monomer and by-products by devolatilization of screw segment; (4) obtaining vinyl copolymer resin with a anticipated molecular weight of 5×102 to 6×105 from the reactive extrusion polymerization by controlling the temperature of different screw segments.
Type:
Grant
Filed:
October 11, 2018
Date of Patent:
June 23, 2020
Assignees:
EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY, SHANGHAI FUYUAN RUBBER AND PLASTIC TECHNOLOGY LTD.
Inventors:
Anna Zheng, Yong Guan, Dafu Wei, Xiang Xu, Pengfei Zhan, Weixing Liu, Han Shi